Periodic Pattern Formation in Metal-Ceramic Reactions

Abstract:

Formation of diffusion zone morphologies periodic in time and space during metalceramic reactions is considered as a manifestation of the Kirkendall effect. In a diffusion-controlled interaction, the Kirkendall marker plane can bifurcate, which is attributed to diverging vacancies fluxes in the reaction zone. When the Kirkendall plane is present in a phase layer, it attracts in situproduced inclusions of “secondary-formed phase”, which, in turn, can result in a highly patterned microstructure.

• Periodical: Advances in Science and Technology (Volume 46)
• Pages: 136-145
• DOI: https://doi.org/10.4028/www.scientific.net/AST.46.136
• Online since: October 2006
• Authors: A.A. Kodentsov, F.J.J. van Loo
• Keywords: Kirkendall Effect, Metal-Ceramic Reaction, Periodic Pattern

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