Composite Material Based on Gold Mine Tailings and Metakaolin Produced through Geopolymerization

Article Preview

Abstract:

This research studies the manufacture of a composite material based on gold mine tailings and metakaolin as a novel construction material through a geopolymer process. Geopolymers, derived from aluminosilicate-rich mining waste, offer a promising alternative to traditional construction materials by mitigating environmental pollution and reducing production costs. Different combinations and solution contents were used, with sodium hydroxide as the alkaline activator at different molarities and temperatures of 70°C and 110°C. To determine the optimal mixture, an indirect tensile test was performed to determine the optimization factor (Fopt), which resulted in a mixture of 60% tailings and 40% metakaolin in a 24% solution at a concentration of 6 molar and 110°C. Using the optimal mixture, brick tiles were manufactured, which were tested under simple compression, achieving a resistance of 6MPa; the specimens were also tested using the flexural strength test, obtaining a result of 11MPa, thus complying with the Ecuadorian standard for their use as a construction material.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

153-158

Citation:

Online since:

July 2026

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2026 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] X. He et al., "Mine tailings-based geopolymers: A comprehensive review," Ceram. Int., vol. 48, no. 17, p.24192–24212, 2022.

DOI: 10.1016/j.ceramint.2022.05.345

Google Scholar

[2] D. Komljenovic, L. Stojanovic, V. Malbasic, and A. Lukic, "A resilience-based approach in managing the closure and abandonment of large mine tailing ponds," Int. J. Min. Sci. Technol., vol. 30, no. 5, p.737–746, 2020.

DOI: 10.1016/j.ijmst.2020.05.007

Google Scholar

[3] G. Bumanis, R. M. Novais, J. Carvalheiras, D. Bajare, and J. A. Labrincha, "Metals removal from aqueous solutions by tailored porous waste-based granulated alkali-activated materials," Appl. Clay Sci., vol. 179, no. May, p.105147, 2019.

DOI: 10.1016/j.clay.2019.105147

Google Scholar

[4] E. M. Opiso, C. B. Tabelin, C. V. Maestre, J. P. J. Aseniero, I. Park, and M. Villacorte-Tabelin, "Synthesis and characterization of coal fly ash and palm oil fuel ash modified artisanal and small-scale gold mine (ASGM) tailings based geopolymer using sugar mill lime sludge as Ca-based activator," Heliyon, vol. 7, no. 4, p. e06654, 2021.

DOI: 10.1016/j.heliyon.2021.e06654

Google Scholar

[5] R. S. Krishna et al., "A review on developments of environmentally friendly geopolymer technology," Materialia, vol. 20, no. August, p.101212, 2021.

DOI: 10.1016/j.mtla.2021.101212

Google Scholar

[6] J. Davidovits, "Geopolymers: Ceramic-like inorganic polymers," J. Ceram. Sci. Technol., vol. 8, no. 3, p.335–350, 2017.

Google Scholar

[7] P. Duxson, A. Fernández-Jiménez, J. L. Provis, G. C. Lukey, A. Palomo, and J. S. J. van Deventer, "Geopolymer technology: the current state of the art," J. Mater. Sci., vol. 42, no. 9, p.2917–2933, May 2007.

DOI: 10.1007/s10853-006-0637-z

Google Scholar

[8] G. Palma, H. Bolaños, R. Huamani, C. Clements, and A. Hedayat, "Optimization of Geopolymers for Sustainable Management of Mine Tailings: Impact on Mechanical, Microstructural, and Toxicological Properties," Minerals, vol. 14, no. 10, 2024.

DOI: 10.3390/min14100997

Google Scholar

[9] V. J. García, C. O. Márquez, A. R. Zúñiga-Suárez, B. C. Zuñiga-Torres, and L. J. Villalta-Granda, "Brazilian Test of Concrete Specimens Subjected to Different Loading Geometries: Review and New Insights," Int. J. Concr. Struct. Mater., vol. 11, no. 2, p.343–363, 2017.

DOI: 10.1007/s40069-017-0194-7

Google Scholar

[10] M. S. Muñiz-Villarreal et al., "The effect of temperature on the geopolymerization process of a metakaolin-based geopolymer," Mater. Lett., vol. 65, no. 6, p.995–998, 2011.

DOI: 10.1016/j.matlet.2010.12.049

Google Scholar

[11] Q. Mohsen and N. Y. Mostafa, "Investigating the possibility of utilizing low kaolinitic clays in production of geopolymer bricks," Ceram. - Silikaty, vol. 54, no. 2, p.160–168, 2010.

Google Scholar

[12] M. Zhang et al., "Reaction kinetics of red mud-fly ash based geopolymers: Effects of curing temperature on chemical bonding, porosity, and mechanical strength," Cem. Concr. Compos., vol. 93, p.175–185, 2018.

DOI: 10.1016/j.cemconcomp.2018.07.008

Google Scholar

[13] N. INEN 297, "Ladrillos cerámicos. Requisitos," Inst. Ecuatoriano Norm., vol. 297, p.7, 1978.

Google Scholar