Hydrogenation Kinetics of N-Ethylcarbaozle as a Heteroaromatic Liquid Organic Hydrogen Carrier

Ming Yang; Yuan Dong; Han Song Cheng

doi:10.4028/www.scientific.net/AMR.953-954.981

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 953-954Hydrogenation Kinetics of N-Ethylcarbaozle as a...

Hydrogenation Kinetics of N-Ethylcarbaozle as a Heteroaromatic Liquid Organic Hydrogen Carrier

Abstract:

The catalytic hydrogenation kinetics of N-ethylcarbazole over 5 wt% Ru/Al₂O₃ was investigated at various temperatures. The results shows that the hydrogenation reaction was exothermic and high temperature is unfavorable for the reaction rate. Fully hydrogenation was achieved within 1 hour under the best reaction temperature of 170 °C. The kinetics of N-ethylcarbazole follows the first-order kinetics in terms of the reactant concentration but independent of hydrogen pressure, which was maintained as a constant in the reaction process. The apparent activation energy of N-ethylcarbazole hydrogenation reaction at 150-180 °C was found to be 71.2 kJ/mol.

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Periodical:

Advanced Materials Research (Volumes 953-954)

Pages:

981-984

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.953-954.981

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Online since:

June 2014

Authors:

Ming Yang, Yuan Dong, Han Song Cheng*

Keywords:

Catalytic Hydrogenation, Hydrogen Storage, Kinetic, Liquid Organic Carriers, Polyheterocyclic

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