Wetting/Dewetting Phenomena in the CaF2/Ga and CaF2/Ge Systems

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Abstract:

The wettability of calcium fluoride by liquid Ga and Ge was studied. The initial contact angles indicate that pure liquid Ge and Ga do not wet CaF2. Different spreading kinetics during the experiments was observed. The contact angle in CaF2/Ge system increases with time, while the contact angle in CaF2/Ga system decreases. The same differences were also observed for temperature dependences of the contact angle. It was suggested that these wetting/dewetting tendencies are related to the ratio of the vapor pressure values for the melt and for the substrate. The experimental observations were confirmed by a thermodynamic analysis.

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1532-1536

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October 2006

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© 2006 Trans Tech Publications Ltd. All Rights Reserved

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[1] V. Krasovsky and Y. Naidich: Journal of Materials Science Letters The Nonwettability Behavior of Solid Substrates in Contact with Chemical Active Reach Ti-, Zr-, and Hf- liquid alloys, vol. 17, (1998).

Google Scholar

[2] V. Krasovsky and Y. Naidich: Capillary Properties of Alloys Containing Chemically Active Metals in Contact with Fluoride Refractories, Trans. JWRI vol. 30, (2001).

Google Scholar

[3] N. Eustathopoulos, M.G. Nicholas and B. Devet Wettability at High Temperatures, Pergamon Materials Series (1999).

Google Scholar

[4] J. Bischof, D. Scherer, S. Herminghaus and P. Leiderer: PRL 77 (8) (1996), p.1536.

Google Scholar

[5] G. Reiter: PRL 68 (1) (1992), p.75.

Google Scholar

[6] N. Ravishankar, R. Shelley, C. Gilliss and C. Barry Carter: J. Euro. Ceram. Soc. 23 (2003), p.2777.

Google Scholar

[7] G. Levi and W.D. Kaplan: Acta Mater. 51 (2003), p.2793.

Google Scholar

[8] E. Saiz, A.P. Tomsia and R.M. Cannon: Acta Mater. 46 (7) (1998), p.2349.

Google Scholar

[9] J. A. Campion, B.J. Keene and J.M. Sillwood: J. Mater. Sci. 9 (1994), p.547.

Google Scholar

[10] SGTE Substance, Thermodynamic Data-Base SSUB3.

Google Scholar