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HomeDefect and Diffusion ForumDefect and Diffusion Forum Vols. 258-260Mössbauer Investigations of Grain-Boundary...

Mössbauer Investigations of Grain-Boundary Diffusion and Segregation

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Abstract:

Possibilities of grain-boundary diffusion and segregation studies using nuclear gammaresonance spectroscopy (NGR) are considered. It is shown that the results of the Mössbauer investigations testify the necessity to specify the classical Fisher’s model of grain-boundary diffusion, and a possible way of such specification is suggested. It is demonstrated that investigation of grain boundaries using emission Mössbauer spectroscopy appreciably supplement the information obtained from the diffusion profiles analysis. In particular, Mössbauer investigations make it possible to evaluate directly the grain-boundary segregation factor, to determine the grain-boundary diffusion mechanism, to estimate the rate of the diffusant pumping from a grain boundary core into the bulk, etc.

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Diffusion in Solids and Liquids, DSL-2006 I

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Defect and Diffusion Forum (Volumes 258-260)

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497-508

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https://doi.org/10.4028/www.scientific.net/DDF.258-260.497

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Online since:

October 2006

Authors:

Vladimir V. Popov

Keywords:

Emission Mössbauer Spectroscopy, Grain Boundary, Grain Boundary Diffusion, Segregation

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© 2006 Trans Tech Publications Ltd. All Rights Reserved

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[1] I. Kaur, Y. Mishin and W. Gust: Fundamentals of grain and interface boundary diffusion (Wiley, Chichester 1995).

[2] V.N. Kaigorodov and S.M. Klotsman: Phys. Rev. B. Vol. 49 (1994), p.9374.

[3] S.M. Klotsman, V.N. Kaigorodov, M.I. Kurkin and V.V. Dyakin: Interface Science. Vol. 8 (2000), p.323.

DOI: 10.1023/a:1008723627168

[4] B.S. Bokshtein, Y.B. Voitkovsky, A.A. Zhuhovitsky and G.N. Pautkina: Fizika Tverdogo Tela (Solid State Physics) (in Russian), Vol. 10 (1968), p.3699.

[5] V.N. Kaigorodov and S.M. Klotsman: Letters to JETF (in Russian). Vol. 28 (1978), p.386.

[6] S.M. Klotsman, V.N. Kaigorodov, M.I. Kurkin, A.V. Ermakov, V.K. Rudenko, A.N. Timofeev and N.I. Timofeev: Phys. Met. Metallogr. Vol. 93 (2002), p.349.

[7] S.M. Klotsman, V.N. Kaigorodov, A.V. Ermakov, V.K. Rudenko and N.I. Timofeev: Phys. Met. Metallogr. Vol. 93 (2002), p.575.

[8] V.N. Kaigorodov, V.V. Popov, E.N. Popova, T.N. Pavlov and S.V. Efremova: J. Phase Equilibria and Diffusion. Vol. 26 (2005), p.510.

DOI: 10.1361/154770305x66646

[9] J.C. Fisher: J. Appl. Phys. Vol. 22 (1951), p.74.

[10] M.C. Dudarev, V. V, Dyakin, V.N. Kaigorodov, S.M. Klotsman, and M.I. Kurkin: Fizika Metallov i Metallovedenie (in Russian). Vol. 79 (1995), p.136.

[11] M.I. Kurkin, S.M. Klotsman and V. V, Dyakin: Fizika Metallov i Metallovedenie (in Russian). Vol. 81 (1996), p.16.

[12] S.M. Klotsman, M.I. Kurkin, V.N. Kaigorodov and V. V, Dyakin: Fizika Metallov i Metallovedenie (in Russian). Vol. 82 (1996), p.136.

[13] V.N. Kaigorodov, S.M. Klotsman, M.I. Kurkin, V. V, Dyakin and D.V. Jerebtsov: Phys. Met. Metallogr. Vol. 84 (1997), p.277.

[14] V.N. Kaigorodov, S.M. Klotsman, M.I. Kurkin, V. V, Dyakin and D.V. Jerebtsov: Phys. Met. Metallogr. Vol. 85 (1998), p.137.

[15] V.N. Kaigorodov, S.M. Klotsman and D.V. Jerebtsov: Phys. Met. Metallogr. Vol. 86 (1998), p.277.

[16] V.N. Kaigorodov, S.M. Klotsman, M.I. Kurkin, V. V, Dyakin and D.V. Jerebtsov: Phys. Met. Metallogr. Vol. 86 (1998), p.386.

[17] A. Atkihson and R.I. Teylor: Phil. Mag. Vol. 43 (1981), p.979.

[18] J. Sommer and C. Herzig: J. Appl. Phys. Vol. 72 (1992), p.2758.

[19] G.N. Belozersky. Mössbauer spectroscopy as a method of investigation of surfaces. (in Russian). Moscow: Energoizdat, 1990, p.351.

[20] V.I. Goldansky and R.H. Herber. Chemical Application of Mössbauer Spectroscopy (in Russian) Moscow: Mir, 1970, 502 p.

[21] S.M. Klotsman, S.V. Osetrov, A.N. Timofeev: Physical Review. Vol. 46 (1992), p.2831.

[22] О. Askill: Phys. Stat. Sol. V. 9 (1965), p. K167.

[23] V.V. Kondratev, I.S. Trachtenberg: Phys. Stat. Sol. (b). Vol. 171 (1992), p.303.

[24] L. Klinger, E. Rabkin: Acta Mater. Vol. 47 (1999), p.725.

[25] G. Martin, D.A. Blackburn and Y. Adda: Phys. Status Solidi. Vol. 23 (1967), p.223.

[26] Peterson N.L.: Int. Met. Reviews. Vol. 28 (1983), p.85.

[27] B.S. Bokshtein, A.B. Yaroslavtsev: Diffusion of atoms and ions in solids. (in Russian). Moscow: MISIS (2005), 362 p.

[28] M.R. Sorensen, Y. Mishin, A.F. Voter: Physical Review B. Vol. 62 (2000), p.3658.

[29] S.M. Klotsman, V.N. Kaigorodov, A.V. Ermakov and V.K. Rudenko: Phys. Met. Metallogr. Vol. 95 (2003), p.79.