Defect and Diffusion Forum Vols. 319-320

Abstract: The bulk diffusion of homovalent non-magnetic atomic probes (APs) from the IVB group of the periodic table of elements (PTE) – Ti and Zr in tungsten single crystals was investigated by sec-tioning, using secondary ion mass spectrometry (SIMS). The Arrhenius dependences had the fol-lowing parameters: DWTi - (D0)WTi = (3.00.4 ) x 10-4 m2s-1, enthalpy QWTi = (576 ± 9) kJ/mole; DWZr - (D0)WZr = (2.3  0.6) x 10-4 m2s-1, QWZr = (561 9) kJ/mole. The measured parameters (D0,Q)WTi,Zr of diffusion of Ti and Zr atomic probes (APs) in W are in accord with the empirical correlation: the diffusion coefficients of the substitutional APs coincide with the self-diffusion coefficients in W at (Tm)W – its melting temperature. Enthalpies QWTi,Zr,Hf of the volume diffusion of homovalent non-magnetic APs of the IVB group of periodic table of elements (PTE) - Ti, Zr and Hf increase with the decrease of relaxation volumes of the complexes «vacancy-IVBAP» in W lattice. The energies (E)WvacIVBAP of elastic relaxation of the complexes «vacancy-IVBAP» in W lattice were estimated. Electron contributions EDN to the energies EWvacIVBAP of interaction of the point defects in complexes «vacancy-IVBAP» increase relative to value EWvacIIIBAP of interac-tion of the point defects in complexes «vacancy-IIIBAP» with the growth of d-electrons number in comparison with the complexes «vacancy-IIIBAP».

Abstract: Severe plastic deformation (friction, compression shear, filing or rolling) of Hadfield steel leads to the growth of the internal effective field on 57Fe cores, removal of the magnetic degeneracy in spectra, and the extension of the paraprocess up to room temperature. The observed change of the magnetic characteristics is explained by the deformation-induced redistribution of carbon and short-range ordering of carbon and manganese. Since the magnetic degeneracy is removed in the Hadfield steel upon deformation, it is possible to consider a mechanism of magnetic precipitation hardening, which is realized in local magnetically ordered regions of the structure containing Mn-C pairs.

Abstract: Miniature specimen techniques viz. small-punch tests (SPT) have been carried out at room temperature in order to correlate the microstructural degradation of 2.25Cr-1Mo steel with that of SPT parameters. Microstructural degradation of this steel has been introduced as a result of thermal ageing corresponding to Larson-Miller parameters (LMP) values of 33,012, 35,402, 37,846 and 38,374. SPT parameters viz. total area and area under the region of plastic instability of the load-displacement curve have been found to decrease with an increase in LMP values. A strength parameter viz. UTS obtained using uniaxial tensile tests has also been found to decrease with an increase in LMP values. The results indicated that miniature specimen techniques viz. small-punch test could be successfully used to assess the degradation of microstructures in 2.25Cr-1Mo steel generated due to their exposure to high temperatures.

Abstract: Positron annihilation lifetime (PAL) is one of the most important nuclear techniques used in material science. Electrical measurements are also used in material science. Samples of 25 % deformation have been used for these studies. Both positron annihilation lifetime and electrical measurements were used to determined the activation energy of migration the dislocation in 7075 alloy. The isothermal annealing measurements were performed at 643, 663, 683 and 703 K. The activation energy of migration the dislocation are obtained as 1.35 ± 0.16 eV and 1.25 ± 0.05 eV for positron annihilation lifetime and electrical techniques respectively.

Abstract: In this paper, the application of photoacoustic methods to study thermal properties of Al-Li alloy is described. The photoacoustic measurements are carried out for thermal properties on Al-Li alloy and studied for various thicknesses. The theoretical basis for quantitative measurements is discussed together with the advantages and limitations of these methods as compared with conventional measurements. Applications to spectroscopic and depth-profile analysis and also to thermal property measurements in Al-Li samples heat-treated at 755K per hour and annealed at 505K are discussed. The results are compared with literature values, and discussed.

Abstract: A comprehensive and systematic study using PALS technique, Vickers hardness test and electrical LCR meter were undertaken to follow property development during the recently promoted interrupted ageing treatment for 2024 aluminum alloy. In this work, solution heat treatments at different temperatures were performed in aircraft materials 2024 aluminum alloy. This work describes the development of the dependence of mechanical, electrical properties of 2024 Al-alloys on heat treatment to characterize microstructural changes during heat treatment. PALS, mechanical and electrical testing will be used to measure the features of the material as a function of time for each ageing temperatures.

Abstract: Cu-4% mixed-powder consisting of rough copper powder and graphite powder was separately mechanical alloyed by high-energy ball milling. The phases and micrograph of these powders were determined by X-ray diffraction and scanning electron microscopy (SEM). The results show an increase in the lattice parameter of copper with milling times, up to a saturation value of about 24h; There was an absence of graphite reflections from X-ray diffractograms after longer milling times.

Abstract: In this study, metal composite feed stocks were prepared and test samples were produced by powder injection molding and Multiple Live-Feed Molding (MLFM) devices to investigate the effects of fiber content and macro-shear on the fiber fracture. Fiber-length was measured using an image processing system. The results showed that the fiber volume content increased fiber fracture by 9% and viscosity showed 10% increase in fiber fracture. Samples produced by MLFM devices showed a 1% higher fiber fracture compared to the test bars produced by injection molding. Tensile strength of composites was calculated using fiber contents and fiber length. Considerable increase in tensile strength was noted for metal composites with fiber length above a critical length.

Abstract: Available information on the composition and methods of production for particulate reinforced metal matrix composites (PRMMCs) for wear resistant applications is reviewed. In general, PRMMCs exhibit better wear resistance compared to its unreinforced counterparts. Nevertheless, under specified conditions, the wear performance of PRMMCs is similar to or lower than its respective alloy. Conflicting results were found among investigators with regards to different tribological parameters used in their investigations. A general framework was developed by identifying three parameters that affect the effectiveness of wear mechanisms model; fabrication method, types and characteristics of reinforcement and wear testing apparatus.

Abstract: Ceramic-ceramic composites are used around the world in demanding thermal, structural and electrical insulating applications. The present study aims to develop Alumina-Silica sand nanoparticles composites through powder processing route. Effect of amount of silica sand nanoparticles on the composite properties at different sintering temperatures was studied. Composites with 5, 10, 15 and 20 wt.% of silica sand nanoparticles were developed and sintered at 1300, 1400 and 1500 oC. It was observed that the incorporation of silica sand nanoparticles enhanced the hardness and sintered density of the composites. FESEM and EDS analysis evidenced the proposed liquid phase sintering, mullite and spinel formation mechanisms are primary cause of the composites mechanical properties improvement.