The Effect of Using Baffles on the Rate of Mass Transfer of a Cylindrical Stirred Tank Reactor

Article Preview

Abstract:

Owing to the high mixing capacity, the stirred tank reactor is the key class of reactors in the chemical process industry and pharmaceutical industry. The mass transport nature of a batch stirred tank reactor with a fixed copper wall with a cylinder form was studied using copper dissolution in acidified dichromate which is controlled by diffusion. Variables analyzed included the speed of rotation of the impeller, the shape of the impeller and the physical specifications of the solution and the existence of baffles. The data were correlated for the conditions 3667.323 < Re < 34993.18 and 960 < Sc < 1364, for radial flow by the equation: Sh =0.3453 *Sc1/3*Re0.66 but for axial flow by the equation: Sh =0.5866 *Sc1/3*Re0.59. Through speed of rotation of the impeller increases,it allows the rate of mass transfer from the fixed bed to the solution to rise. The radial-flow turbine is more effective than the axial-flow turbine in increasing the rate of mass transfer. The usage of baffles plays a significant role in rising the rate of mass transfer. Using baffles; the correlation will be Sh =0.0769 *Sc1/3*Re0.84 for radial flow and Sh =0.1157 *Sc1/3*Re0.78 for axial flow. The purpose of this research is to estimate the rate of mass transport that can be required in corrosive reactions, and also to maximize the mass transfer rate that can be achieved in other processes, such as electroplating in presence of baffles.

You might also be interested in these eBooks

Info:

Periodical:

Materials Science Forum (Volume 1008)

Pages:

168-176

Citation:

Online since:

August 2020

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2020 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] M.H. Abdel-Aziz, I.Nirdosh, G.H. Sedahmed. Mass and heat transfer at the outer surface of helical coils under single and two phase flow. Appl Therm Eng.103:713-719(2016).

DOI: 10.1016/j.applthermaleng.2016.04.146

Google Scholar

[2] Z.H,Shi, W.F.Li, K.J.Du, H.Liu, and F.C. Wang, Experimental study of mixing enhancement of viscous liquids in confined impinging jets reactor at low jet Reynolds numbers, Chem. Eng. Sci., 138, 216-226 (2015).

DOI: 10.1016/j.ces.2015.08.014

Google Scholar

[3] A.J. Madden, D.G. Nelson, A novel technique for determining mass transfer coefficients in agitated solid–liquid systems, AIChE J. 10 415–429(1964).

DOI: 10.1002/aic.690100326

Google Scholar

[4] Y. Kato, N. Kamel, Y. Tada, Y. Iwasaki, Y. Nagatsu, S. Iwata, Y.S. Lee, S.T.KOH, Transport phenomena around cylindrical baffles in an agitated vessel measured by an electrochemical technique, J. Chem. Eng. Jpn. 40 611–616(2007).

DOI: 10.1252/jcej.40.611

Google Scholar

[5] D.A.El-Gayar, A.H. Konsowa, Y.A.El-Taweel , H.A. Farag , G.H. Sedahmed. Intensification of the rate of diffusion controlled catalytic and electrochemical reactions in a new stirred tank reactor with a multi cylindrical blade impeller. Chem. Eng. Res. Des. 109 607-617(2016).

DOI: 10.1016/j.cherd.2015.12.019

Google Scholar

[6] M.S. Soliman, S.A. Nosier, M. Hussein, G.H. Sedahmed, A.A. Mubarak, Mass and heat transfer behaviour of a new heterogeneous stirred tank reactor with serpentine tube baffles, Chem. Eng. Res. Des. 124 211–221(2017).

DOI: 10.1016/j.cherd.2017.06.012

Google Scholar

[7] R. Gruber, T. Melin, Mixed conversion in the copper dissolution technique of studying mass transfer, Int. J. Heat Mass Trans. 46 2403–2413(2003).

DOI: 10.1016/s0017-9310(03)00011-5

Google Scholar

[8] T.Mizushina, R.Ito , S.Hiraoka , A.Ibusuki and I.Sakaguchi , Transport phenomena at the wall of agitated vessels, J. of Chem. Eng. of Japan 2 89-94(1969).

DOI: 10.1252/jcej.2.89

Google Scholar

[9] A.H. El-Shazly, S.A. Nosier, M.Z. El-Abd, G.H. Sedahmed, Solid–liquid mass trans-fer at the walls of a rectangular agitated vessel, Chem. Eng. Commun. 158 31–41(1997).

DOI: 10.1080/00986449708936580

Google Scholar

[10] M.H. Mowena, A.A. Zaatout, G.H. Sedahmed, Liquid-solid mass transfer behavior of a new stirred-tank reactor with a packed bed fixed to its wall, Chem. Eng. Technol. 36 603–610(2013).

DOI: 10.1002/ceat.201200049

Google Scholar

[11] A. I. Vogel, A Textbook of Quantitative Inorganic Analysis,, Longmans, London, (1961).

Google Scholar

[12] A.Findlay, J.K. Kitchner, Practical physical chemistry. Longmans, London (1965).

Google Scholar

[13] D.P. Gregory, A.C. Riddiford, Dissolution of copper in sulphuric acid, J. Elec-trochem. Soc. 107 950–956(1960).

Google Scholar

[14] F. Walsh, A First Course in Electrochemical Engineering, The Electrochemical Consultancy, Hants, UK, (1993).

Google Scholar

[15] T.Z. Fahidy , Principles of electrochemical reactor analysis. Elseiver, N.Y (1985).

Google Scholar

[16] D.J. Pickett, Electrochemical reactor design, Elsevier, N.Y (1977).

Google Scholar

[17] D.Hyman , Mixing and agitation. Advances in Chem. Eng. 3 119-202(1962).

Google Scholar

[18] J.H. Rushton, J.Y. Oldshue , Mixing-present theory and practice. Chem. Eng. Prog. 49 161-275(1953).

Google Scholar

[19] M.W. Chudacek. Solid's suspension behaviour in profiled bottom and flat bottom mixing tanks. Chem. Eng. Sci. 40; 385-392(1985).

DOI: 10.1016/0009-2509(85)85100-9

Google Scholar

[20] G.H. Sedahmed, Y.El-Taweel ,M.H. Abdel-Aziz , H.M.El-Naqeara, Mass and heat transfer enhancement at the wall of cylindrical agitated vessel by turbulence promoters . Chem. Eng. and processing 80;43-50(2014).

DOI: 10.1016/j.cep.2014.04.004

Google Scholar