Photocatalytic Degradation of Humic Acid with Metal-Doped TiO2 under Near-Visible Irradiation

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The improvement of photocatalytic activity of TiO2 has been explored. TiO2 has been doped with some transition metal elements for new photocatalytic materials. They were prepared using nitrates of Fe, Cu and Zn. Their photocatalytic activities were investigated by conducting a semi-batch experiment. The degradation of aqueous humic acid was performed under near-visible irradiation. For examining the photocatalytic characteristics of the new materials, the dissolved organic carbon and the UV254 absorption of humic acid were analyzed. The new metal-doped photocatalysts showed higher photoactivities than the synthesized pure TiO2. And photodegradation result of humic acid by the new metal-doped material was even better than by the commercial Degussa P-25 TiO2 at wavelengths of 315 nm - 400 nm.

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589-593

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December 2016

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© 2017 Trans Tech Publications Ltd. All Rights Reserved

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[1] Z. Xiong, H. Dou, J. Pan, J. Ma, C. Xu, X. Zhao, Synthesis of mesoporous anatase TiO2 with a combined template method and photocatalysis, Cryst. Eng. Comm. 12 (2010) 3455-3457.

DOI: 10.1039/c0ce00228c

Google Scholar

[2] D. Macwan, P. N. Dave, S. Chaturvedi, A review on nano- TiO2 sol-gel type synthesis and its applications, J. Mater. Sci. 46 (2011) 3669-3686.

DOI: 10.1007/s10853-011-5378-y

Google Scholar

[3] J. Lyu, L. Zhu, C. Burda, Considerations to improve adsorption and photocatalysis of low concentration air pollutants on TiO2, Cat. Today 225 (2014) 24-33.

DOI: 10.1016/j.cattod.2013.10.089

Google Scholar

[4] J. Dziedzic, D. Wodka, P. Nowak, P. Warszynski, C. Simon, I. Kumakiri, Photocatalytic degradation of the humic species as a method of their removal from water, Physicochem. Probl. Miner. Process. 45 (2010) 15-28.

Google Scholar

[5] C. S. Uyguner-Demirel, M. Bekbolet, Significance of analytical parameters for the understanding of natural organic matter in relation to photocatalytic oxidation, Chemosphere 84 (2011) 1009-1031.

DOI: 10.1016/j.chemosphere.2011.05.003

Google Scholar

[6] J. Wiszniowski, D. Robert, J. Surmacz-Gorska, K. Miksch, J. Weber, Photocatalytic decomposition of humic acids on TiO2, J. Photochem. Photobiol. A: Chem. 152 (2002) 267-273.

DOI: 10.1016/s1010-6030(02)00022-9

Google Scholar