High Performance Porous Wave-Transmitting Silicon Nitride Ceramics by Gel-Casting Technique

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Porous wave transmitting Si3N4 ceramics have been of great interest and technological importance in aerospace area. In this paper, the high performance wave transmitting porous Si3N4 ceramics was prepared by gel-casting method, without any pore-former. The porosity was controlled by the solid content of the slurry and the sintering temperature. The flexural strength and dielectric properties of the material were determined by three bending method and a resonant cavity method. The relationship of the dielectric constant versus the sintering temperature was discussed, and the effect of porosity on dielectric properties was investigated also. As a result, the flexural strength of the porous Si3N4 is 40-200MPa with porosity of 67-45%, dielectric constant of 2.2-3.4 in the frequency of 8GHz at room temperature. With the increase of porosity, both the dielectric constant and dielectric loss decreased. This technique is considered to be a potentially useful method to fabricate the porous ceramics with complex shape.

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Key Engineering Materials (Volumes 512-515)

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869-872

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June 2012

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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[1] C Kawai, T Matsuura and A Yamakawa, Separation–permeation performance of porous Si3N4 ceramics composed of columnar β-Si3N4 grains as membrane filters for microfiltration, J Mater Sci. 34 (1999) 893-896.

Google Scholar

[2] H. J. Wang, J. L. Yu, J. Zhang, et. al, Preparation and properties of pressureless-sintered porous Si3N4, J Mater Sci. 45 (2010) 3671-3676.

DOI: 10.1007/s10853-010-4412-9

Google Scholar

[3] C. Kawai, A. Yamakawa, Effect of Porosity and Microstructure on the Strength of Si3N4: Designed Microstructure for High Strength, High Thermal Shock Resistance, and Facile Machining, J Am Ceram Soc. 80 (1997) 2705-2708.

DOI: 10.1111/j.1151-2916.1997.tb03179.x

Google Scholar

[4] Y. Xia, Y. P. Zeng and D. L. Jiang, Dielectric and mechanical properties of porous Si3N4 ceramics prepared via low temperature sintering, Ceram. Inter. 35 (2009) 1699-1703.

DOI: 10.1016/j.ceramint.2008.09.010

Google Scholar

[5] P. Sepulveda, J. G. P. Binner, Processing of Cellular Ceramics by Foaming and in situ Polymerisation of Organic Monomers, J. Eur. Ceram. Soc. 19 (1999) 2059-2066.

DOI: 10.1016/s0955-2219(99)00024-2

Google Scholar

[6] X. P. Fu, F. G. Qiu, X. J. Liu , L. P. Huang, Development of Reticulated Porous Ceramics by Two-step Centrifuging Crocessing, J. Inorg. Mater. 20 (2005) 1431-1437.

Google Scholar

[7] T. Fukasawa, Z. Y. Deng and M. Ando, Synthesis of Porous Silicon Nitride with Unidirectionally Aligned Channels Using Freeze-Drying Process, J. Am. Ceram. Soc. 85 (2002) 2151-2155.

DOI: 10.1111/j.1151-2916.2002.tb00426.x

Google Scholar

[8] Y. Zhang, H. J. Wang and Z. H. Jin, Preparation and Study of Porous Si3N4 Ceramics with High strength, Rare Metal. Mater. & Engin. 33 (2004) 655-658.

Google Scholar

[9] W. Zhang, H. J. Wang and Z. H. Jin, Preparation and Properties of Macroporous Silicon Nitride Ceramics by Gelcasting and Carbonthermal Reaction, J. Mater. Sci. Technol. 21 (2005) 894-898.

Google Scholar

[10] O. O. Omatete, M. A. Janney, R. A. Strehlow, Gelcsating a new ceramic forming process, Am. Ceram. Soc. Bull. 74 (1991) 1641-1649.

Google Scholar

[11] J. M. Tulliani, C. Bartuli and E. Bemporad, Preparation and mechanical characterization of dense and porous zirconia produced by gel casting with gelatin as a gelling agent, Ceram. Int. 35 (2009) 2481-2491.

DOI: 10.1016/j.ceramint.2009.02.017

Google Scholar

[12] J. K. Park, J. S. Lee, and S. I. Lee., Preparation of Porous Cordierite Using Gelcasting Method and its Feasibility as a Filter, J. Porous Mater. 9 (2002) 203-210.

Google Scholar

[13] W. Zhang, H. J. Wang and Z. H. Jin., Gel casting and properties of porous silicon carbide/silicon nitride composite ceramics, Mater. Lett. 59 (2005) 250-256.

DOI: 10.1016/j.matlet.2004.07.059

Google Scholar

[14] J. Yu, H. Wang, J. Zhang and D. Zhang, Gelcasting preparation of porous silicon nitride ceramics by adjusting the content of monomers, J. Sol-gel Sci. Technol. 53 (2010) 515-523.

DOI: 10.1007/s10971-009-2125-9

Google Scholar

[15] W. D. Kingery, H. K. Bowen and D. R. Uhlmann, Introduction of Ceramics,John Wiley and Sons Inc. (1976).

Google Scholar

[16] S. J. Penn, N. M. Alford, A. Templeton, X. Wang, M. Xu, M. Reece et al, Effect of Porosity and Grain Size on the Microwave Dielectric Properties of Sintered Alumina, J. Am. Ceram. Soc. 80 (1997) 1885-1888.

DOI: 10.1111/j.1151-2916.1997.tb03066.x

Google Scholar