Influence of (Bi0.5M0.5)TiO3 (M=Li, Na, K, Rb) Addition on the Curie Temperature and PTC Effect of BaTiO3-Based Ceramics

Article Preview

Abstract:

In order to investigate the influence of (Bi0.5M0.5)TiO3 (M=Li, Na, K, Rb) addition on the Curie temperature (Tc) and positive temperature coefficient (PTC) effect of BaTiO3-based ceramics, BaTiO3-(Bi0.5M0.5)TiO3 (M=Li, Na, K, Rb) solid solutions were prepared by a conventional solid sintering reaction using high-purity reagents. It was found that the Tc of the samples would vary with (Bi0.5M0.5)TiO3 of different alkali ions, in which BT-BKT ceramics had the highest value (about 148 °C). Moreover, the incorporation of alkali ions would influence the PTC effect of the sample, which can be defined by the resistivity jump with the ratio of maximum to minimum resistivity (ρmaxmin). Under the present conditions, the ρmaxmin of BT-BRT and BT-BLT ceramics were almost equal and higher than those of BT-BNT and BT-BKT ceramics.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

239-242

Citation:

Online since:

July 2016

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2016 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] T Shimada, K Touji, Y Katsuyama, et al., Lead free PTCR ceramics and its electrical properties, J. Eur. Ceram. Soc. 27 (2007) 3877–3882.

DOI: 10.1016/j.jeurceramsoc.2007.02.171

Google Scholar

[2] S L Leng, G R Li, L Y Zheng, et al., Influences of Ba/Ti ratios on the positive temperature coefficient of resistivity effect of Y-doped BaTiO3-(Bi0. 5Na0. 5)TiO3 ceramics, J. Am. Ceram. Soc. 94 (2011) 1340–1342.

DOI: 10.1111/j.1551-2916.2011.04506.x

Google Scholar

[3] O Saburi, Properties of semiconductive barium titanates, J. Phys. Soc. Jpn. 14 (1959) 1159–1174.

DOI: 10.1143/jpsj.14.1159

Google Scholar

[4] Y L Chen, S F Yang, PTCR effect in donor doped barium titanate: review of compositions, microstructures, processing and properties, Adv. Appl. Ceram. 110 (2011) 257-269.

DOI: 10.1179/1743676111y.0000000001

Google Scholar

[5] O I Prokpalo, A V Turlk, Point defects and electrical properties of ferroelectrics, Ferroelectrics 22 (1978) 749-751.

DOI: 10.1080/00150197808237388

Google Scholar

[6] H D Wu, Y P Pu, Z Wang, et al., Study of electrical and dielectric properties of Y2O3 doped Ba1−x(Bi0. 5Na0. 5)xTiO3 ceramics, Mater. Lett. 76 (2012) 222–225.

DOI: 10.1016/j.matlet.2012.02.105

Google Scholar

[7] H Takeda, Y Hoshi, T Kinoshita, et al., Fabrication of lead-Free and high Tc BaTiO3-based thermistor ceramics using deoxidizing effect of oxygen-containing α-zirconium, Ceram. Int. 34 (2008) 2073–(2077).

DOI: 10.1016/j.ceramint.2007.08.009

Google Scholar

[8] Q B Yuan, Y P Pu, Effects of K0. 5Bi0. 5TiO3 addition on dielectric properties of BaTiO3 ceramics, Ceram. Int. 39 (2013) 3507–3510.

DOI: 10.1016/j.ceramint.2012.10.174

Google Scholar

[9] Y P Pu, J F Wei, Y Q Mao, et al., Positive temperature coefficient of resistivity behavior of niobium-doped (1−x)BaTiO3-xBi0. 5Li0. 5TiO3 ceramics, J. Alloy. Compd. 498 (2010) L5–L7.

DOI: 10.1016/j.jallcom.2010.03.149

Google Scholar

[10] J C Zhao, L T Li, Z L Gui, Influence of lithium modification on the properties of Y-doped Sr0. 5Pb0. 5TiO3 thermistors, Sensor. Actuat. A 95 (2001) 46-50.

Google Scholar

[11] S L Leng, G R Li, L Y Zheng, et al., Effect of donor concentration on the PTCR behavior of Y-doped BaTiO3-(Bi1/2Na1/2)TiO3 ceramics, J. Mater. Sci.: Mater. Electron. 24 (2013) 431–435.

DOI: 10.1007/s10854-012-0774-x

Google Scholar

[12] B Li, Inorganic Dielectric Material, National Defence Industry Press, Beijing, 1980, p.263.

Google Scholar