Synthesis of Aromatic Diketoximes and their Complexes with Nickel Salts

Abstract:

The diketoximes of 4,4'-diacetyldiphenyl oxide and 4,4'-diacetyldiphenyl sulfide were synthesized, the possibility of their use for the synthesis of simple and complex polyesters and polypyrroles, as well as the ability to complex with nickel salts. Organic chemistry used oximes in the 19th century, afterward, as an analytical reagent in the 20th century. Currently, oximes are superior to carbonyl compounds and alcohols in the variety of reactions and the widespread use in synthetic chemistry. Oximes easily turn into other classes of organic compounds – amines, cyano and nitro compounds, carbonyl compounds, heterocyclic compounds, including pyrroles, imidazoles, pyridines, they can be used as suitable compounds with salts of Cu (II), Ni (II), Zn (II), Cd (II), and Co (II). Oximes with complex heterocyclic and aromatic substituents are used as intermediates in fine organic synthesis. It should be noted that oximes have a wide spectrum of biocidal action and are used as anti-inflammatory, antiviral, antimicrobial agents, insecticides. Their versatile biological activity is considered in the preparation of antidepressant, sedative, vasodilator and other drugs [1].

• Periodical: Key Engineering Materials (Volume 869)
• Pages: 571-576
• DOI: https://doi.org/10.4028/www.scientific.net/KEM.869.571
• Online since: October 2020
• Authors: Yurii I. Musaev*, Eleonora B. Musaeva, Svetlana Khashirova, Marina O. Sanakoeva, Artur E. Baykaziev
• Keywords: 4,4'-Diacetyldiphenyl Sulfide, Complexes, Diketoximes 4,4'-Diacetyldiphenyl Oxide, IR-Spectra, Nickel Nitrate

References

[1] A.I. Mikhaleva, A.B. Zaitsev, B.A. Trofimov, Oximes as reagents, J. Usp. Chem. 75 (2006) 884-912.

[2] Yu.I. Musaev, Synthesis features and reaction mechanisms for the production of polyarylates, aromatic polyethers and polypyrroles in non-aqueous media, Diss. ... Dr. chem. Sciences, Nal'chik, (2004).

[3] Yu.I. Musaev, E.B. Musaeva, A.K. Mikitaev, O.S. Khamukova, Polyformals and polyetherformals and method for their preparation. Patent RF № 2223977.

[4] Yu.I. Musaev, E.B. Musaev, F.A. Gashaev, Polyphenylene ether ketone oxime and method for its preparation. Patent RF № 2466153.

[5] Yu.I. Musaev, E.B. Musaeva, N.I. Mashukov, M.A. Mikitaev, V.A. Kvashin, Polymer composition. Patent RF № 2261878 (2005).

[6] Yu.I. Musaev, E.B. Musaeva, M.A. Mikitaev, V.A. Kvashin, A polymer composition used as a structural material. Patent RF № 2292366 (2007).

[7] Yu.I. Musaev, E.B. Musaev, A.M. Kharaev, A.B. Zhekamukhov, V.A. Kvashin, M.A. Mikitaev, Polymer composition for structural materials. Patent RF № 2303612 (2007).

[8] Yu.I. Musaev, E.B. Musaev, A.K. Mikitaev, O.S. Khamukova, Polymers containing pyrrole rings in the main chain and a process for their preparation. Patent RF № 2265622 (2005).

[9] B.A. Trofimov, A.I. Mikhaleva, E.Yu. Schmidt, L.N. Sobenin, Chemistry of pyrrole. New Pages, Nauka, Novosibirsk, (2012).

[10] A.S. Agronomists, Yu.S. Shabarov Laboratory work in an organic workshop, Chemistry, Moscow, (1974).

[11] I. Demir, M. Bayrakci, K. Mutlu, I. Pekarac, Synthesis and Characterization of a Novel Iminooxime Schiff Base Ligand and Its Complexation with Copper (II), Nickel (II), Zinc (II), Cadmium (II), and Cobalt (II), Acta Chim. Slov. 55 (2008) 120.

DOI: 10.1021/acsomega.2c08001.s001

[12] R.E. Rundle, C.V. Banks, J. Phys. Chem. 67 (1963) 508-512.