Long-Term, Cyclic Oxidation Behaviour of Alumina- and Chromia-Forming Alloys

Abstract:

The oxidation resistance behaviour of a number of surface-treated FeCrAl commercial alloys and some model alloys of well-defined composition, incorporating a range of reactive elements in trace amounts, has been studied under thermal cyclic conditions in air with and without additions of water vapour. Additions of reactive elements such as Zr, La, Y, Hf modify the oxidation resistance behaviour of FeCrAl-alloys by improving the scale adherence and consequently may extend the lifetime of FeCrAl steels. The presence of the water vapour can affect oxidation in a number of different ways. Our results may indicate that high content of water vapour can cause the lives of such alloys to be decreased. This work forms part of a larger European-funded project to evaluate physical properties, microstructural features, oxidation/corrosion resistance and lifetime improvement. The correlation between alloy parameters and lifetime; as well as the modeling of oxide scale behaviour as function of cycling conditions is also studied.

• Periodical: Defect and Diffusion Forum (Volumes 237-240)
• Pages: 1107-1114
• DOI: https://doi.org/10.4028/www.scientific.net/DDF.237-240.1107
• Online since: April 2005
• Authors: Renata Bachorczyk Nagy, Richard J. Fordham
• Keywords: Aluminium Enrichment, Coating, Corrosion Resistance, FeCrAl Steels, Oxidation Resistance

References

[1] K. Messaoudi, A.M. Huntz, B. Lesage, Mat. Sci. Eng., Vol. A247 (1998), p.248.

[2] F.H. Stott, Materials Science Forum, Vol. 251-254 (1997), p.19.

[3] S. Zhao, J. Zhang, D. Weng, X. Wu, Surface and Coatings Techn., Vol. 167 (2003), p.97.

[4] L. MarJchal, B. Lesage, A.M. Huntz, R. Molins, Oxidation of metals, Vol. 60 (2003), p.1.

[5] W.J. Quadakkers, M.J. Bennett, Mat. Sci. Techn., Vol. 10 (1994), p.126.

[6] D.R. Siegler, Oxidation of Metals, Vol. 32 (1989), p.337.

[7] P.Y. Hou, K. Prhssner, D.H. Fairbrother, J.G. Roberts, K.B. Alexander, Scripta Materialia, Vol. 40 (1999), p.241.

[8] W.J. Quadakkers, A. Elschner, H. Holzbrecher, K. Schmidt, W. Speier, H. Nickel, Microchimica Acta, Vol. 107 (1990), p.659.

[9] Z. Liu, W. Gao, Y. He, Oxidation of Metals, Vol. 53 (2000), p.341.

[10] D.P. Whittle, J. Stringer, Philosophical Transactions of the Royal Society in London, Vol. A295 (1980), p.309.

[11] B.A. Pint, A.J. Garratt-Reed, L.W. Hobbs, Materials at High Temp., Vol. 13 (1995), p.3.

[12] D. Naumenko, V. Kochubey, J. Le-Coze, L. Niewolak, L. Singheiser, W.J. Quadakkers, MatJriaux and Techniques, Vol. 7-8-9 (2003), p.63.

DOI: 10.1051/mattech/200391070063

[13] B.A. Pint, Oxidation of Metals, Vol. 45 (1996), p.1.

[14] I. Kvernes, M. Oliveira, P. Kofstad, Corros. Sci., Vol. 17 (1977), p.237.

[15] H. Buscail, S. Heinze, Ph. Dufour, J.P. Larpin, Oxid. Met., Vol. 47 (1997), p.445.

[16] J.L. Smialek, Met. Trans., Vol. 22A (1991), p.739.

[17] D.R. Singler, Oxid. Met., Vol. 40 (1993), p.555.

[18] R. Janakiraman, G.H. Meier, F.S. Pettit, European Federation of Corrosion Publications, Vol. 27 (1999), p.38.