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Effect of Nature of Surfactant on the Formation of β-Ag2Se Nanoparticles and Optical Properties of β-Ag2Se and ZnS/β-Ag2Se Nanocomposite

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Abstract:

Surfactant assisted synthetic route was followed to prepare silver selenide (β-Ag2Se) nanoparticles. The effect of three different surfactants viz., Triton X100, SDS and CTAB in the formation of silver selenide nanoparticles had been examined. Pure and crystalline β-Ag2Se nanophase was obtained in the presence of Triton X100 and SDS. However, the presence of CTAB leads to metallic silver formation. Nano Composite of β-Ag2Se and ZnS was fabricated in the presence of glycine as a molecular linker. The products were characterized by different techniques such as XRD, FT-IR, SEM and TEM. Room temperature photoluminescence spectrum of the ZnS/ β-Ag2Se nanocomposite exhibited two emission peaks at around 286 nm and 392 nm with enhanced intensity (lex = 250 nm).

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Journal of Nano Research Vol. 30 View Preview

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Journal of Nano Research (Volume 30)

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96-105

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https://doi.org/10.4028/www.scientific.net/JNanoR.30.96

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Online since:

March 2015

Authors:

V. Andal*, G. Buvaneswari

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Chemical Preparation, Electron Microscopy, Optical Property, Semiconductor, X-Ray Diffraction

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