Positron Annihilation in TaN Thin Sputtering Films Prepared with Various N2 Partial Pressures

Article Preview

Abstract:

Tantalum nitride (TaN) thin films were deposited using magnetron sputtering method under different N2/Ar ratio condition. Slow positron beam was used to analyze the microstructure of those films. The results show that the films which deposited at low N2/Ar flow ratio contain more vacancy-like defects, and the corresponding S parameter is relatively large. The sheet resistance measurement displays that ohms-per-square greatly increase with increased N2/Ar ratio. And the reasons could be related to nonstoichiometry-induced vacancies and lattice distortions.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

237-240

Citation:

Online since:

March 2017

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2016 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] S. Mardani, H. Norström, U. Smith, J. Olsson, S. Zhang, Influence of tantalum/tantalum nitride barriers and caps on the high-temperature properties of copper metallization for wide-band gap applications, Microelectronic Engineering 137 (2015).

DOI: 10.1016/j.mee.2015.01.023

Google Scholar

[2] J. C. Tsao, C. P. Liu, H. C. Fang, Y. L. Wang, How tantalum proceeds phase change on tantalum nitride underlayer with sequential Ar plasma treatment, Mater. Chem. Phys. 137 (2013) 689–693.

DOI: 10.1016/j.matchemphys.2012.09.053

Google Scholar

[3] M. Eldrup. Positron Methods for the Study of Defects in Bulk Materials. Journal de Physique IV Colloque, 05 (1995) C1-93.

DOI: 10.1051/jp4:1995111

Google Scholar

[4] A. van Veen, H. Schut, M. Clement, J. M. M. de Nijs, A. Kruseman, M. R. IJpma, Appl. Surf. Sci. 85 (1995) 216.

DOI: 10.1016/0169-4332(94)00334-3

Google Scholar

[5] W. H. Lee, J. C. Lin, C. P. Lee, Characterization of tantalum nitride films deposited by reactive sputtering of Ta in N2/Ar gas mixtures, Mater. Chem. Phys. 68. 1 (2001) 266-271.

DOI: 10.1016/s0254-0584(00)00370-9

Google Scholar

[6] S. Thiel, C. W. Schneider, L. Fitting Kourkoutis, D. A. Muller, N. Reyren, A. D. Caviglia, S. Gariglio, J. -M. Triscone, J. Mannhart, Electron Scattering at Dislocations in LaAlO3/SrTiO3 Interfaces, Phys. Rev. Lett. 102 (2009) 046809.

DOI: 10.1103/physrevlett.102.046809

Google Scholar

[7] P. Y. Huang, C. S. Ruiz-Vargas, A. M. van der Zande, W. S. Whitney, M. P. Levendorf, J. W. Kevek, S. Garg, J. S. Alden, C. J. Hustedt, Y. Zhu, J. Park, P. L. McEuen, D. A. Muller, Grains and grain boundaries in single-layer graphene atomic patchwork quilts, Nature 469 (2011).

DOI: 10.1038/nature09718

Google Scholar