Effect of STAC on Structure of Biotite when Biotite Transform to Hydrated Ba-Mica

Abstract:

After Ba²⁺/K⁺ ion exchange, hydrated Ba²⁺ replaced K⁺ from interlayer spacing of biotite. original biotite transformed to vermiculite-type hydrated Ba-mica. in order to study the effect of long-chain alkylammonium on biotite after structure changes, biotite, hydrated Ba-mica and mixing mica (A mixture of biotite and hydrated Ba-mica) were used to be modified by STAC (octadecyl trimethylammonium chloride). Fourier transform infrared spectroscopy and powder X-ray diffraction spectroscopywere were used to characterize the obtained samples to reveal the changes of interlayer spacing and basal spacing. The results showed that STA⁺ could not enter into the interlayer spacing of biotite but enter into that of hydrated Ba-mica and mixing mica. Almost all basal spacing of Ba-mica and mixing mica were increased to 2.8nm.

• Periodical: Key Engineering Materials (Volume 723)
• Pages: 567-571
• DOI: https://doi.org/10.4028/www.scientific.net/KEM.723.567
• Online since: December 2016
• Authors: Yu Wei, Zhi Liang Huang*, Xiao Yu Huang
• Keywords: Biotite, Hydrated Ba-Mica, STAC

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