Degradation of Micro-Arc Oxidation Coatings on the Surface of Magnesium Alloy under NaCl Droplet

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Abstract:

With scanning Kelvin probe and microscopy technique, the degradation process of the micro-arc oxidation (MAO) treated magnesium alloy was investigated under a 3% NaCl droplet. Because of the unique two-layer structure of the MAO specimen, the droplet penetrated in and spread through the external loose layer during the initial several minutes. Subsequently, with the increase of time, only a thin layer of electrolyte was left on the surface of the MAO specimen. During the entire corrosion process, the potential exhibited a valley type distribution, only the width of potential valley increased with time. Based on above observations, a model was proposed for describing the contamination mechanism of MAO treated magnesium alloy under droplet.

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Key Engineering Materials (Volumes 480-481)

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437-442

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June 2011

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© 2011 Trans Tech Publications Ltd. All Rights Reserved

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[1] B.L. Mordike, T. Ebert, Magnesium properties-applications-potential, Materials Science and Engineering, 2001, A302: 37.

Google Scholar

[2] A. Stalmann,W. Sebastian, H. Friedrich, S. Schumann and K. Dröder, Properties and processing of magnesium wrought products for automotive applications, Advanced Engineering Materials, 2001, 3(12): 969.

DOI: 10.1002/1527-2648(200112)3:12<969::aid-adem969>3.0.co;2-9

Google Scholar

[3] F.H. Froes, D. Eliezer, The science, technology and application of magnesium, J Mine Metals and Mater Soc, 1998, 5(9): 30.

Google Scholar

[4] J.E. Gray, B. Luan, Protective coatings on magnesium and its alloys-a critical review, Journal of Alloys and Compounds, 2002, 336: 88.

DOI: 10.1016/s0925-8388(01)01899-0

Google Scholar

[5] R. LindstrÖm, L.G. Johansson, G. E. Thompson, Corrosion of magnesium in humid air, Corrosion Science 2004, 46: 1141–1158.

DOI: 10.1016/j.corsci.2003.09.010

Google Scholar

[6] M. Jönsson, D. Persson, The influence of the microstructure on the atmospheric corrosion behaviour of magnesium alloys AZ91D and AM50, Corrosion Science, 2010, 52 (3): 1077-1085.

DOI: 10.1016/j.corsci.2009.11.036

Google Scholar

[7] M. Jönsson, D. Persson, C. Leygraf, Atmospheric corrosion of field-exposed magnesium alloy AZ91D, Corrosion Science, 2008, 50 (5): 1406-1413.

DOI: 10.1016/j.corsci.2007.12.005

Google Scholar

[8] H. Hoche, H. Scheerer, D. Probst, et al., Plasma anodisation as an environmental harmless method for the corrosion protection of magnesium alloys, Surface and Coatings Technology, 2003, 174 –175: 1002.

DOI: 10.1016/s0257-8972(03)00655-8

Google Scholar

[9] N.M. Chigrinova, V.E. Chigrinov, and A.A. Kukharev, Formation of coatings by anodic microarc oxidation and their operation in thermally-stressed assemblies, Powder Metallurgy and Metal Ceramics, 2001, 40(5-6): 213.

Google Scholar

[10] L. R. Krishna, K.R.C. Somaraju, G. Sundararajan, The tribological performance of ultra-hard ceramic composite coatings obtained through microarc oxidation, Surface and Coatings Technology, 2003, 163 –164: 484.

DOI: 10.1016/s0257-8972(02)00646-1

Google Scholar

[11] H. Hoche, H. Scheerer, D. Probst, et al., Development of a plasma surface treatment for magnesium alloys to ensure sufficient wear and corrosion resistance, Surface and Coatings Technology, 2003, 174-175: 1018.

DOI: 10.1016/s0257-8972(03)00634-0

Google Scholar

[12] A.L. Yerokhin, A. Shatrov, V. Samsonov, et al., Fatigue properties of Keronite coatings on a magnesium alloy, Surface and Coatings Technology, 2004, 182: 78.

DOI: 10.1016/s0257-8972(03)00877-6

Google Scholar

[13] L. Shi, Y. Xu, K. Li, Z. Yao, S. Wu, Effect of additives on structure and corrosion resistance of ceramic coatings on Mg–Li alloy by micro-arc oxidation, Current Applied Physics, 2010, 10 (3): 719-723.

DOI: 10.1016/j.cap.2009.10.011

Google Scholar