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HomeKey Engineering MaterialsKey Engineering Materials Vol. 500Influence of F/P on Structure and Thermal Property...

Influence of F/P on Structure and Thermal Property of Phenolic Resin

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Abstract:

The influence of F/P on structure and thermal property of resin was studied. Six resins were synthesized with different molar ratios of F/P. These resins were cured by means of temperature and without catalyst. The characterization of the resin was done by Fourier transform infrared spectroscopy (FTIR), thermo gravimetric analysis (TGA) and differential thermo gravimetric analysis (DTG). From the thermal properties of fully cured resins, characteristic properties including pyrolysis temperature and char yield were obtained. A maximum in the benzene ring substitutions, methylene bridge and the result of the thermal properties allow us to say that the resin with F/P molar ratio 1.2 has the highest crosslinking density and highest char yield, over 73%.

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Periodical:

Key Engineering Materials (Volume 500)

Pages:

98-103

DOI:

https://doi.org/10.4028/www.scientific.net/KEM.500.98

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Online since:

January 2012

Authors:

Zhi Qin Chen, Wei Jun Zeng, Yang Fei Chen, Wen Kui Li, Hong Bo Liu

Keywords:

Char Yield, F/P, Phenolic Resin, Pyrolysis Temperature

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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[1] Knop A, Pilato LA: Phenolic resins Heidelberg, Springer (1985).

[2] Reghunadhan Nair C P, Bindu R L, Ninan K N: Polym. Degrad. Stab. Vol. 73 (2001), p.251.

[3] Golfarb, IJ, Lee CY-C, Arnold FE, Helminiak TE Park Ridge(NS), Noyes Data Corporation (1987).

[4] Moragues J, Relations Structure-Properties. Ph D Thesis, INSA, Lyon, Franch (1994).

[5] G. Astarloa Aierbe, J.M. Echeverría, M.D. Martin, et al: Polymer Vol. 41 (2000), p.6797.

[6] Young Jeon Kim, Myung I1 Kim, Chang Hun Yun, et al: J. Colloid Interface Sci. Vol. 274 (2004), p.556.

[7] KRYSTYNA ROCZNIAK, TERESA BIERNACKA and MACIEJ SKARZYNSKI: J. Appl. Polym. Sci. Vol. 28 (1983), p.541.

[8] Yang-Fei Chen, Zhi-Qin Chen, Hong-Bo Liu: Acta Polymerica Sinica Vol. 5 (2008), p.401.

[9] Marie-Florence, Grenier-Loustalot, Stephane Larroque, et al: Polymer Vol. 37 (1996), p.645.

[10] Grenier-Loustalot MF, Larroque S, Grenier P, et al: Polymer Vol. 37 (1996), p.955.

[11] Jones RT.: J. Polym. Sci. Vol. 21 (1985), p.1801.

[12] Cherng Chang, Juanita R. Tackett: Thermochim. Acta Vol. 192 (1991), pp.181-190.

[13] L. Costa, L.R. Montelera, G. Camino et al: Polym. Degrad. Stab. Vol. 56 (1997), p.23.

[14] C. Morterra, M.J.D. Low: Carbon Vol. 23 (1985), p.525.

[15] Yoram Cohen and Zeev Aizenshtat: J. Anal. Appl. Pyrolysis Vol. 22 (1992), p.153.

[16] WILLIAM M. JACKSON, ROBERT T. CONLEY: J. Appl. Polym. Sci. Vol. 8 (1964), p.2163.

[17] Drumm LF, Lebranc JR, In: Solomon DH, editor. Step Growth Polymerization. New York, Marcel Dekker, (1972).

[18] Vázquez A, Adabbo HE, Williams RJJ: Ind. Eng. Chem. Prod. Res. Dev. Vol. 23 (1984), p.375.

[19] Stockmayer NH: J. Chem. Phys. Vol. 11 (1943), p.45.