Preparation and Performance of Ni-YSZ/YSZ Co-Ceramic Using Multiple Gel-Tape Casting

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Abstract:

Use starch, corn meal and activated carbon as pore-making agent, Ni-YSZ/YSZ composite ceramic green body was prepared by multiple gel-tape casting with acryloyl ammonium-polyvinyl alcohol. The specimen was sintered at 1450°C for 4h, then reduced in hydrogen atmosphere at 800°C for 4h, Ni-YSZ/YSZ composite ceramic disk was obtained, the porosity, thermal expansion coefficient, electrical properties and microstructures of the specimen was tested. The results showed that the porosity of Ni-YSZ/YSZ composite ceramic disk reaches about 30% when use starch as pore-making agent, expansion coefficient is proportional to porosity, both of them reduced with the temperature increased. The YSZ is continued and compact with network structure, Ni particulates are well distributed in it, suitable for intermediate temperature solid oxide fuel cell anode materials. Image analysis of SEM micrograph showed that the structure is loose, porous, uniform and compact in Ni/YSZ/YSZ multi-layer composite ceramics, which meet the requirement of intermediate temperature SOFC.

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Key Engineering Materials (Volumes 512-515)

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1555-1558

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June 2012

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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[1] J. Will, A. Mitterdorfer and C. Kleinlogel, Fabrication of thin electrolytes for second-generation solid oxide full cells, Sol. Sta. Ion..131(2000)79-96.

Google Scholar

[2] T. Fukui, S. Ohara and M. Naito, Performance and stability of SOFC anode fabricated from NiO-YSZ composite particles, J.Power Sources. 110 (2002)91-95.

DOI: 10.1016/s0378-7753(02)00218-5

Google Scholar

[3] F. Snijkers, A. Wilde and S. Mullens, Aqueous tape casting of yttriastabilized zirconia using natural product binder, Eur. Cera. Soc.. 24 (2004)1107-1110.

DOI: 10.1016/s0955-2219(03)00388-1

Google Scholar

[4] J.G Li, K.N. Sun and J.R. Kong: Fabrication of Ni-YSZ/YSZ compound substrate membranes using tape casting method and performance measurements, Chem.Indu.Eng. Pro..27 (2008)135-138.

Google Scholar

[5] S.H Xie and J.Z Xiao, Development of fabrication methods for solid oxide fuel cell, Battery Bimonthly.34 (2004)59-61.

Google Scholar

[6] L.X He,T.L Wen and Z.Y lv, Research development on electrolyte membrane for ceramic fuel cells made by tape casting, J. Mater. Sci. Eng..15(1997)15-18.

Google Scholar

[7] I.A. Proctor, A. L. Hopkin and R. M. Ormerod. Development of anodes for direct electrocatalytic oxidation of methane in solid oxide fuel cells, Ionics. 9(2003) 3-4.

DOI: 10.1007/bf02375974

Google Scholar