Experimental Investigation of Microstructure and Piezoresistive Properties of Phosphorus-Doped Hydrogenated Nanocrystalline Silicon Thin Films Prepared by PECVD

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This paper presents an experimental investigation of microstructure and piezoresistive properties of phosphorus-doped hydrogenated nanocrystalline silicon (nc-Si:H) thin films. The phosphorus-doped nc-Si:H thin films (5% doping ratio of PH3 to SiH4) were deposited by plasma enhanced chemical vapor deposition (PECVD) technique. The microstructure and surface morphology of the deposited thin films was characterized and analyzed with Raman spectroscopy and atomic force microscopy (AFM), respectively. The piezoresistive properties of the deposited thin films were investigated with a designed four-point bending-based evaluation system. In addition, the influence of temperature on the piezoresistive properties of these thin films was evaluated with the temperature coefficient of resistance (TCR) measurements from room temperature up to 80°C. The experimental results show that phosphorus-doped nc-Si:H thin films prepared by PECVD technique are a two-phase material that constitutes of nanocrystalline silicon and amorphous silicon, and they present a granular structure composed of homogeneously scattered nanoclusters formed by nanocrystalline silicon grains (6nm). Moreover, phosphorus-doped nc-Si:H thin films exhibit negative GF at room temperature and show good thermal stability from room temperature up to 80°C, and the value of GF and TCR is about-31 and-509ppm/°C, respectively. These features could make phosphorus-doped nc-Si:H thin films act as a promising material for piezoresistive-based MEMS sensor.

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Key Engineering Materials (Volumes 609-610)

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208-217

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April 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] Li Z, Zhang XW and Han GR. Electrical and optical properties of boron-doped nanocrystalline silicon films deposited by PECVD. Phys. Status Solidi A 2010; 207: 144-148.

DOI: 10.1002/pssa.200925107

Google Scholar

[2] Kima IK, Limb JH and Yeom GY. Characteristics of hydrogenated silicon thin film deposited by RF-PECVD using He-SiH4 mixture. Vacuum 2011; 86: 82-86.

DOI: 10.1016/j.vacuum.2011.04.018

Google Scholar

[3] Amrani R, Benlekehal D, Baghdad R, et al. Low-temperature growth of nanocrystalline silicon films prepared by RF magnetron sputtering: Structural and optical studies. J. Non-Cryst. Solids 2008; 354: 2291-2295.

DOI: 10.1016/j.jnoncrysol.2007.10.044

Google Scholar

[4] Vygranenko Y, Fathi E, Sazonov A, et al. Nanocrystalline p-layer for a-Si: H p-i-n solar cells and photodiodes. Sol. Energy Mater. Sol. Cells 2010; 94: 1860-1863.

DOI: 10.1016/j.solmat.2010.06.044

Google Scholar

[5] Le Donne A, Binetti S, Isella G, et al. Structural characterization of nc-Si films grown by low-energy PECVD on different substrates. Appl. Surf. Sci. 2008; 254: 2804-2808.

DOI: 10.1016/j.apsusc.2007.10.025

Google Scholar

[6] Chowdhury A, Mukhopadhyay S and Ray S. Fabrication of low defect density nanocrystalline silicon absorber layer and its application in thin-film solar cell. Thin Solid Films 2008; 516: 6858-6862.

DOI: 10.1016/j.tsf.2007.12.048

Google Scholar

[7] Guo LQ, Ding JN, Yang JC, et al. Effects of high hydrogen dilution ratio on surface topography and mechanical properties of hydrogenated nanocrystalline silicon thin films. Thin Solid Films 2011; 519: 6039-6043.

DOI: 10.1016/j.tsf.2011.04.117

Google Scholar

[8] Cheng IC, Allen S and Wagner S. Evolution of nanocrystalline silicon thin film transistor channel layers. J. Non-Cryst. Solids 2004; 338: 720-724.

DOI: 10.1016/j.jnoncrysol.2004.03.076

Google Scholar

[9] Anutgan TA, Anutgan M, Atilgan I, et al. Large area uniformity of plasma grown hydrogenated nanocrystalline silicon and its application in TFTs. J. Non-Cryst. Solids 2010; 356: 1102-1108.

DOI: 10.1016/j.jnoncrysol.2010.04.012

Google Scholar

[10] Alpuim P, Andrade M and Sencadas V. Piezoresistive properties of nanocrystalline silicon thin films deposited on plastic substrates by hot-wire chemical vapor deposition. Thin Solid Films 2007; 515: 7658-7661.

DOI: 10.1016/j.tsf.2006.11.138

Google Scholar

[11] Alpuim P, Marins ES and Rocha PF. Ultra-sensitive shape sensor test structures based on piezoresistive doped nanocrystalline silicon. Vacuum 2009; 83: 1279-1282.

DOI: 10.1016/j.vacuum.2009.03.031

Google Scholar

[12] He YL, Liu H, Yu MB, et al. The structure characteristics and piezoresistance effect in hydrogenated nanocrystalline silicon films. Nanostructured Materials 1996; 7: 769-777.

DOI: 10.1016/s0965-9773(96)00052-9

Google Scholar

[13] Son JI, Shim JH and Cho NH. Effect of substrate temperature on the nanostructural and chemical features of nc-Si: H thin films prepared by PECVD. Curr. Appl. Phys. 2010; 10: S365-S368.

DOI: 10.1016/j.cap.2009.12.030

Google Scholar

[14] Gullanar MH, Zhang YH, Chen H, et al. Effect of phosphorus doping on the structural properties in nc-Si: H thin films. J. Cryst. Growth 2003; 256: 254-260.

DOI: 10.1016/s0022-0248(03)01371-x

Google Scholar

[15] Luo PQ, Zhou ZB, Li YJ, et al. Effects of deposition pressure on the microstructural and optoelectrical properties of B-doped hydrogenated nanocrystalline silicon (nc-Si : H) thin films grown by hot-wire chemical vapor deposition. Microelectron. J. 2008; 39: 12-19.

DOI: 10.1016/j.mejo.2007.10.019

Google Scholar

[16] Hu ZH, Liao XB, Diao HW, et al. Hydrogenated p-type nanocrystalline silicon in amorphous silicon solar cells. J. Non-Cryst. Solids 2006; 352: 1900-(1903).

DOI: 10.1016/j.jnoncrysol.2006.02.010

Google Scholar

[17] Seto JYW. Piezoresistive properties of polycrystalline silicon. J. Appl. Phys. 1976; 47: 4780-4783.

Google Scholar

[18] French PJ and Evens AGR. Piezoresistance in polysilicon and its applications to strain gauges. Solid-State Electronics 1989; 32: 1-10.

DOI: 10.1016/0038-1101(89)90041-5

Google Scholar

[19] Chen XY and Shen WZ. Electron localization and resonant tunneling in uniform nanocrystalline silicon quantum dot systems. Surf. Coat. Technol. 2005; 198: 30-35.

DOI: 10.1016/j.surfcoat.2004.10.057

Google Scholar

[20] Shi CZ, Liu XW and Chuai RY. Piezoresistive sensitivity, linearity and resistance time drift of polysilicon nanofilms with different depostion temperatures. Sensors 2009; 9: 1141-1166.

DOI: 10.3390/s90201141

Google Scholar

[21] Ding GQ, Shen WZ and Zheng MJ. Fabrication of highly ordered nanocrystalline Si: H nanodots for the application of nano device arrays. J. Cryst. Growth 2005; 283: 339-345.

DOI: 10.1016/j.jcrysgro.2005.06.052

Google Scholar

[22] Fraga MA, Furlan H, Massi M, et al. Effect of nitrogen doping on piezoresistive properties of a-SixCy thin film strain gauges. Microsyst. Technol. 2010; 16: 925-930.

DOI: 10.1007/s00542-010-1033-9

Google Scholar