Interfacial Tension Prediction of Readily-Mixed Waxy Crude Oil Emulsion at Pour Point Temperature

Article Preview

Abstract:

In the industry, stubborn emulsion still constitutes up to 20% of the total emulsion volume. The existing remediation strategies for emulsion treatment rely heavily on the study of heavy crude oil emulsion. However, minimal information is available on integrating interfacial rheology with emulsion stability on waxy crude oil emulsion. The proposed research provides a study to the development of integration between interfacial rheology and emulsion stability so that it can be a quick assessment but an accurate method to measure emulsion stability. The primary objectives of the research are to provide an extensional study to the design development of a comprehensive interfacial rheology protocol for the assessment of emulsion stability by developing a method of testing and monitoring the interfacial rheology and to investigate the demulsification ability of the waxy crude oil emulsion subjected to microbial treatment. The novelty of this study is to use the newly developed measurement protocol via interfacial rheology to predict emulsion stability. Application of the microbes on waxy crude oil to breakdown the water-in-oil emulsion using a rheometer will also be explored. The treatment is targeted to disintegrate the interfacial layer within the emulsion leading to better oil recovery. Rheological properties of the emulsion will be monitored upon the microbial injection to analyze the effects of the treatment on the rheology of emulsion. The outcomes from this research is that the newly developed protocol will predict emulsion stability that could resolve the stubborn emulsion issues via the developed interfacial rheology protocol, which could be time-saving and increases the production efficiency. This research paper is a study to develop a correlation on surface tension and interfacial tension between crude oil, water and a readily-mixed emulsion.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

62-71

Citation:

Online since:

August 2019

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2019 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] G. Zhang, Y. Wang, L. Chen, L. Zhang. Colloids Surf., A, 443 (2014), pp.141-148.

Google Scholar

[2] A. Mosayebi, and R. Abedini, Using Demulsifiers for Phase Breaking of Water / Oil Emulsion, Pet. coal, vol. 55, no. (1) 26–30, (2013).

Google Scholar

[3] M. S. Liyana Nadirah et al. Rheological Study of Petroleum Fluid and Oil-in-Water Emulsion, Int. J. Eng. Sci. Res. Technol. 3(1) (2014).

Google Scholar

[4] D. C. Maia, J. B. V. S. Ramalho, G. M. S. Lucas, E. F. Lucas, Aging of water-in-crude oil emulsions: Effect on rheological parameters, Colloids Surf. A: Physicochem. Eng. Asp. 405 (2012) 73-78.

DOI: 10.1016/j.colsurfa.2012.04.041

Google Scholar

[5] A. M. Al-sabagh, N. M. Nasser, T. M. A. El-hamid, Investigation of Kinetic and Rheological Properties for the Demulsification Process, Egypt. J. Pet. 22(1) (2013) 117-127.

DOI: 10.1016/j.ejpe.2012.11.013

Google Scholar

[6] G. Bognolo, Biosurfactants as emulsifying agents for hydrocarbons, Colloids Surf. A: Physicochem. Eng. Aspects, 152(1-2) (1999) 41-52.

DOI: 10.1016/s0927-7757(98)00684-0

Google Scholar

[7] I. M. Banat et al. Microbial biosurfactants production, applications and future potential, Appl. Microbiol. Biotechnol. 87(2) (2010) 427-444.

DOI: 10.1007/s00253-010-2589-0

Google Scholar

[8] J., Van Hamme, Ind Microbiol Biotechnol. 2003 May; 30(5):260-70. Epub 2003 Apr 3.

Google Scholar

[9] J. S. Lim, S. F. Wong, M. C. Law, A Review on the Effects of Emulsion on Flow Behaviours and Common Factors Affecting the Stability of Emulsion, J. Appl. Sci. 15(2) (2015) 167-172.

Google Scholar

[10] J. Sjoblom, N. Aske, I.H. Auflem, O. Brandal, T.E. Havre, O. Saether, A. Westvik, E.E Johnsen and H. Kallevik, 2003. Our current understanding of water-in-crude oil emulsions. Recent characterization techniques and high pressure performance. Adv. Colloid Interface Sci., 399; 100-102.

DOI: 10.1016/s0001-8686(02)00066-0

Google Scholar

[11] M. Meriem-benziane, H. Zahloul, Rheological Behaviors of Crude Oil in the Presence of Water, 7(3) (2013) 223-227.

Google Scholar

[12] J.E. Strassner, 1968. Effect of pH on interfacial films and stability of crude oil-water emulsions. J. Pet. Technol., 3: 303.

DOI: 10.2118/1939-pa

Google Scholar

[13] R. M. Abd, A. H. Nour, A. Z. Sulaiman, Experimental Investigation on Dynamic Viscosity and Rheology of Water-Crude Oil Two Phases FlowBehavior at Different Water Volume Fractions, Am. J. Eng. Res. 3(3) (2014) 113-120.

Google Scholar

[14] M. T. Ghannam, S. W. Hasan, B. Abu-jdayil, N. Esmail, Rheological properties of heavy & light crude oil mixtures for improving fl owability, J. Pet. Sci. Eng. 81 (2012) 122-128.

DOI: 10.1016/j.petrol.2011.12.024

Google Scholar

[15] E. Rosenberg, & E.Z. Ron, 1999. High- and low-molecular-mass microbial surfactants. Applied Microbiology and Biotechnology, 52(2), p.154–162.

DOI: 10.1007/s002530051502

Google Scholar

[16] M. K. Ekeh, Prediction of wax deposition of Malaysian crude from Viscosity-Temperature correlation for Dead Crude, Int. J. Sci. Adv. Technol. 1 (2011) 89-100.

Google Scholar

[17] R. M. Illias, S. W. Ooi, A. K. Idris et al. Production of Biosurfactant and Biopolymer from Malaysian Oil Fields Isolated Microorganisms, Soc. Pet. Eng. (1999).

DOI: 10.2118/57315-ms

Google Scholar

[18] D. Li et al. Microbial biodiversity in a Malaysian Oil Weld and a systematic comparison with oil reservoirs worldwide, Archives Microbiol. 194(6) (2012) 513-523.

DOI: 10.1007/s00203-012-0788-z

Google Scholar

[19] A. Sadeghazad, N. Ghaemi, 2003, Microbial Prevention of Wax Precipitation in Crude Oil by Biodegradation Mechanism, presented at the SPE Asia Pacific Oil and Gas Conference and Exhibition, Jakarta, Indonesia.

DOI: 10.2118/80529-ms

Google Scholar

[20] N. Das, P. Chandran, Microbial degradation of petroleum hydrocarbon contaminants: an overview, Biotechnol. Res. Int. (2011) 941810.

Google Scholar

[21] R. M. Illias, S. W. Ooi, A. K. Idris, Isolation and Characterization of Thermophilic Microorganisms from Malaysian Oil Fields, Soc. Pet. Eng. (1999) 261-266.

DOI: 10.2118/56496-ms

Google Scholar

[22] M. A. Krawezyk, D. T. Wasan, C. S Shetty, Fundamentals of Emulsions, Ind. Eng. Chem. Res. 30 (1991) 367.

Google Scholar