Novel Method for Recycle Epoxy Resin from Waste Printed Circuit Board

Article Preview

Abstract:

This research was aimed to study and develop a method for recycle epoxy resin from waste printed circuit board by hot solvent methods and DMSO/NaOH catalytic extraction method. It was found that the pressure tank system, sub set of hot solvent method, variable as following; pressure of 15 bar, temperature of 80 °C, reaction time for 6 h and ethyl acetate solvent presented maximum yield 50.46 %, while DMSO/NaOH catalytic system at 145 °C for 5 h was found maximum yield of 42.97 %. Recycled epoxy resin, the final product from hot solvent and DMSO/NaOH catalytic were showed similarly clear orange-yellow high viscosity. Comparatively, DMSO/NaOH system showed slightly darker color than that of hot solvent system. Functional group at 3000-2850, 1480-1540 and 1020-1040 cm-1, characterized from Fourier transform infrared spectroscopy (FT-IR), indicated that the both product were alkane, aromatic, and phenyl-O-C group, respectively. It could be confirmed that the beneficial functional group of recycled epoxy resin was appeared as a new epoxy resin.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 931-932)

Pages:

90-94

Citation:

Online since:

May 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] J. Li, H. Lu, J. Guo, Z. Xu, Y. Zhou, Recycle technology for recovering resources and products from waste printed circuit boards, Environ. Sci. Technol. 47 (2007) 1995-(2000).

DOI: 10.1021/es0618245

Google Scholar

[2] K. Huang, J. Guo, Z. Xu, Recycling of waste printed circuit boards: A review of current technologies and treatment status in China, J. Hazard. Mater. 164 (2009) 399-408.

DOI: 10.1016/j.jhazmat.2008.08.051

Google Scholar

[3] J. Ladou, Printed circuit board industry, Int. J. Hyg. Envir. Heal. 209 (2006) 211-219.

Google Scholar

[4] R. Dantungee, S. Somchua, S. Siengchin, Recycling glass fiber/epoxy resin of waste print circuit board: morphology and mechanical properties, Mech. Compos. Mater. 48 (2012) 325-330.

DOI: 10.1007/s11029-012-9279-1

Google Scholar

[5] M. Luda, A. Balabanovic, and, G. Camino, Thermal decomposition of fire retardant brominated epoxy resins, J. Anal. Appl. Pyrolysis. 65 (2002) 25-40.

DOI: 10.1016/s0165-2370(01)00175-9

Google Scholar

[6] X. Wang, Q. Zhang, Synthesis Characterization and cure properties of phosphorous-containing epoxy resin for flame retardance, Eur. Polym. J. 40 (2004) 385-395.

DOI: 10.1016/j.eurpolymj.2003.09.023

Google Scholar

[7] W. Dang, M. Kubouchi, S. Yamamoto, H. Sembokuya, K. Tsuda, An approach to chemical recycling of epoxy resin cured with amine using nitric acid, Polymer. 43 (2002) 2953-2958.

DOI: 10.1016/s0032-3861(02)00100-3

Google Scholar

[8] W. Dang, M. Kubouchi, H. Sembokuya, K. Tsuda, Chemical recycling of glass fiber reinforced epoxy resin cured with amine using nitric acid, Polymer. 46 (2005) 1905-(1912).

DOI: 10.1016/j.polymer.2004.12.035

Google Scholar

[9] J. Chang, Y. Sheen, R. Chang, F. Chang, The thermal degradation of phosphorous-containing co polyesters, Polym. Degrad. Stab. 54 (1996) 365-371.

Google Scholar

[10] H. Tagaya, Y.I. Suzuki, N. Komuro, J.I. Kadokawa, Reactions of model compounds of phenol resin in sub- and supercritical water under an argon atmosphere, J. Mater. Cycle. Waste Manage. 3 (2001) 32-37.

Google Scholar

[11] P. Zhu, Y. Chen, L.Y. Wang, M. Zhou, J. Zhou, The separation of waste printed circuit board by dissolving bromine epoxy resin using organic solvent. Waste. Manag. 33 (2013) 484-488.

DOI: 10.1016/j.wasman.2012.10.003

Google Scholar

[12] P. Yang, Q. Zhou, X.X. Yuan, J.M.N. van Kasteren, Y.Z. Wang, Highly efficient solvolysis of epoxy resin using poly(ethylene glycol)/NaOH systems. Polym. Degrad. Stab. 97 (2012) 1101-1106.

DOI: 10.1016/j.polymdegradstab.2012.04.007

Google Scholar