Isomerization of Allyl Derivatives of Bisphenol A

Vladimir A. Lisovenko; Pavel A. Yudaev; Evgeniy M. Chistyakov

doi:10.4028/www.scientific.net/KEM.869.357

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HomeKey Engineering MaterialsKey Engineering Materials Vol. 869Isomerization of Allyl Derivatives of Bisphenol A

Isomerization of Allyl Derivatives of Bisphenol A

Abstract:

4,4'-diallyloxy-2,2-diphenylpropane, based on bisphenol A and allyl bromide wassynthesized. The thermal properties of the obtained products were studied using thermogravimetricanalysis and differential scanning calorimetry. The process of thermal isomerization of allyl groupsin 4,4'-diallyloxy-2,2-diphenylpropane, which is a Claisen rearrangement, was discovered. Allcompounds were characterized by 1H NMR spectroscopy.

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Periodical:

Key Engineering Materials (Volume 869)

Pages:

357-361

DOI:

https://doi.org/10.4028/www.scientific.net/KEM.869.357

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Online since:

October 2020

Authors:

Vladimir A. Lisovenko*, Pavel A. Yudaev, Evgeniy M. Chistyakov

Keywords:

Bisphenol A, Claisen Rearrangement, Isomerization

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References

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