The Effects of RE and Si on the Thickness and Cross Section Morphology of Zn-6Al-3Mg Alloy Coating

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Hot-dip galvanized steels are widely used in modern industry. The corrosion resistance and formability of them are closely related to the thickness and cross section microstructure of the hot-dip coating. In this paper, the effects of Si and RE on the thickness of Zn-6Al-3Mg alloy coating (ZAM) were investigated. Steel sheets were coated by using an experimental hot-dip galvanizing simulator. The thickness and cross section microstructure of ZAM coating alloyed with different content of Si and RE were characterized by using optical microscope and SEM, and element distribution was study by EDS. The results demonstrated that the reaction between Al from the bath and Fe form the steel sheets was suppressed by the addition of 0.1 wt. % Si to the Zn-6Al-3Mg bath, and the addition of RE effectively decreased the thickness of coating by means of improving the flowing property of the zinc alloy bath. Under the combined effects of Si and RE, the thickness of Zn-6Al-3Mg alloy coating went down from 33 μm to 10.1 μm.

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Key Engineering Materials (Volumes 562-565)

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935-941

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July 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] L. J. Han, K. J. Do, O. J. Seok, P. S. Jeong, Effect of Al coating conditions on laser weldability of Al coated steel sheet, Trans. Nonferrous Met. Soc. China. 19 (2009) 946-951.

DOI: 10.1016/s1003-6326(08)60383-0

Google Scholar

[2] N.C. Hosking, M.A. Ström, P.H. Shipway, C.D. Rudd, Corrosion resistance of zinc– magnesium coated steel, Corros. Sci. 49 (2007) 3669-3695.

DOI: 10.1016/j.corsci.2007.03.032

Google Scholar

[3] T. Prosek, A. Nazarov, U. Bexell, D. Thierry, J. Serak, Corrosion mechanism of model zinc-magnesium alloys in atmospheric conditions, Corros. Sci. 50 (2008) 2216-2231.

DOI: 10.1016/j.corsci.2008.06.008

Google Scholar

[4] S. Schürz, G.H. Luckeneder, M. Fleischanderl, P. Mack, H. Gsaller, A.C. Kneissl, G. Mori, Chemistry of corrosion products on Zn-Al-Mg alloy coated steel, Corros. Sci. 52 (2010) 3271-3279.

DOI: 10.1016/j.corsci.2010.05.044

Google Scholar

[5] L. Suarez, F. Leysen, C. Masquelier, D. Warichet, Y. Houbaert, Effects of Mg additions on surface morphology and corrosion resistance of hot-dipped Zn coatings, DIFFUSION IN SOLIDS AND LIQUIDS III. 273-276 (2008) 300-305.

Google Scholar

[6] [Q.F. Zhang, B.J. Liu, J.Z. Huang, Modern continuous Hot-dip Galvanizing of Steel Strip, first ed., Metallurgical Industry Press, Beijing, 2007.

Google Scholar

[7] L. Zhu, Hot-dip Galvanizing of Steel, first ed., Chemical Industry Press, Beijing, 2006.

Google Scholar

[8] K. Honda, K. Ushioda, W. Yamada, Influence of Si Addition to the Coating Bath on the Growth of the Al-Fe Alloy Layer in Hot-dip Zn-Al-Mg Alloy-coated Steel Sheets, ISIJ Int. 51 (2001) 1895-1902.

DOI: 10.2355/isijinternational.51.1895

Google Scholar

[9] J. Elia , E. Petit, J.S. Lecomte, B. Gay, V. Pitchon, TEM STUDY OF THE INHIBITION LAYER OF COMMERCIAL HOT-DIP GALVANIZED STEELS, Ceram. Trans. 200 (2009) 131-142.

DOI: 10.1002/9780470444191.ch15

Google Scholar

[10] J.D. Culcasi, P.R. Seré, C.I. Elsner, A.R. Di Sarli, Control of the growth of zinc-iron phases in the hot-dip galvanizing process, Surf. Coat. Technol. 122 (1999) 21-23.

DOI: 10.1016/s0257-8972(99)00404-1

Google Scholar

[11] F. Rosalbino, E. Angelini, D. Macciò, A. Saccone, S. Delfino, Influence of rare earths addition on the corrosion behaviour of Zn–5%Al (Galfan) alloy in neutral aerated sodium sulphate solution, Electrochim. Acta, 52 (2007) 7107-7114.

DOI: 10.1016/j.electacta.2007.05.041

Google Scholar

[12] D. Yang, J.S. Chen, Q. Han, K.R. Liu, Effects of lanthanum addition on corrosion resistance of hot-dipped galvalume coating, J. Rare Earths, 27 (2009) 114-118.

DOI: 10.1016/s1002-0721(08)60203-3

Google Scholar

[13] S.R. Ying, Y.S. Yun W.X. Jie, X. Lian, H.C. Bao, Effects of rare earth on the corrosion- resisting performance of zinc-based alloy coatings, J. Rare Earths. 11 (1993) 32-35.

Google Scholar

[14] A. Amadeh, B. Pahlevani, S. Heshmati-Manesh, Effects of rare earth metal addition on surface morphology and corrosion resistance of hot-dipped zinc coatings, Corros. Sci. 44 (2002) 2321-2331.

DOI: 10.1016/s0010-938x(02)00043-4

Google Scholar

[15] G.F. Tu, S.W. Li, B. Gao, L. Hu, Q.L. Wen, W.X. Shi, Y. Hao and S.H. Yin, Patent CN 101838786. (2010)

Google Scholar

[16] B. Gao, S.W. Li, G.F. Tu, S.H. Yin, W.X. Shi, L. Hu and Y. Hao, Patent CN 101948990. (2010)

Google Scholar

[17] A.R. Marder, The metallurgy of zinc-coated steel, Prog. Mater. Sci. 45 (2000) 191-271.

Google Scholar

[18] F. Weinberg, M. Mager, L. Frederick, Segregation in Galfan hot dipped sheet steel, Can. Metall. Q. 29 (1990) 163-166.

DOI: 10.1179/cmq.1990.29.2.163

Google Scholar