Bio-Based Conductive Polymer Composite Materials for Fuel Cells Bipolar Plates

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Conductive polymer composite materials for polymer electrolyte membrane fuel cells bipolar plates have been successfully prepared from renewable plant biomass sources. The composites are based on various conductive fillers (natural, oxidized and colloidal graphites) and the 5-hydroxymethylfurfural synthesis by-product resin that consists of complex furanic oligomers and polymers. The influences of the resin content and type of conductive filler were investigated. The conductivity of the composite are decreased with increasing resin content, but its mechanical properties are improve. A sample with a resin content of 10 wt. % and colloidal graphite filler have showed the optimal balance between electrical conductivity and mechanical properties. The interfacial contacting resistance, flexural and compressive strength of the composite were 0.035 ohm•cm2, 18.4 MPa and 21.4 MPa, respectively. Composite based on 5-hydroxymethylfurfural synthesis by-product resin and conductive filler (colloidal graphite) are showed a great potential application as bipolar plates for polymer electrolyte membrane fuel cells.

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591-596

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October 2020

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© 2020 Trans Tech Publications Ltd. All Rights Reserved

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[1] Y. Li, J. Yang, J. Song, Structure models and nano energy system design for proton exchange membrane fuel cells in electric energy vehicles, Renewable and Sustainable Energy Reviews. 67 (2017) 160-172.

DOI: 10.1016/j.rser.2016.09.030

Google Scholar

[2] G. Wang, et al., Progress on design and development of polymer electrolyte membrane fuel cell systems for vehicle applications: A review, Fuel Processing Technology. 179 (2018) 203-228.

DOI: 10.1016/j.fuproc.2018.06.013

Google Scholar

[3] R. Wlodarczyk, Carbon-based materials for bipolar plates for low-temperatures PEM fuel cells, Functional Materials Letters. 12 (2019) 1930001.

DOI: 10.1142/s1793604719300019

Google Scholar

[4] N. Guo, M.C. Leu, Effect of different graphite materials on the electrical conductivity and flexural strength of bipolar plates fabricated using selective laser sintering, International journal of hydrogen energy. 37 (2012) 3558-3566.

DOI: 10.1016/j.ijhydene.2011.11.058

Google Scholar

[5] N.A.M. Radzuan, et al., The effect of milled carbon fibre filler on electrical conductivity in highly conductive polymer composites, Composites Part B: Engineering. 110 (2017) 153-160.

DOI: 10.1016/j.compositesb.2016.11.021

Google Scholar

[6] J. Zhu, Carbon black-reinforced 3D and 4D printable conductive polymer composites, 3D and 4D Printing of Polymer Nanocomposite Materials. Elsevier. (2020) 367-385.

DOI: 10.1016/b978-0-12-816805-9.00012-0

Google Scholar

[7] D. Prasanna, V. Selvaraj, Cyclophosphazene based conductive polymer-carbon nanotube composite as novel supporting material for methanol fuel cell applications, Journal of colloid and interface science. 472 (2016) 116-125.

DOI: 10.1016/j.jcis.2016.03.032

Google Scholar

[8] L. Flandin, et al., Effect of strain on the properties of an ethylene-octene elastomer with conductive carbon fillers, Journal of Applied Polymer Science. 76 (2000) 894-905.

DOI: 10.1002/(sici)1097-4628(20000509)76:6<894::aid-app16>3.0.co;2-k

Google Scholar

[9] R. Taherian, A review of composite and metallic bipolar plates in proton exchange membrane fuel cell: Materials, fabrication, and material selection, Journal of Power Sources. 265 (2014) 370-390.

DOI: 10.1016/j.jpowsour.2014.04.081

Google Scholar

[10] A. Mukherjee, M.J. Dumont, V. Raghavan, Sustainable production of hydroxymethylfurfural and levulinic acid: Challenges and opportunities, Biomass and Bioenergy. 72 (2015) 143-183.

DOI: 10.1016/j.biombioe.2014.11.007

Google Scholar

[11] B.R. Caes, et al., Biomass to furanics: renewable routes to chemicals and fuels, ACS Sustainable Chemistry & Engineering. 3 (2015) 2591-2605.

DOI: 10.1021/acssuschemeng.5b00473

Google Scholar

[12] P.K. Rout, et al., Synthesis of hydroxymethylfurfural from cellulose using green processes: A promising biochemical and biofuel feedstock, Chemical Engineering Science. 142 (2016) 318-346.

DOI: 10.1016/j.ces.2015.12.002

Google Scholar

[13] D.V. Chernysheva, et al., Sustainable utilization of biomass refinery wastes for accessing activated carbons and supercapacitor electrode materials, ChemSusChem. 11 (2018) 3599-3608.

DOI: 10.1002/cssc.201801757

Google Scholar

[14] K.Yao, et al., Highly conductive and strong graphite-phenolic resin composite for bipolar plate applications, Energy & Fuels. 31 (2017) 14320-14331.

DOI: 10.1021/acs.energyfuels.7b02678

Google Scholar

[15] V.A. Klushin, et al., Technological aspects of fructose conversion to high-purity 5-hydroxymethylfurfural, a versatile platform chemical, Russian Journal of Organic Chemistry. 52 (2016) 767-771.

DOI: 10.1134/s1070428016060014

Google Scholar

[16] S.B. Lee, et al., Improved corrosion resistance and interfacial contact resistance of 316L stainless-steel for proton exchange membrane fuel cell bipolar plates by chromizing surface treatment, Journal of Power Sources. 187 (2009) 318-323.

DOI: 10.1016/j.jpowsour.2008.11.064

Google Scholar

[17] B.K. Kakati, K.R. Guptha, A. Verma, Fabrication of composite bipolar plate for proton exchange membrane fuel cell, J. Environ Res Dev. 4 (2009) 202-211.

Google Scholar

[18] Q. Yin, et al., Study on the electrical and mechanical properties of phenol formaldehyde resin/graphite composite for bipolar plate, Journal of power sources. 165 (2007) 717-721.

DOI: 10.1016/j.jpowsour.2006.12.019

Google Scholar

[19] R.K. Gautam, K.K. Kar, Synergistic effects of carbon fillers of phenolic resin based composite bipolar plates on the performance of PEM fuel cell, Fuel Cells. 16 (2016) 179-192.

DOI: 10.1002/fuce.201500051

Google Scholar

[20] N.B. Brandt, S.M. Chudinov, Y.G. Ponomarev (ed.), Semimetals: 1. Graphite and its Compounds. Elsevier, (2012).

Google Scholar

[21] M. Ardanuy, M.A. Rodríguez-Perez, I. Algaba, Electrical conductivity and mechanical properties of vapor-grown carbon nanofibers/trifunctional epoxy composites prepared by direct mixing, Composites Part B: Engineering. 42 (2011) 675-681.

DOI: 10.1016/j.compositesb.2011.02.006

Google Scholar