Apatite Coating on Titanium Samples Obtained by Powder Metallurgy

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Titanium and its alloys are widely used as orthopedic and dental implant materials. However, they cannot bond with bone directly and promote new bone formation. It is desirable to provide a bone-bonding ability to Ti metal and its alloys. This ability can be achieved by surface modification such as chemical treatments. The aim of this study was to evaluate in SBF the apatite-forming ability of Ti subjected to different pre-treatments. Titanium laminated and samples Ti obtained by powder metallurgy were compared. The pretreatments studied were the alkali-treated; alkali and heat-treated; acid and alkali-treated; alkali-CaCl2-heat and hot water treatment. The groups were soaking in SBF for 1, 3, 6 and 9 days in equipment with constant agitation at 36.5°C. The obtained coatings were analyzed by diffuse reflectance spectroscopy on the infrared (DRIFT) and scanning electron microscopy (SEM). The apatite formation was present in all groups; however, the apatite-coating was more effective in samples obtained by powder metallurgy.

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28-33

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September 2012

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[1] X.Y. Liu, K.C. Paul, C.X. Ding, Surface modification of titanium, titanium alloys, and related materials for biomedical applications, Mater. Sci. Eng. R 47 (2004) 49–121.

DOI: 10.1016/j.mser.2004.11.001

Google Scholar

[2] W.Q. Yan, T. Nakamura, K. Kawanabe, S. Nishigochi, M. Oka, T. Kokubo, Apatite layer-coated titanium for use as bone bonding implants, Biomaterials 18 (1997) 1185-1190.

DOI: 10.1016/s0142-9612(97)00057-4

Google Scholar

[3] S. Sobieszczyk, Surface modifications of Ti and its alloys, Adv. Mater Sci. 10 (2010) 29-41.

Google Scholar

[4] B. Feng, J.Y. Chen, S.K. Qi, L. He, J.Z. Zhao, X.D. Zhang, Carbonate apatite coating on titanium induced rapidly by precalcification. Biomaterials 23 (2002) 173-179.

DOI: 10.1016/s0142-9612(01)00093-x

Google Scholar

[5] T. Kokubo, H. Takadama, How useful is SBF in predicting in vivo bone bioactivity? Biomaterials 27 (2006) 2907-2915.

DOI: 10.1016/j.biomaterials.2006.01.017

Google Scholar

[6] M. Bohner, J. Lemaitre. Can bioactivity be tested in vitro with SBF solution? Biomaterials 30 (2009) 2175-2179.

DOI: 10.1016/j.biomaterials.2009.01.008

Google Scholar

[7] S. Nishiguchi, H. Kato, H. Fujita, M. Oka, H-M. Kim, T. Kokubo, T. Nakamura, Titanium metals form direct bonding to bone after alkali and heat treatments, Biomaterials 22 (2001) 2525-2533.

DOI: 10.1016/s0142-9612(00)00443-9

Google Scholar

[8] T. Miyazaki, H-M. Kim, T. Kokubo, C. Ohtsuki, H. Kato, T. Nakamura, Mechanism of bonelike apatite formation on bioactive tantalum metal in a simulated body fluid, Biomaterials 23 (2002) 827-832.

DOI: 10.1016/s0142-9612(01)00188-0

Google Scholar

[9] T. Kokubo, Design of bioactive bone substitutes based on biomineralization process, Mater. Sci. Eng. C 25 (2005) 97-104.

DOI: 10.1016/j.msec.2005.01.002

Google Scholar

[10] D.K. Pattanayak, S. Yamaguchi, T. Matsushita, T. Kokubo, Effect of heat treatments on apatite-forming ability of NaOH- and HCl-treated titanium metal, J Mater. Sci.: Mater. Med. 22 (2011) 273-278.

DOI: 10.1007/s10856-010-4218-y

Google Scholar

[11] F.A. Müller, M.C. Bottino, L. Müller, V.A.R. Henriques, U. Lohbauer, A.H.A. Bressiani, J.C. Bressiani, In vitro apatite formation on chemically treated (P/M) Ti-13Nb-13Zr, Dental Mater. (2007), doi: 10. 1016/j. dental. 2007. 02. 005.

DOI: 10.1016/j.dental.2007.02.005

Google Scholar

[12] T. Kizuki, H. Takadama, T. Matsushita, T. Nakamura, T. Kokubo, Preparation of bioactive Ti metal surface enriched with calcium ions by chemical treatments, Acta Biomater. (20100, doi: 10. 1016/j. actbio. 2010. 01. 007.

DOI: 10.1016/j.actbio.2010.01.007

Google Scholar

[13] E.C.S. Rigo, A.O. Boschi, M. Yoshimoto, S. Allegrini Jr., B. Konig Jr., M.J. Carbonari, Evaluation in vitro and in vivo of biomimetic hydroxyapatite coated on titanium dental implants. Mater. Sci. Eng. C (2004) 647-651.

DOI: 10.1016/j.msec.2004.08.044

Google Scholar