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Paper Title Page
Abstract: Barium modified lead zirconate titanate (PBZT) thin films were grown epitaxially on
Pt/Ti/SiO2/Si substrates by radio-frequency magnetron sputtering deposition and characterized by X-ray
diffraction and scanning electron microscopy. Depending on the growth condition, a wide variation of
crystal structure and morphology was evolved in PBZT thin films. The formation of phase structure and
pyrochlore phase was strongly dependent on the oxygen partial pressure and re-evaporation of lead from
the films during the deposition. Perovskite films were obtained by optimizing the deposition conditions
and analyzed by the ferroelectric hysteresis (P~E).
173
Abstract: A series of powders of (Ba1-xLa2x/3)(Ti1-xNb4x/5)O3 (0.05≤x≤0.3) have been synthesized by
solid-state reaction route, and the effects of the dopants on the microstructure of BaTiO3 were investigated
by XRD, SEM, HTEM and EDS in the BaTiO3-La2O3-Nb2O5 ternary system. It was found that the
secondary titanium-rich phase occurred for x ≤ 0.1, while Ba3La3Ti5Nb5O30 yields as secondary phase for
x ≥ 0.2. In the whole range of 0.05 ≤ x ≤ 0.3, the crystal structure of BaTiO3 solid solutions is cubic system.
There are two substitution modes in the system: the substitution mode of La ions dissolved into Ba sites is
significant for x ≤ 0.2, but the substitution mode of Nb ions dissolved into Ti sites is significant for x>0.2.
TEM observation and EDS analysis revealed that the concentration gradient of Nb existed and La almost
distributed homogeneously in a grain. Thus, the dielectric materials composed of La-Nb-codoped BT are
not fitted to form the core-shell structure for the higher dopants.
177
Abstract: Lead-free (1-x) Bi1/2Na1/2TiO3-xKNbO3 (x=0, 0.01, 0.02, 0.04, 0.05 0.06, 0.10) piezoelectric
ceramics were prepared by conventional ceramics fabrication technique. The results of x-ray diffraction
(XRD) show that these ceramics possess pure perovskite structures with a symmetry transition from
rhombohedral to cubic at about x = 0.05. The piezoelectric properties of these ceramics were reported and
found to reach extreme values at x = 0.04 with d33 up to 113pC/N and kp up to 22%. The temperature
dependence of dielectric constant and dielectric loss of these ceramics were also investigated. The Curie
temperature and depolarization temperature dropped with the increase of KNbO3 amount.
184
Abstract: In this study, ferroelectric materials with Bi-layered structure BaBi2Nb2O9 with excess x
wt% Bi2O3 (x=0, 1.5, and 3) are investigated as the main compositions, and the sintering is proceeded
from 1000oC~1100oC. The effect of Bi2O3 on the morphologies, crystal structure, and dielectric
characteristics of BaBi2Nb2O9 ceramics is developed with the aid of SEM, X-ray diffraction, and
dielectric-temperature curves. Dielectric properties are investigated in the temperature of 25oC~
465oC at frequency 10KHz~1MHz. It is found that sintering temperature and Bi2O3 content has no
apparent influence on the Curie temperatures, but they have large influence on the maximum
dielectric constants.
188
Abstract: The microwave properties of (Ca1-xBax)[(Li1/3Nb2/3)0.95Zr0.15]O3+δ(0.0≤x≤0.2, CBLNZ)
ceramics were investigated. A single phase with orthorhombic perovskite structure was obtained at x =
0.0 − 0.025. Both the εr and Qf value firstly increased with increasing Ba2+ content, and then began to
decrease at x = 0.025. The τf value increased from −9.4 ppm/°C at x=0.0 to 18ppm/°C at x=0.2, which
could be explained by the decrease of B-site bond valence in perovskite structure.
196
Abstract: Lead-free piezoelectric ceramics lithium sodium potassium niobate (LixNayK1-x-y)NbO3
(LNKN100x/100y) have been synthesized by a conventional solid state process. The effects of MnO2
addition on the properties of (LixNayK1-x-y)NbO3(x=0.06, y=0.5)(LNKN6/50) ceramics were investigated.
It was found that a morphotropic phase boundary (MPB) between orthorhombic and tetragonal phases is
in the composition range 0.05
199
Abstract: Orthorhombic perovskite-type K0.5Na0.5NbO3 (KNN) films on Pt/Ti/SiO2/Si substrates were
prepared by sol-gel processing. The morphology of the films was characterized using SEM and AFM. The
KNN films with a total thickness of about 0.5 micron had relatively dense and uniform microstructure.
The ferroelectricity of the KNN films was confirmed by polarization-electric field (P-E) hysteresis loop.
203
Abstract: (Na0.5Bi0.5)TiO3 (BNT) system ceramics are considered to be an excellent candidate for leadfree
piezoelectric ceramics. In this paper, (1–x)Na0.5Bi0.5TiO3-xBaTiO3 (x = 0.03 ~ 0.10) was synthesized
by conventional mixed-oxide technique. The powders were calcined at 950oC for 2 h and the pressed
disks were sintered at 1145oC for 2 h in air atmosphere. The phase structure was investigated by X-ray
diffraction technique (XRD). It is revealed that the morphotropic phase boundary (MPB) lies in a narrow
composition range of x=0.05–0.08 but not a unique composition (x = 0.055 or 0.06) as shown before [1-4].
The microstructures of the ceramics were investigated by scanning electron microscopic. In addition, the
piezoelectric and dielectric properties of this system were also investigated. It was indicated that both the
piezoelectric and dielectric properties are better with the compositions lie near the tetragonal phase within
the MPB than that whose compositions lie near the rhombohedral phase.
206