On the Formation of Martensite in Low-Carbon Alloy Steel Wire Rod for Welding Applications during Slow Continuous Cooling

Abstract:

Relevance of the work. One of the key challenges currently faced by manufacturers of steel wire rod for welding applications worldwide is achieving maximum plasticity in the metal before delivery to hardware plants. This need arises due to the ongoing technological advancements in hardware plants and the integration of modern equipment capable of producing wire at high drawing speeds with significant degrees of unit deformation. Such processes demand high-quality raw materials (wire rod). Another crucial aspect is ensuring a high-quality surface for the welding wire, free from microcracks and hard inclusions. These defects can negatively impact the welding process by increasing metal spatter, causing electric arc instability, and leading to critical defects in welded joints, such as cavities and cracks. Rational microstructural design is a key principle in producing highly plastic wire rod for the efficient manufacturing of solid-section welding wire from low-carbon alloy steels. The presence of hard components (such as martensite, bainite, or their mixtures) in the wire rod’s structure is undesirable, as they increase the risk of metal failure during intensive cold deformation by drawing. Minimizing these hard phases remains an urgent scientific and practical challenge. The aim of the study is to determine the mechanism of martensite grains formation during slow cooling of low-carbon alloy steel grade CrMoV1Si wire rod, used for producing welding wire, from the austenitization temperature to room temperature. Material and methodology. The material used in this study was steel with the chemical composition (in wt.%) 0.08C–1.30Mn–0.54Si–1.06Cr–0.54Mo–0.24V–Fe_(balance). The samples were subjected to thermal cycles using an automated Gleeble 3800 thermal deformation simulation system. The thermal cycle involved heating the samples to the temperature required for complete austenitization, holding them at this temperature, and then continuously cooling at controlled rates of 0.20, 0.10, and 0.05 °C/s to room temperature. Metallographic analysis was conducted using an optical microscope and a scanning electron microscope. The hardness of individual structural components was measured using a microhardness tester following the standard method. The chemical composition of the phases was determined by energy-dispersive X-ray spectroscopy and Auger electron spectroscopy. Results. The study established an anomalous increase in the volume fraction of austenite shear transformation products in CrMoV1Si steel after continuous slow cooling at rates of 0.20–0.05 °C/s, at the same time, martensite had a relatively high carbon content (up to 1.6 wt.%). The authors attribute this microstructural evolution to dynamic changes in the chemical composition of individual phases during cooling, primarily due to the partitioning of carbon and other alloying elements between the α and γ phases, as confirmed experimentally. Based on the obtained results, a mechanism has been proposed for the formation of high-carbon martensite grains in low-carbon alloy steel wire rod during slow cooling from the austenitization temperature to room temperature.

• Periodical: Key Engineering Materials (Volume 1041)
• Pages: 3-9
• DOI: https://doi.org/10.4028/p-sW6lDI
• Online since: February 2026
• Authors: Eduard Parusov, Ihor Chuiko*, Serhii Bobyr, Eduard Oliinyk, Viktor Zhukov
• Keywords: Chemical Composition, Martensite, Microstructure, Partitioning, Welding Steel

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