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HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 936The Synthesis and Electro-Optical Properties of...

The Synthesis and Electro-Optical Properties of Perylene Dicarboximide Dimer with Electron Withdrawing Groups

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Abstract:

Perylene dicarboximide dimer with electron withdrawing groups were synthesized and fully characterized by ¹H-NMR and ¹³C-NMR spectra. The effects of the substituted groups on the optical and electrochemical properties of the two compounds were investigated. The ∏-∏* absorption peak of the perylene dicarboximide dimer compounds were red shifted from 525nm to 535nm. The band gaps of the dimer could be tuned from 2.28 eV to 2.13 eV. The first reduction wave of the dimer with electron withdrawing groups is shifted by 60 mV to more positive potential compared to that of perylene dicarboximide, suggesting the enhanced electron affinity. Furthemore, the dimer exhibited intermolecular aggregation, and decrease fluorescence quantum yield.

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Materials Science and Engineering Technology

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Periodical:

Advanced Materials Research (Volume 936)

Pages:

950-954

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.936.950

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Online since:

June 2014

Authors:

Hui Min Wei*, Nan Zhao, Nan Jiang, Wen Feng Duan, Bao Xiang Gao

Keywords:

Electron Withdrawing Groups, Extinction Coefficient, Fluorescence Quantum Yield, Optoelectronic Properties, Perylene Dicarboximide

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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