Thermodynamics of FeS-PbS-In₂S₃ and Properties of Intermediate Phases

Abstract:

The thermodynamic analysis and the X-ray Phase Analysis (XPA) of the FeS–PbS–In₂S₃ system were carried out. It is shown that along with the triple phases of MIn₂S₄ (M – Fe, Pb) and Pb₆In₆S₂₁, the Fe_1.5Pb_5.5In₁₀S₂₂ phase also participates in the triangulation of the system. The standard thermodynamic functions for the formation of MIn₂S₄ (M-Fe, Pb), Pb₆In₆S₂₁ and Fe_1.5Pb_5.5In₁₀S₂₂ are estimated. An isothermal section of the FeS–PbS–In₂S₃ system at 298 K is constructed. It is shown that the activation energy of the impurity level located in the band gap of Fe_1.5Pb_5.5In₁₀S₂₂ is equal to 0.19 eV.

• Periodical: Defect and Diffusion Forum (Volume 385)
• Pages: 175-181
• DOI: https://doi.org/10.4028/www.scientific.net/DDF.385.175
• Online since: July 2018
• Authors: MirSalim M. Asadov, Solmaz N. Mustafaeva, Ulviya A. Hasanova, Faiq M. Mamedov, Ozbak M. Aliev, Kazimir I. Yanushkevich, Sergey A. Nikitov, Esmira S. Kuli-Zade
• Keywords: Chalcogenide Compounds, Electrical Properties, FeS–PbS–In₂S₃, Thermodynamics

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