Synthesis and Characterization of (Gd, Y)-Doped Ceria Electrolytes for Solid Oxide Fuel Cell

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Abstract:

Ceria electrolytes co-doped with Gd3+ and Y3+ (Ce0.8Gd0.2-xYxO1.9) were synthesized by GNP. The crystal structures, lattice parameters and crystallite sizes were determined by XRD. The morphology of the powders was observed by TEM. Sintered at 1250oC for 4 h, all die-pressed ceria pellets achieved densities higher than 95% of theoretical values. The ionic conductivities were measured using AC impedance technique and Ce0.8Gd0.05Y0.15O1.9 showed a higher ionic conductivity than those of other compositions at 500-750oC, indicating that it is an attractive electrolyte material for IT-SOFC.

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Key Engineering Materials (Volumes 336-338)

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395-397

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April 2007

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© 2007 Trans Tech Publications Ltd. All Rights Reserved

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