Synthesis of Lanthanum Orotate and its Application as PVC Thermal Stabilizer

Mansurjon Juraev; Xiao Ya Zhou; Xiao Tao Ma; Cheng Fang; Ye Qian Ge; Qiu Feng Ye; Feng Ye

doi:10.4028/www.scientific.net/MSF.1032.57

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HomeMaterials Science ForumMaterials Science Forum Vol. 1032Synthesis of Lanthanum Orotate and its Application...

Synthesis of Lanthanum Orotate and its Application as PVC Thermal Stabilizer

Abstract:

The structure of basic lanthanum orotate (LaOr) were characterized by elemental analysis and infrared spectroscopy. The thermal stability of polyvinyl chloride (PVC) was further studied by Congo red method, oven discoloration method and thermogravimetric analysis. The results showed that LaOr could prolong the oven discoloration time of PVC, and the color was not completely blackened until 120 min. It has a good synergetic effect with dibenzoyl methane (DBM), and the best effect is achieved when LaOr/DBM ratio is 1.8/1.2. The thermal decomposition kinetics experiment showed that adding DBM can effectively improve the activation energy of PVC/LaOr. The stabilization mechanism of PVC was studied by absorbing HCl method and infrared spectroscopy. The results showed that LaOr could not only replace the unstable chlorine atoms on PVC, but also promote the long-term thermal stability of PVC by absorbing HCl.

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Materials Science and Industrial Applications III

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Materials Science Forum (Volume 1032)

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57-63

DOI:

https://doi.org/10.4028/www.scientific.net/MSF.1032.57

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Online since:

May 2021

Authors:

Mansurjon Juraev, Xiao Ya Zhou, Xiao Tao Ma, Cheng Fang, Ye Qian Ge, Qiu Feng Ye, Feng Ye*

Keywords:

Lanthanum, LaOr, Poly(Vinyl Chloride), Synergetic Effect, Thermal Stabilizer

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References

[1] L. Fang, Y.H. Song, X.N. Zhu, Q. Zheng, Influence of lanthanum stearate as a co-stabilizer on stabilization efficiency of calcium/zinc stabilizers to polyvinyl chloride, Polym. Degrad. Stabil. 94 (2009) 845-850.

DOI: 10.1016/j.polymdegradstab.2009.01.024

Google Scholar

[2] M. Wang, S.H. Li, H.Y. Ding, et al., Construction of efficient tung-oil-based thermal stabilizers bearing imide and epoxy groups for PVC, New. J. Chem. 44(2020) 4538.

DOI: 10.1039/c9nj05777c

Google Scholar

[3] M. Li, C. Duan, H.O. Wang, et al., Lanthanum histidine with pentaerythritol and zinc stearate as thermal stabilizers for poly(vinyl chloride), J. Appl. Polym. Sci. 133(2016) 42878-42885.

DOI: 10.1002/app.42878

Google Scholar

[4] Q.F. Ye, X.T. Ma, B.B.Li, et al., Development and Investigation of Lanthanum Sulfadiazine with Calcium Stearate and Epoxidised Soyabean Oil as Complex Thermal Stabilizers for Stabilizing Poly(vinyl chloride), Polymers. 11(2019) 531.

DOI: 10.3390/polym11030531

Google Scholar

[5] F. Ye, Feng; Q.F. Ye, Qiufeng; H.H. Zhan, et al., Synthesis and Study of Zinc Orotate and Its Synergistic Effect with Commercial Stabilizers for Stabilizing Poly(Vinyl Chloride), Polymers. 11(2019) 194.

DOI: 10.3390/polym11020194

Google Scholar

[6] F. Ye, Q.F. Ye, X.J. Guo, et al., Investigation of lanthanum trioxypurine with zinc stearate and pentaerythritol as complex thermal stabilizers for poly(vinyl chloride), J. Vinyl. Addit. Techn. 25 (2019) 347-358.

DOI: 10.1002/vnl.21702

Google Scholar

[7] F. Ye, X. J. Guo, H.H. Zhan, et al., The synergistic effect of zinc urate with calcium stearate and commercial assistant stabilizers for stabilizing poly(vinyl chloride), Polym. Degrad. Stabil. 156 (2018) 193-201.

DOI: 10.1016/j.polymdegradstab.2018.08.012

Google Scholar

[8] W.H. Ye, Q.H. Chen, Z. Chen, et al., Improvement of the processability and thermal stability of poly(vinyl chloride) with 5,6-diamino-1,3-dimethyluracil, J. Appl. Polym. Sci.137(2020) e49319.

DOI: 10.1002/app.49319

Google Scholar

[9] B. Ma, X. Wang, S.Y. Lu, H.W. He, et al., A novel double agent of triazole-based zinc-containing complex which constituted Zn/Zn stabilizer system with zinc stearate as thermal stabilizer for poly(vinyl chloride), Polym. Degrad. Stabil. 168(2019)108953.

DOI: 10.1016/j.polymdegradstab.2019.108953

Google Scholar

[10] D.G. Li, M. Zhou, L.H. Xie, et al., Tang, Synergism of pentaerythritol-zinc with beta-diketone and calcium stearate in poly(vinyl chloride) thermal stability, Polym. J. 45(2013) 775-782.

DOI: 10.1038/pj.2012.210

Google Scholar

[11] N.A. Mohamed, Antimicrobial itaconimido aromatic hydrazide derivatives for inhibition of the thermal degradation of rigid PVC, Polym. Bull. 45(2013)775-782.

DOI: 10.1007/s00289-018-2486-8

Google Scholar

[12] Y.N. Jiang, Z.H. Yang, Q.S. Su, et al., Preparation of Magnesium-Aluminum Hydrotalcite by Mechanochemical Method and Its Application as Heat Stabilizer in poly(vinyl chloride), Materials. 13(2020) 5223.

DOI: 10.3390/ma13225223

Google Scholar