Preparation and Properties of MgAl2O4-CaAl12O19 High Temperature Composite

Article Preview

Abstract:

The utilization of lightweight refractories plays an important role in reducing the energy consumption of industrial furnaces. In this paper, MgAl2O4-CaA112O19 high temperature composite was synthesized via solid state reaction using magnesite, dolomite and industrial alumina as raw materials. The influences of raw materials and reaction temperature on phase compositions and microstructure of the composite were investigated by XRD and SEM,respectively. The parameters to prepare MgAl2O4-CaA112O19 high temperature composite were optimized. The results show that the optimum reaction conditions for synthesizing MgAl2O4-CaA112O19 composite is the CA6/MA weight ratio of 2:3, and the reaction temperature of 1500°C for 4h. The CaA112O19 crystals showed laminated or plate-like structure, and the MgAl2O4 showed spherical morphology. The reaction temperature had little effect on the phase compositions of MA-CA6 composite in this experiment. The content of Al2O3 in the raw material affected the phase composition of MA-CA6 composite.With the increase of the CaA112O19 amount, the bending strength of the composite decreased.

You might also be interested in these eBooks

Info:

Periodical:

Key Engineering Materials (Volumes 512-515)

Pages:

617-620

Citation:

Online since:

June 2012

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Y. M. Liu, X. P. Yu, Comprehensive Development and Utilization of Dolomite, Yunnan Chemical Technology. 30(2003) 5-6.

Google Scholar

[2] X. Y. Zhang, Ways of Improving Utilization Level of Magnesite Resource in China, Conservation and Utilization of Mineral Resources. 4(2008)23-25.

Google Scholar

[3] M. Fuhrer, A. Hey, W. E. Lee, Microstructure evolution in self-forming spinel/Calcium Aluminate-bonded castable refractories, J Eur Ceram Soc. 18(1997) 813-820.

DOI: 10.1016/s0955-2219(97)00182-9

Google Scholar

[4] C. Q. Pei, G. Shi, Properties and Application of Novel Calcium Hexaluminate Insulating Refractory, Industrial Furnace. 29(2007) 45-49.

Google Scholar

[5] S. Yi, F. Wang, Effects of materials and synthesizing temperature on synthesized CA6, Refractories. 44(2010) 20-23

Google Scholar

[6] C. Dominguer, Microstructure development in calcium hexaluminate, J Eur Ceram Soc. 21(2001) 381-387.

Google Scholar