Fabrication and Electrical Conductivity of a YSZ-NiCr Cermet

Article Preview

Abstract:

YSZ-NiCr powder was synthesized by gel-reduction process at 850°C for 2 h. YSZ-NiCr cermet was fabricated by hot-press sintering at 1350°C for 1 h. The powder has a mean particle size of 42 nm and the sintered specimen has a fine and homogeneous microstructure with a mean crystalline size of 0.2 &m. The conductivity has a tendency to decrease with increasing temperature. This behavior can be accounted for that there are two conduction paths through the cermet, an electronic path through the Ni/Cr metal phase and an ionic path through the ZrO2-Y2O3 phase. The objective of this work is to give a possible improvement in the cermet anode of SOFC.

You might also be interested in these eBooks

Info:

Periodical:

Key Engineering Materials (Volumes 336-338)

Pages:

384-386

Citation:

Online since:

April 2007

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2007 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] M. Marinšek, K. Zupan and J. Maček: J. Power Sources Vol. 86 (2000), p.383.

Google Scholar

[2] J-H. Lee, H. Moon, H. -W. Lee, et al.: Solid State Ionics Vol. 148 (2002), p.15.

Google Scholar

[3] M. Mori, Y. Hiei and H. Itoh: Solid State Ionics Vol. 160 (2003), p.1.

Google Scholar

[4] T. Matsushima, H. Ohrui and T. Hirai: Solid State Ionics Vol. 111 (1998), p.315.

Google Scholar

[5] S.T. Aruna, M. Muthuraman and K.C. Patil: Solid State Ionics Vol. 111 (1998), p.45.

Google Scholar

[6] H. Koide, Y. Someya and T. Yoshida: Solid State Ionics Vol. 132 (2000), p.253.

Google Scholar

[7] S.P. Jiang, P.J. Callus and S.P.S. Badwal: Solid State Ionics Vol. 132 (2000), p.1.

Google Scholar

[8] D. Kek and P. Panjan: J. Euro. Ceram. Soc. Vol. 21 (2001), p.1861.

Google Scholar

[9] N. Bamba, Y. -H. Choa, T. Sekino, K. Niihara: Solid State Ionics Vol. 111 (1998), p.171.

Google Scholar

[10] H. Kondo and T. Sekino: Mater. Lett. Vol. 57 (2003), p.1624.

Google Scholar

[11] K. Jensen, S. Primdahl, I. Chorkendorff, et al.: Solid State Ionics Vol. 144 (2001), p.197.

Google Scholar

[12] D. Sciti and A. Bellosi: J. Euro. Ceram. Soc. Vol. 21 (2001), p.45.

Google Scholar

[13] J.Q. Li, X.R. Zeng, Tang J N and Xiao P: J. Euro. Ceram. Soc. Vol. 23 (2003), p.1847.

Google Scholar

[14] D. Simwonis, H. Thülen, F.J. Dias, et al.: J. Mater. Proc. Technol. Vol. 92 (1999), p.107.

Google Scholar

[15] G.Q. Shao, M. Pan, S.C. Jia, et al.: Chinese Invention Pat No. ZL 94 1 20137. 6. Dec. 29, (1994).

Google Scholar

[16] A.S. Carrillo, T. Tagawa and S. Goto: Mater. Res. Bull. Vol. 36 (2001), p.1017.

Google Scholar

[17] D. Sporn, J. GroBmann and A. Kaiser: Nanostruc. Mater. Vol. 6 (1995), p.329.

Google Scholar

[18] S. -J. Kim, W. Lee and W. -J. Lee: J. Mater. Res. Vol. 16 (2001), p.3621.

Google Scholar

[19] T. Kawada, N. Sakai and H. Yokokawa: Solid State Ionics Vol. 53 (1992), p.418.

Google Scholar

[20] A. Tsoga, A. Naoumidis and P. Nikolopoulos: Acta Mater. Vol. 44 (1996), p.3679.

Google Scholar

[21] G.Q. Shao, J.R. Xie, X.L. Duan, et al.: Chinese Invention Pat No. ZL 02 1 15711. 1. Apr. 12, (2002).

Google Scholar

[22] G.Q. Shao, H. Cai, J.R. Xie, et al.: Mater. Lett. Vol. 57 (2003), p.3287. Fig. 5. Conductivity vs. temperature of YSZ-NiCr cermet.

Google Scholar