Synthesis of Composite Materials Based Eggshell Reinforced with Silver Nanoparticles for Possible Biomedical Applications

Abstract:

This research synthesized a composite ceramic material base CaCO₃/Al₂O₃, CERMET, with possible biomedical applications. Eggshell was used as raw material to obtain CaCO_3, and it was reinforced with silver nanoparticles to improve the structural and mechanical properties of the ceramic system. The addition of silver nanoparticles promotes the formation of two phases. The first is a continuous phase called a matrix formed of CaAl₂O₄ (calcium aluminate). The second is a dispersed phase known as reinforcement made up of silver nanoparticles. The composite ceramics were synthesized using the solid-state synthesis technique from a chemical mixture of CaCO₃ and Al₂O₃ powders in the following chemical ratio: 49.5% CaCO₃ + 50.5% Al₂O₃, with silver nanoparticles added at different percentages (1%, 5%, 10%, 15%). The powder mixture was made in a high-energy mill for homogenization. After that, the mixture was compressed into cylindrical samples for their consolidation by sintering in a high-temperature muffle with a controlled atmosphere, using heating ramps. The sintered samples were characterized by X-ray diffraction, optical microscopy, scanning electron microscopy, and microhardness, including fracture toughness studies. In addition, the Archimedes method determined the sintered samples' density. The results showed a clear relation between the mechanical properties of the CaAl₂O₄ ceramic base and the incorporated silver nanoparticles since these increased as the percentage of silver nanoparticles increased. In addition, it was observed that the porosity of the samples could be controlled, making the composite material suitable for biomedical applications.

• Periodical: Defect and Diffusion Forum (Volume 439)
• Pages: 115-126
• DOI: https://doi.org/10.4028/p-fmgQY0
• Online since: February 2025
• Authors: Alejandra Linares Duarte*, Enrique Hernández Sánchez, José Guadalupe Miranda Hernández, Yesenia Sánchez Fuentes, Jonathan Jorge Ruíz Domínguez
• Keywords: Biomaterials, Bone Tissue, Ceramic Synthesis, Cermet, Sintering

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