Comparative Study of Thermal Degradation Behavior of High Char Yield Phenolic Resin and Commercial Resin

Zhi Qin Chen; Wei Jun Zeng; Yang Fei Chen; Wen Kui Li; Hong Bo Liu

doi:10.4028/www.scientific.net/KEM.500.94

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HomeKey Engineering MaterialsKey Engineering Materials Vol. 500Comparative Study of Thermal Degradation Behavior...

Comparative Study of Thermal Degradation Behavior of High Char Yield Phenolic Resin and Commercial Resin

Abstract:

The thermal degradation behavior of high char yield phenolic resin (PF_1.2) synthesized by us was investigated, in comparison with that of commercial resin (PF_1.5), using TGA and ¹³C-NMR techniques. It was found that the degradation process of PF_1.2 behaved very similar to that of PF_1.5 during heat treatment up to 700 °C under N₂ atmosphere, but resulted in a somewhat different extent of some specific reactions. That was, although the reactions occurring up to 700 °C were dominated by crosslinking and/or polyaromatization, fewer methyl bonds from breaking of methylene bridges were formed in PF_1.2 than in PF_1.5. As a consequence, a higher char yield of 73.8% of PF_1.2 than that of PF_1.5 (57.5%) up to 700 °C under N₂ atmosphere was attached, with better thermal properties.

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Periodical:

Key Engineering Materials (Volume 500)

Pages:

94-97

DOI:

https://doi.org/10.4028/www.scientific.net/KEM.500.94

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Online since:

January 2012

Authors:

Zhi Qin Chen, Wei Jun Zeng, Yang Fei Chen, Wen Kui Li, Hong Bo Liu

Keywords:

¹³C-NMR, Phenolic Resin, TGA, Thermal Degradation

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References

[1] L. Jia-Min, M. Chen-Chi: Polym. Degrad. Stab. Vol. 69 (2000), p.229.

Google Scholar

[2] A.H. Basta, M.Z. Sefain, N.A. El-Wakil: Polym. Plast. Technol. Vol. 33 (1994), p.265.

Google Scholar

[3] L. Costa, L. R. Montelera, G. Camino, E. D. Weil, E. M. Pearce: Polym. Degrad. Stab. Vol. 56 (1997), p.23.

Google Scholar

[4] C.P. Reghunadhan Nair, R.L. Bindu, K.N. Ninan: Polym. Degrad. Stab. Vol. 73 (2001), p.251.

Google Scholar

[5] E. FITZER and W. SCHAFER: Carbon, Vol. 8 (1970), p.353.

Google Scholar

[6] Young Jeon Kim, Myung Il Kim, Chang Hun Yun, et al: J. Colloid Interface Sci. Vol. 274 (2004), p.555.

Google Scholar

[7] KRYSTYNA ROCZNIAK, TERESA BIERNACKA and MACIEJ: J. Appl. Polym. Sci. Vol. 28 (1983), p.531.

Google Scholar

[8] L．B．Manfredi，O. de la Osa, N. Galego Fernandez, et al: Polymer Vol. 40 (1999) 867-3875.

Google Scholar

[9] Kimberly, A. Trick and Tony E. Saliba: Carbon, Vol. 33 (1995), p.1509.

Google Scholar

[10] K. A. Trick, T. E. Saliba and S.S. Sandhu: Carbon, Vol. 35 (1997), p.393.

Google Scholar

[11] K. Quchi and H. Hond: Fuel, Vol. 38 (1959), p.429.

Google Scholar

[12] WILLIAM M, JACKSON and ROBER T. COKLEY: J. Appl. Polym. Sci. Vol. 8 (1964), p.2163.

Google Scholar

[13] J.A. Parker and E.L. Winkler: NASA TR R-276, Ames. Research Center (1967).

Google Scholar

[14] C. Morterra, M.J.D. Low: Carbon, Vol. 23 (1985), p.525.

Google Scholar

[15] Marie-Florence Grenier-Loustalot, Stbphane Larroque and Philippe Grenier: Polymer, Vol. 37 (1996), p.639.

Google Scholar

[16] Yang-Fei Chen, Zhi-Qin Chen, Hong-Bo Liu: Acta Polymerica Sinica Vol. 5 (2008), p.399.

Google Scholar

[17] Jinqi Lu. Doctor of philosophy's dissertation, Mississippi state university: Synthesis if pheolic resin anines and silid-state NMR of phenolic resins in nose rocket motors (1998).

Google Scholar