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HomeKey Engineering MaterialsKey Engineering Materials Vol. 508Orientation and Morphology of LiCoO2 Prepared by...

Orientation and Morphology of LiCoO₂ Prepared by Chemical Vapor Deposition on Al₂O₃ Single Crystal

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Abstract:

Lithium Cobaltate (LiCoO₂) Films Were Prepared on the (001), (110), (110) and (112) Planes of Al₂O₃ Single Crystals Substrates by Metal Organic Chemical Vapor Deposition, and the Phases, Orientated Textures and Surface Morphologies Were Examined. (001)-Oriented LiCoO₂ Films Were Obtained on (001) and (110) Al₂O₃ Substrates, while (018)- and (104)-Oriented LiCoO₂ Films Were Grown on (110) and (112) Al₂O₃ Substrate. Triangular and Elongated Rectangular Faceted Structures Were Directionally Aligned, and (001)- and (018)-Oriented Grains Were Epitaxially Grown on (001) and (110) Al₂O₃ Substrates. Randomly Arranged Polygonal Faceted Structures Were Observed in the (001)-Oriented Licoo2 Film on (110) Al₂O₃ Substrate, while Locally Inhomogeneous Grains Were Observed in the (104)-Oriented LiCoO₂ Film on (1_,12) Al₂O₃ Substrate.

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Periodical:

Key Engineering Materials (Volume 508)

Pages:

300-303

DOI:

https://doi.org/10.4028/www.scientific.net/KEM.508.300

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Online since:

March 2012

Authors:

Hirokazu Katsui, Yamashita Yuji, Takashi Goto

Keywords:

(001)-, (104)- and (018)-Oriented Textures, Epitaxial Growth, Faceted Structures, LiCoO₂, Metal Organic Chemical Vapor Deposition

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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