Dielectric and Curing Properties of ZnFe2O4 Loaded Epoxidized Natural Rubber (ENR 25)

Article Preview

Abstract:

Electroceramic with high magnetic properties such as ZnFe2O4 is widely used in many electronic device applications. One of the major drawbacks of electroceramic is the difficulty in molding and processing into desired shapes due to its brittle nature. Flexible electroceramic with the superior process and mold abilities can be made by mixing magnetic ceramic with a flexible matrix, for instance, rubber. In this present study, the aims were to produce ZnFe2O4 loaded epoxidized natural rubber (ENR 25) as well as to determine its electrical and curing properties. The magnetic ceramic of ZnFe2O4 was blended with ENR 25 at different loadings varying from 0 to 120 parts per hundred of rubber (phr) in an interval of 20. The properties of produced composites include scorch time, cure time, torque and dielectric properties were characterised. The results demonstrated that the increase of ZnFe2O4 concentration in ENR 25 leads to a significant increase in the dielectric constant from 4.94 to 5.62 at 1.15 MHz, and decrease in the dielectric loss curves of the composites start from 0.0827 to 0.0586. Furthermore, the results of curing property studies exhibited an increasing pattern of the composite torques, starting from 1.43 to 1.76 dN.m.

You might also be interested in these eBooks

Info:

Periodical:

Materials Science Forum (Volume 1010)

Pages:

292-297

Citation:

Online since:

September 2020

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2020 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] K. A. Malini, E.M. Mohammed, S. Sindhu, P.A. Joy, S.K. Date, S.D. Kulkarni, P. Kurian, and M.R. Anantharaman, Magnetic and processability studies on rubber ferrite composites based on natural rubber and mixed ferrite, J. Mater. Sci. 36, 23 (2001) 5551-5557.

DOI: 10.1007/bf02704011

Google Scholar

[2] V. Blanco-Gutiérrez, M.J. Torralvo-Fernández, and R. Sáez-Puche, Magnetic behavior of ZnFe2O4 nanoparticles: Effects of a solid matrix and the particle size, J. Phys. Chem. C, 114, 4 (2010) 1789-1795.

DOI: 10.1021/jp908395v

Google Scholar

[3] K.J. Kim and S. Tadokoro, Electroactive polymers for robotic applications, Artif. Muscles Sensors, 23(2007) 291.

Google Scholar

[4] S. Salaeh, N. Muensit, P. Bomlai, and C. Nakason, Ceramic/ natural rubber composites: Influence types of rubber and ceramic materials on curing, mechanical, morphological, and dielectric properties, J. Mater. Sci. 46, 6 (2011) 1723-1731.

DOI: 10.1007/s10853-010-4990-6

Google Scholar

[5] N. M. Deraz and A. Alarifi, Microstructure and magnetic studies of zinc ferrite nano-particles, Int. J. Electrochem. Sci. 7, 7 (2012) 6501-6511.

Google Scholar

[6] C. N. Chinnasamy, A. Narayanasamy, N. Ponpandian, K. Chattopadhyay, H. Guerault, and J.M. Greneche, Magnetic properties of nanostructured ferrimagnetic zinc ferrite, J. Phys. Condens. Matter, 12, 35 (2000) 7795.

DOI: 10.1088/0953-8984/12/35/314

Google Scholar

[7] B.T. Poh, C.P. Kwok, and G.H. Lim, Reversion behaviour of epoxidized natural rubber, Eur. Polym. J. 31, 3 (1995) 223-226.

DOI: 10.1016/0014-3057(94)00167-7

Google Scholar

[8] S.T. Sam, H. Ismail, M.N. Ahmad Fauzi, and A. Abu Bakar, The effect of carbon black on the properties of magnetic ferrite filled natural rubber composites, J. Reinf. Plast. Compos. 27, 16-17 (2008) 1893-1908.

DOI: 10.1177/0731684407082545

Google Scholar

[9] V.G. Geethamma, R. Joseph, and S. Thomas, Short coir fiber‐reinforced natural rubber composites: Effects of fiber length, orientation, and alkali treatment, J. Appl. Polym. Sci. 55, 4 (1995) 583-594.

DOI: 10.1002/app.1995.070550405

Google Scholar

[10] S.R. Khimi and K.L. Pickering, A new method to predict optimum cure time of rubber compound using dynamic mechanical analysis, J. Appl. Polym. Sci. 131, 6 (2014) 1-17.

DOI: 10.1002/app.40008

Google Scholar

[11] B. Karaağaç, M. İnal, and V. Deniz, Artificial neural network approach for predicting optimum cure time of rubber compounds, Mater. Des. 30, 5 (2009) 1685-1690.

DOI: 10.1016/j.matdes.2008.07.010

Google Scholar

[12] J.L. Leblanc, Rubber-filler interactions and rheological properties in filled compounds, Prog. Polym. Sci. 27, 4 (2002) 627-687.

DOI: 10.1016/s0079-6700(01)00040-5

Google Scholar

[13] H. Ismail, H.D. Rozman, R.M. Jaffri, and Z.A.M. Ishak, Oil palm wood flour reinforced epoxidized natural rubber composites: The effect of filler content and size, Eur. Polym. J. 33, 10-12 (1997) 1627-1632.

DOI: 10.1016/s0014-3057(97)00020-7

Google Scholar

[14] H. Ismail, A. Rusli, and A.A. Rashid, Maleated natural rubber as a coupling agent for paper sludge filled natural rubber composites, Polym. Test. 24, 7 (2005) 856-862.

DOI: 10.1016/j.polymertesting.2005.06.011

Google Scholar

[15] A. Ciesielski, An introduction to rubber technology. iSmithers Rapra Publishing, (1999).

Google Scholar

[16] I. Surya and H. Ismail, Alkanolamide as a novel accelerator and vulcanising agent in carbon black-filled polychloroprene rubber compounds, Plast. Rubber Compos. 45, 7 (2016) 287-293.

DOI: 10.1080/14658011.2016.1187477

Google Scholar

[17] S. Wolff, Chemical aspects of rubber reinforcement by fillers, Rubber Chem. Technol. 69, 3 (1996) 325-346.

DOI: 10.5254/1.3538376

Google Scholar

[18] H. Ismail, S.T. Sam, A.F. Mohd Noor, and A.A. Bakar, Properties of ferrite-filled natural rubber composites, Polym. - Plast. Technol. Eng. 46, 6, (2007) 641-650.

DOI: 10.1080/03602550701305054

Google Scholar

[19] K.H. Prema, P.Kurian, P.A. Joy, and M.R. Anantharaman, Physicomechanical and magnetic properties of neoprene based rubber ferrite composites, Polym. - Plast. Technol. Eng. 47, 2 (2008) 137-146.

DOI: 10.1080/03602550701815946

Google Scholar

[20] M.A. Sulaiman, S.D. Hutagalung, M.F. Ain, and Z.A. Ahmad, Dielectric properties of Nb-doped CaCu3Ti4O12 electroceramics measured at high frequencies, J. Alloys Compd. 493, 1–2 (2010) 486-492.

DOI: 10.1016/j.jallcom.2009.12.137

Google Scholar

[21] M.A. Sulaiman, W. Panwiriyarat, B.L.C. Jie, M.N. Masri, and M. Yusuff, Mechanical and Electrical Properties of TiO2 Loaded Vulcanized Natural Rubber, Int. J. Electroact. Mater. 4 (2016) 39-43.

Google Scholar