Synthesis, Structure, Luminescest and Thermal Stable Properties of a Silver(I) Coordination Polymer Constructed from 2,4-Dichlorophenoxyacetic Acid and 1,3-Bis(4-Pyridyl) Propane Ligands

Abstract:

A novel complex of [Ag (poa)(bpp)] n (poa:2,4-Dichlorophenoxyacetic acid;bpp: 1,3-Bis (4-pyridyl) propane) was synthesized and characterized by elemental analysis, IR, X-ray single crystal diffraction. The title complex belongs to Monoclinic system with space group P21/c, a=8.849(4)Å, b=26.654(13)Å, c=9.821(5)Å,α=90°,β=111.257(8)°,γ=90°,V=2158.7(17)ų, Z=4,D_c=1.619 g/cm³, μ=1.206 mm^-1, F(000)=1056. Final indices is R=0.0331, wR=0.0851. Therm al stability and luminescent property of compound have also been nvestigated.

• Periodical: Advanced Materials Research (Volume 934)
• Pages: 91-95
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.934.91
• Online since: May 2014
• Authors: Xiao Min Hao, Gang Chen*, Chang Sheng Gu
• Keywords: Ag (I) Complex, Luminescest, Synthesis, Thermo-Gravimetry (TG)

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