Novel and Emerging Routes for Titanium Powder Production - An Overview

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Abstract:

As the adoption of components fabricated via titanium powder metallurgy (PM) techniques becomes more prevalent, and projected to increase at a substantial rate over the next decade, especially in the field of additive manufacturing (AM), there is a necessity to increase titanium powder production capacity from the current annual level of ca. 6000 tonnes per annum. At present a well-documented barrier restricting this widespread implementation, is the inherently high cost of the feedstock, an issue which to date has been neglected to some degree, at the expense of developing the individual powder metallurgy routes. The scope of this overview therefore is to provide an insight of both established and novel methods of titanium powder production, as potential opportunities to satisfy this growing demand. Particular emphasis will focus on Metalysis, a company founded to commercialize an innovative electrochemical approach for the synthesis of metals and alloys from their respective oxides, where the ability to generate titanium eloquently demonstrates the extent of its capabilities.The patented Metalysis technology, exploiting the FFC® Cambridge process, lends itself to producing alloys and intermetallics, where Ti-6Al-4V provides a prime example of this. Furthermore, as electrolysis occurs solely in the solid state, issues pertaining to segregation due to dissimilar densities and melting points are avoided. It is possible to tailor both the average particle diameter and size distribution of the product targeted powder metallurgy (PM) applications, based upon appropriate selection of the feed. The attraction of this strategy is that the steps associated with conventional metal powder synthesis are circumvented, resulting in a significant cost reduction. Moreover it has recently been revealed that titanium can be produced directly from naturally occurring ore (beach sand) and synthetic rutile, with the ensuing product presenting itself as an inexpensive and abundant feedstock for additive manufacturing (AM). This represents a paradigm shift in the availability of consumables for the 3D printing market.

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[1] E. H. Kraft, Summary of emerging titanium cost reduction technologies, US Department of Energy and Oak Ridge National Laboratory Subcontract 4000023694, (2004).

Google Scholar

[2] F. H. Froes, Titanium Powder Metallurgy: A Review – Part 1, Adv. Mater. Processes 170 (September 2012) 16 – 21.

Google Scholar

[3] G. M. Delphine Cantin, N. A. Stone, D. Alexander, M. A. Gibson, D. Ritchie, R. Wilson, M. Yousuff, R. Rajakumar and K. Rogers, Production of Ti-6Al-4V by direct rolling of blended elemental powder, Mater. Sci. Forum 654 – 655 (2010) 807 – 810.

DOI: 10.4028/www.scientific.net/msf.654-656.807

Google Scholar

[4] B. Thomas, F. Derguti and M. Jackson, Continuous extrusion of titanium particulates, Proceedings of the 13th World Conference on Titanium, San Diego, USA, 16th-20th August (2015).

DOI: 10.1002/9781119296126.ch16

Google Scholar

[5] D. Whittaker and F. H. Froes, Future prospects for titanium powder metallurgy markets, in: M. Qian and F. H. Froes (Eds. ), Titanium Powder Metallurgy – Science, Technology and Applications, Butterworth-Heinemann, Waltham, Massachusetts, 2015, p.579.

DOI: 10.1016/b978-0-12-800054-0.00030-7

Google Scholar

[6] Information on http: /materialstoday. com/additive-manufacturing/news/titanium-sales-in-am-could-exceed-us300-million.

Google Scholar

[7] F. H. Froes, Titanium Powder Metallurgy: A Review – Part 2, Adv. Mater. Processes 170 (October 2012) 26 – 29.

Google Scholar

[8] Y. H. Moll and C. F. Yolton, Production of titanium powder, in: P. W. Lee, Y. Trudel, R. Iacocca, R. M. German, B. L. Ferguson, W. B. Eisen, K. Moyer, D. Madan and H. Sanderow (Eds. ), ASM Handbook, Volume 7: Powder Metal Technologies and Applications, ASM International, Materials Park, Ohio, 1998, p.160.

Google Scholar

[9] O. Neikov, Non-ferrous powder production: Manufacturing methods and properties of copper, aluminium, titanium and nickel powders, Powder Metallurgy Review 3 (Summer 2014) 65 – 87.

Google Scholar

[10] C. McCracken, Production of fine titanium powders via the hydride – dehydride (HDH) process, Powder Injection Moulding International 2 (June 2008) 1 – 3.

Google Scholar

[11] J. D. Paramore, Z. Z. Fang, P. Sun, M. Koopman, K. S. Ravi Chandran and M. Dunstan, A powder metallurgy method for manufacturing Ti-6Al-4V with wrought-like microstructures and mechanical properties via hydrogen sintering and phase transformation (HSPT), Scripta Mater. 107 (2015).

DOI: 10.1016/j.scriptamat.2015.05.032

Google Scholar

[12] D. S. van Vuuren, S. Oosthuizen and M. D. Heydenrych, Titanium production via metallothermic reduction of TiCl4 in molten salt: problems and products, J. S. Afr. Inst. Min. Metall. 111 (2011) 141 – 148.

Google Scholar

[13] Z. Z. Fang, S. Middlemas, J. Guo and P. Fan, A new, energy-efficient chemical pathway for extracting Ti metal from Ti minerals, J. Am. Chem. Soc. 135 (2013) 18248 – 18251.

DOI: 10.1021/ja408118x

Google Scholar

[14] H. Zheng, H. Ito and T. H. Okabe, Production of titanium powder by the calciothermic reduction of titanium concentrates or ore using the preform reduction process, Mater. Trans., JIM 48 (2007) 2244 – 2251.

DOI: 10.2320/matertrans.mer2007115

Google Scholar

[15] D. S. van Vuuren, Direct Titanium Powder Production by Metallothermic Processes, in: M. Qian and F. H. Froes (Eds. ), Titanium Powder Metallurgy – Science, Technology and Applications, Butterworth-Heinemann, Waltham, Massachusetts, 2015, p.69.

DOI: 10.1016/b978-0-12-800054-0.00005-8

Google Scholar

[16] D. S. van Vuuren, A critical evaluation of processes to produce primary titanium, J. S. Afr. Inst. Min. Metall. 109 (2009) 455 – 461.

Google Scholar

[17] G. Z. Chen, D. J. Fray and T. W. Farthing, Direct electrochemical reduction of titanium dioxide to titanium in molten calcium chloride, Nature 407 (2002) 361 – 364.

DOI: 10.1038/35030069

Google Scholar

[18] R. O. Suzuki, K. Teranuma and K. Ono, Calciothermic reduction of titanium dioxide and in-situ electrolysis in molten CaCl2, Metall. Mater. Trans B 34B (2003) 287 – 295.

DOI: 10.1007/s11663-003-0074-1

Google Scholar

[19] A. M. Martinez, K. S. Osen, E. Skybakmoen, O. S. Klos, G. M. Haarberg and K. Dring, A new method for low-cost titanium production. Key. Eng. Mater. 436 (2010) 41 – 53.

DOI: 10.4028/www.scientific.net/kem.436.41

Google Scholar

[20] J. C. Withers, Production of Titanium Powder by an Electrolytic Method and Compaction of the Powder, in: M. Qian and F. H. Froes (Eds. ), Titanium Powder Metallurgy – Science, Technology and Applications, Butterworth-Heinemann, Waltham, Massachusetts, 2015, p.33.

DOI: 10.1016/b978-0-12-800054-0.00003-4

Google Scholar

[21] P. C. Pistorius and F. Fatollahi-Fard, Production of titanium oxycarbide from titania-rich mineral sands, TMS Annual Meeting (2015) 297 – 304.

DOI: 10.1007/978-3-319-48214-9_34

Google Scholar

[22] S. Jiao and H. Zhu, Novel metallurgical process for titanium production, J. Mater. Res. 21 (2006) 2172 – 2175.

DOI: 10.1557/jmr.2006.0268

Google Scholar

[23] J. M. Capus, Metal Powders: A Global Survey of Production, Applications and Markets 2001-2010, fourth ed., Elsevier, New York, (2005).

Google Scholar

[24] B. Beauchamp, Raymor AP&C: Leading the way with plasma atomised Ti spherical powders for MIM, Powder Injection Moulding International 5 (December 2011) 55 – 57.

Google Scholar

[25] A. J. Fenn, G. Cooley, D. Fray and L. Smith, Exploiting the FFC Cambridge process, Adv. Mater. Processes, 162 (2004) 51 – 53.

Google Scholar

[26] R. Bhagat, M. Jackson, D. Inman and R. Dashwood, Production of Ti-W alloys from mixed oxide precursors via the FFC Cambridge process, J. Electrochem. Soc. 156 (2009) E1 – E7.

DOI: 10.1149/1.2999340

Google Scholar

[27] I. Mellor, L. Grainger, K. Rao, J. Deane, M. Conti, G. Doughty and D. Vaughan, Titanium Powder Production via the Metalysis Process, in: M. Qian and F. H. Froes (Eds. ), Titanium Powder Metallurgy – Science, Technology and Applications, Butterworth-Heinemann, Waltham, Massachusetts, 2015, p.51.

DOI: 10.1016/b978-0-12-800054-0.00004-6

Google Scholar

[28] L. L. Benson, I. Mellor and M. Jackson, Direct reduction of synthetic rutile using the FFC process to produce low cost novel titanium alloys, J. Mater. Sci, 51 (2016) 4250 – 4261.

DOI: 10.1007/s10853-015-9718-1

Google Scholar

[29] R. Hill, Titanium: 21st century metal, PROCESS – CSIRO research in mineral processing and metal production February (2002) 1 – 2.

Google Scholar