Sustainable Electrochemical Machining of Additively Manufactured Nitinol with Deep Eutectic Solvents

Article Preview

Abstract:

Additively manufactured Nitinol components often exhibit rough surfaces and defects that affect functional performance. This study investigates the feasibility of electropolishing Nitinol in a deep eutectic solvent (ethaline). Linear sweep voltammetry was used to identify anodic potentials suitable for controlled dissolution, and electropolishing was performed at selected potentials. Surface evolution was analysed by SEM, EDX, optical microscopy, and confocal microscopy. Electropolishing in ethaline effectively reduced surface scratches and produced more homogeneous surfaces without altering alloy composition. Higher applied potentials (12.5 V) resulted in complete removal of surface scratches and visually homogeneous surfaces, whereas lower potentials (6 V) mainly reduced the visibility of surface scratches. Compared to conventional inorganic electrolytes, the process exhibits a lower dissolution rate, offering a safer and more controllable approach.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

175-181

Online since:

April 2026

Export:

Share:

* - Corresponding Author

[1] K. Otsuka, C.M. Wayman, Shape memory materials, Cambridge university press, 1999.

Google Scholar

[2] T.W. Duerig, A.R. Pelton, Ti-Ni shape memory alloys, (n.d.).

Google Scholar

[3] K. Otsuka, X. Ren, Physical metallurgy of Ti–Ni-based shape memory alloys, Prog. Mater. Sci. 50 (2005) 511–678.

DOI: 10.1016/j.pmatsci.2004.10.001

Google Scholar

[4] T.C. Dzogbewu, D.J. de Beer, Additive manufacturing of NiTi shape memory alloy and its industrial applications, Heliyon 10 (2024) e23369.

DOI: 10.1016/j.heliyon.2023.e23369

Google Scholar

[5] S. Mei, J. Wang, Z. Li, B. Ding, S. Li, X. Chen, W. Zhao, Y. Zhang, X. Zhang, Z. Cui, P. Fu, X. Pang, M. Liu, 4D printing of polyamide 1212 based shape memory thermoplastic polyamide elastomers by selective laser sintering, J. Manuf. Process. 92 (2023) 157–164.

DOI: 10.1016/j.jmapro.2023.02.033

Google Scholar

[6] A. Jahadakbar, M. Nematollahi, K. Safaei, P. Bayati, G. Giri, H. Dabbaghi, D. Dean, M. Elahinia, Design, Modeling, Additive Manufacturing, and Polishing of Stiffness-Modulated Porous Nitinol Bone Fixation Plates Followed by Thermomechanical and Composition Analysis, Metals (Basel). 10 (2020) 151.

DOI: 10.3390/met10010151

Google Scholar

[7] S.L. Sing, J. An, W.Y. Yeong, F.E. Wiria, Laser and electron-beam powder-bed additive manufacturing of metallic implants: A review on processes, materials and designs, Journal of Orthopaedic Research 34 (2016) 369–385.

DOI: 10.1002/jor.23075

Google Scholar

[8] U.S. Kim, J.W. Park, High-Quality Surface Finishing of Industrial Three-Dimensional Metal Additive Manufacturing Using Electrochemical Polishing, International Journal of Precision Engineering and Manufacturing-Green Technology 6 (2019) 11–21.

DOI: 10.1007/s40684-019-00019-2

Google Scholar

[9] G. Mani, D. Porter, K. Grove, S. Collins, A. Ornberg, R. Shulfer, Surface finishing of Nitinol for implantable medical devices: A review, J. Biomed. Mater. Res. B Appl. Biomater. 110 (2022) 2763–2778.

DOI: 10.1002/jbm.b.35112

Google Scholar

[10] A. Kityk, V. Pavlik, M. Hnatko, Green electropolishing using choline chloride-based deep eutectic solvents: A review, J. Mol. Liq. 392 (2023) 123519.

DOI: 10.1016/j.molliq.2023.123519

Google Scholar

[11] A. Kityk, V. Protsenko, F. Danilov, V. Pavlik, M. Hnatko, J. Šoltýs, Enhancement of the surface characteristics of Ti-based biomedical alloy by electropolishing in environmentally friendly deep eutectic solvent (Ethaline), Colloids Surf. A Physicochem. Eng. Asp. 613 (2021) 126125.

DOI: 10.1016/j.colsurfa.2020.126125

Google Scholar

[12] W.O. Karim, A.P. Abbott, S. Cihangir, K.S. Ryder, Electropolishing of nickel and cobalt in deep eutectic solvents, Transactions of the IMF 96 (2018) 200–205.

DOI: 10.1080/00202967.2018.1470400

Google Scholar