Effect of Etching and Electroless Plating Time on Contact Angle of Acrylonitrile Butadiene Styrene for 3D-Printed Substrates

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Abstract:

Acrylonitrile Butane Styrene (ABS) is a type of polymer that can be metallized with metal through the electroless plating process so as to produce a strong and economical layer bond compared to metal. In this study, ABS plastic will be coated with nickel and the contact angle of ABS after the coating process will be examined. The first step is the etching process for 55 and 75 minutes using chromic acid to improve the adhesiveness and uniformity of the coating metal later. After the etching process is complete, then the surface roughness test is carried out using Mitutoyo SJ 201 Surface Roughness. Furthermore, the activation process with stannous chloride as a catalyst is carried out to accelerate the deposition of metal particles on the substrate surface so that during the electroless plating process the polymer turns into a conductor. Then the electroless plating process with time variations of 15, 25, 35, 45, 55 minutes using nickel sulfate, ammonium chloride, sodium hypophosphite, and sodium hydroxide to deposit nickel metal on the ABS surface. The results of the coating are then analyzed for surface topography using AFM and SEM, as well as investigating the contact angle of the droplets that are dropped on the coated ABS surface. It can be said that the etching variation of 55 minutes electroless nickel plating 75 minutes is the most hydrophobic because it has the largest contact angle and the smoothest surface topography compared to other variations.

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Materials Science Forum (Volume 1051)

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119-124

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January 2022

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© 2022 Trans Tech Publications Ltd. All Rights Reserved

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[1] T. Rayna, L. Striukova, From rapid prototyping to home fabrication: How 3D printing is changing business model innovation, Technol. Forecasting Soc. Change. 102(2016) 214-224.

DOI: 10.1016/j.techfore.2015.07.023

Google Scholar

[2] K. Singh, Experimental study to prevent the warping of 3D models in fused deposition modeling, Int. J. Plastics Technol.  22(2018)177–184.

DOI: 10.1007/s12588-018-9206-y

Google Scholar

[3] C.H. Qing, H. Qin, Advances in fused deposition modeling of discontinuous fiber/polymer composites, Current Opinion in Solid State and Materials Science, 24(2020)100867.

DOI: 10.1016/j.cossms.2020.100867

Google Scholar

[4] S. Biswas, A. Schoeberl, Y. Hao, J. Reiprich, T. Stauden, J. Pezoldt, H.O. Jacobs, Integrated multilayer stretchable printed circuit boards paving the way for deformable active matrix, Nature Comm.,  10(2019)article number: 4909.

DOI: 10.1038/s41467-019-12870-7

Google Scholar

[5] D.M. Elsayed, S.M. Abdelbasir, H.M. Abdel-Ghafar, B.A. Salah, S.A. Sayed, Silver and copper nanostructured particles recovered from metalized plastic waste for antibacterial applications, J. Enviro. Chem. Eng, 8(2020)103826.

DOI: 10.1016/j.jece.2020.103826

Google Scholar

[6] O.S.I. Fayomi, I.G. Akande, A.A. Sode, Corrosion prevention of metals via electroless nickel coating: A review,  J. Phys.: Conf. , 1378(2019)022063.

DOI: 10.1088/1742-6596/1378/2/022063

Google Scholar

[7] S.C. Domenech, E. Lima Jr., V. Drago, J.C. De Lima, N.G. Borges Jr., A.O.V. Avila, V. Soldi, Electroless plating of nickel–phosphorous on surface-modified poly(ethylene terephthalate) films, App. Surf. Sci. (2003)238-250.

DOI: 10.1016/s0169-4332(03)00815-8

Google Scholar

[8] W. Giurlani, G. Zangari, F. Gambinossi, M. Passaponti, E. Salvietti, F. Di Benedetto, S. Caporali, M. Innocenti, Electroplating for decorative applications: recent trends in research and development, Coatings, 8(2018)260.

DOI: 10.3390/coatings8080260

Google Scholar

[9] A. Ojstršek, O. Plohl, S. Gorgieva, M. Kureˇciˇc, U. Janˇciˇc, S. Hribernik, D. Fakin, Metallisation of textiles and protection of conductive layers: an overview of application techniques, Sensors, 21(2021)3508.

DOI: 10.3390/s21103508

Google Scholar

[10] A. Thakur, S. Gharde, B. Kandasubramanian, Electroless nickel fabrication on surface modified magnesium substrates, Defence Technol., 15(2019)636-644.

DOI: 10.1016/j.dt.2019.04.006

Google Scholar

[11] C. Feng, H. Janssen, Impact of water repellent agent concentration on the effect of hydrophobization on building materials, J. Building Eng., 39(2021)102284.

DOI: 10.1016/j.jobe.2021.102284

Google Scholar

[12] T. Zhao, L. Jiang, Contact angle measurement of natural materials, Colloids and Surf. B: Biointerfaces, 161(2018)324-330.

DOI: 10.1016/j.colsurfb.2017.10.056

Google Scholar