Synthesis, Characterization, Structure and Thermal Decomposition of a Ag(I) Complex Derived from 3-Pyridinesulfonate and 1,4-Bis(2-Methyl-Imidazol-1-Yl)Butane

Abstract:

A novel complex of [Ag (bib)(3-pySO₃)] n (3-pySO₃:3-pyridinesulfonate; bib 1, 4-bis (2-methyl-imidazol-1-yl) butane) was synthesized and characterized by elemental analysis, IR, X-ray single crystal diffraction. The title complex belongs to triclinic system with space group P-1, a=7.8030(16)Å, b=8.0070(16)Å, c=10.742(2)Å,α=84.64(3)°,β=82.33(3)°,γ=82.76(3)°, V=657.8(2)ų, Z=2, Dc=1.894g/cm3, μ= 1.697mm^-1, F(000)= 374. Final indices is R =0.0480, wR =0.1169. Thermal stability and luminescent property of compound have also been investigated.

• Periodical: Advanced Materials Research (Volume 934)
• Pages: 86-90
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.934.86
• Online since: May 2014
• Authors: Xiao Min Hao, Gang Chen*, Chang Sheng Gu
• Keywords: Ag (I) Complex, Synthesis Crystal Structure, Thermo-Gravimetry (TG)

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