Effects of Al2O3 on the Structure and Properties of Aluminoborosilicate Glasses

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Abstract:

In alkaline earth aluminoborosilicate glasses CaO-B2O3-Al2O3-SiO2, the changes of structure and properties caused by variations in the ratio Al2O3/B2O3 were investigated. The structure was investigated by Fourier transform infrared spectroscopy. The dielectric constant and tangent loss were measured at 1 MHz. Chemical durability was evaluated by weight losses of glass samples after immersion in HCl and NaOH solutions. The results indicated that the fraction of four-coordinated boron atoms (N4), chemical durability and dielectric properties increased with increasing Al2O3/B2O3 replacements.

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154-157

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January 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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