Microstructural Investigation of Routes for Gamma Titanium Aluminides Production by Powder Metallurgy

Article Preview

Abstract:

The alloy design and efficient routes of TiAl processing are important technological challenges for the development of new aerospace systems. Gamma-TiAl alloys are potential replacements for nickel and conventional titanium alloys in hot sections of turbine engines, as well as in sub-structures of orbital platform vehicles. Powder metallurgy (P/M) of Ti-based alloys may lead to the obtainment of components having weak-to-absent textures, uniform grain structure and higher homogeneity compared with conventional wrought products. This paper aims to investigate the microstructural evolution and densification aspects involved in the obtainment of Ti-48Al-2Cr-2Nb (at.%) alloy by three P/M-processing routes. Samples were prepared from elemental and pre-alloyed powders mixed for 2 h, followed by cold uniaxial and isostatic pressing followed by sintering and hot pressing stages between 1100°C up to 1400°C, for 1 h. After metallographic preparation, sintered samples were characterized by means of scanning electron microscopy (SEM) in the backscattered mode (BSE), X-ray diffraction (XRD), and density measurements. The results showed the potential of TiAl pre-alloyed powders to prevent Kirkendall porosity. A full lamellar microstructure was obtained by the pressureless route while a duplex microstructure was observed in samples produced by the hot pressing route.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

204-213

Citation:

Online since:

August 2016

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2016 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Liu, B.; Liua, Y.; Zhang, W.; Huang, J.S. Hot deformation behavior of TiAl alloys prepared by blended elemental powders, Intermetallics, 19 (2011) 154-159.

DOI: 10.1016/j.intermet.2010.08.024

Google Scholar

[2] Wenbin, F.; Lianxi, H.; Wenxiong, H.; Erde, W.; Xiaoqing, L. Microstructure and properties of a TiAl alloy prepared by mechanical milling and subsequent reactive sintering, Materials Science and Engineering A, 403 (2005) 186–190.

DOI: 10.1016/j.msea.2005.04.049

Google Scholar

[3] Appel, F.; Paul J.D.H.; Oehring, M. Gamma Titanium Aluminide Alloys – Science and Technology, Wiley-VCH, Weinheim, (2011).

DOI: 10.1002/9783527636204

Google Scholar

[4] Kim, Y. -W. Intermetallic Alloys Based on Gamma Titanium Aluminide, Journal of Metals, 41 (1989) 24-30.

Google Scholar

[5] Clemens, H.; Mayer S. Design, processing, microstructure, and applications of advanced intermetallic TiAl alloys. Advanced Engineering Materials, 15 (2013) 191-215.

DOI: 10.1002/adem.201200231

Google Scholar

[6] Collings, E. W.; Welsch, G. Materials Properties Handbook: Titanium Alloys, ASM, (1994).

Google Scholar

[7] Donachie, M.J. Titanium a technical guide, ASM, (1988).

Google Scholar

[8] Boyer, R.R. An overview on the use of titanium in the aerospace industry. Materials Science and Engineering A, 213 (1996) 103-114.

Google Scholar

[9] Thomas, M.; Bacos, M. Processing and Characterization of TiAl-based Alloys: Towards an Industrial Scale. Aerospace Lab Journal, 3 (2011) 1-11.

Google Scholar

[10] Yamaguchi, M.; Inui, H., in: R. Darolia et al (Eds. ), TiAl Compounds for Structural Applications. Structural Intermetallics, The Minerals, Metals & Materials Society, (1993) 127-142.

Google Scholar

[11] German, R. M. Sintering, Theory and practice, John Wiley & Sons, (1996).

Google Scholar

[12] Froes, F.H.; Eylon, D. Powder metallurgy of titanium alloys- a review, Powder Metallurgy International, 17 (1985) 163-167.

DOI: 10.1520/stp28934s

Google Scholar

[13] Moody, N.R.; Garrison, W.M.; Smugeresky J.E.; Costa, J.E. The role of inclusion and pore content on the fracture toughness of powder-processed blended elemental titanium alloys, Metallurgical Transactions A, 24 (1993) 161-174.

DOI: 10.1007/bf02669613

Google Scholar

[14] Hagiwara, M.; Emura, S. Blended elemental P/M synthesis and property evaluation of Ti-1100 alloy Materials Science and Engineering A, 352 (2003) 85-92.

DOI: 10.1016/s0921-5093(02)00897-3

Google Scholar

[15] Henriques, V.A.R.; Galvani, E. T.; Petroni, S.L.G.; Paula, M.S.M.; Lemos, T.G. Production of Ti–13Nb–13Zr alloy for surgical implants by powder metallurgy, Journal of Materials Science, 45 (2010) 5844–5850.

DOI: 10.1007/s10853-010-4660-8

Google Scholar

[16] Lee-Sullivan, P. HIP processing of Ti-Al intermetallic using blended elemental powders, Journal of Materials Processing Technology, 38 (1993) 1-14.

DOI: 10.1016/0924-0136(93)90181-5

Google Scholar

[17] Wang, G. -X.; Dahms, M. An Overview: TiAl-Based Alloys Prepared by Elemental Powder Metallurgy, Powder Metallurgy International, 24 (1992) 219-225.

Google Scholar

[18] K. Shibue, Suppression of Pores for TiAl Intermetallic Compound Prepared by Reactive Sintering, Sumitomo Light Metal Technical Reports, 32 (1991) 95-101.

Google Scholar

[19] Böhm, A.; Kieback, B. Investigation of swelling behavior of Ti-Al elemental powder mixtures during reaction sintering, Zeitschrift Fuer Metallkunde, 89(1998) 90-95.

Google Scholar

[20] Dahms M., Leitner G., Poessnecker W., Schultrich S. Schmelzer F. Pore formation during reactive sintering of extruded titanium aluminum powder mixtures', Zeitschrift Fuer Metallkunde, 1993, 84, 351–357.

DOI: 10.1515/ijmr-1993-840513

Google Scholar

[21] Chraponski, J; Szkliniarz, W.; Serek, B. Microstructure and chemical composition of phases in Ti-48Al-2Cr-2Nb intermetallic alloy. Materials Chemistry and Physics, 81 (2003) 438–442.

DOI: 10.1016/s0254-0584(03)00042-7

Google Scholar

[22] Clemens H., Wallgram W., Kremmer S., Güther V., Otto A., Bartels A. Design of Novel β-Solidifying TiAl Alloys with Adjustable β/B2-Phase Fraction and Excellent Hot-Workability, Advanced Engeneering Materials, 10 (2008) 707-713.

DOI: 10.1002/adem.200800164

Google Scholar

[23] Huang, Y, Wang, Y., Fan, H., Shen, J. A TiAl based alloy with excellent mechanical performance by gas atomization and spark plasma sintering, Intermetallics, 31 (2012) 202-207.

DOI: 10.1016/j.intermet.2012.07.006

Google Scholar

[24] Hsiung, L.M., Nieh, T.G. Microstructures and properties of powder metallurgy TiAl alloys, Materials Science and Engineering A, 364 (2004) 1–10.

DOI: 10.1016/s0921-5093(02)00639-1

Google Scholar