Preparation at Low-Temperature and Characterization of TiO2 Film Used for Solar Cells

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In this work, nanocrystalline TiO2 powder was prepared by the sol-gel method via tetrabutyl titanate as raw material, non-ion surfactant TO8 as a template. Then the nanocrystalline TiO2 thin film electrodes which were coated on FTO glass substrates via the slurry consiting of TiO2 powder prepared by us and the trabutyl titanate precursor were successfully prepared by using a simple and convenient hydrothermal method at low temperature. The structure and morphology of powders and films were characterized by X-ray diffraction, scanning electric microscopy. The influence factors on the samples were discussed. The photoelectric properties of cells assembled by the films were measured. The results show that, at 25°C and under 1000W/m2 light intensity,open voltage is 708mV, Jsc is 14.648mA/cm2, fill factor is 53.788, the conversion efficiency is 5.5988%.

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205-208

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January 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] T. Kado, M. Yamaguchi, Y. Yamada, et al. Low Temperature Preparation of Nano-porous TiO2 Layers for Plastic Dye-sensitized Solar Cells, Chem. Lett., 15 (2003) 1056-1062.

DOI: 10.1246/cl.2003.1056

Google Scholar

[2] C. Longo, J. Freitas, M. A. DePaoli, Performance and Stability of TiO2/Dye Solar Cells Assembled with Flexible Electrodes and a Polymer Electrolyte, J. Photochem. Photobiol. A: Chem., 23 (2003) 33-40.

DOI: 10.1016/s1010-6030(03)00106-0

Google Scholar

[3] T. Yamaguchi, N. Tobe, D. Matsumoto, H. Arakawa, Highly Efficient Plastic Substrate Dye-sensitized Solar Cells using a Compression Method for Preparation of TiO2 Photoelectrodes, J. Chem. Commun., 18 (2007) 4767-4768.

DOI: 10.1039/b709911h

Google Scholar

[4] H. Lindstrom, A. Holmberg, E. Magnusson, et al., Optimization of Dye-sensitized Solar Cells Prepared by Compression Method, J. Nano. Lett., 125 (2002) 11-15.

Google Scholar

[5] D. S. Zhang, J. A. Downing, F. J. Knorr, et al., Room-temperature Preparation of Nanocrystalline TiO2 Films and the Influence of Surface Properties on Dye-sensitized Solar Energy Conversion, J. Phys Chem B., 110 (2006) 21890-21898.

DOI: 10.1021/jp0640880

Google Scholar

[6] J. Nemoto, M. Sakata, T. Hoshi, et al., All-plastic Dye-sensitized Solar Cell using a Polysaccharide Film Containing Excess Redox Electrolyte Solution, J. Electroanal Chem., 62 (2007) 23-40.

DOI: 10.1016/j.jelechem.2006.08.011

Google Scholar

[7] Y. Takeshi, T. Nobuyuki, et al. Highly Efficient Plastic Substrate Dye-sensitized Solar Cells using a Compression Method for Preparation of TiO2 Photoelectrodes, Chem Commun., 32 (2007) 4767-4783.

DOI: 10.1039/b709911h

Google Scholar