For Libraries For Publication Open Access Downloads About Us Contact Us
Paper Titles
Synthesis of Iron Nanoparticles Capped by Citric Acid or Citrates and its Characterizations
p.107
Microstructure and Hardness Properties of Hardfacing Overlays Deposited by Shielded Metal Arc Welding on Low Carbon Steel Plate
p.113
Phase Composition, Crystal Structure and Microwave Dielectric Properties of Nb-Doped Yttrium Aluminum Garnet Ceramics
p.123
RKKY Interaction in Spin Valve Structure with LaAlO3 Spacer
p.131
The Distorted Octahedral and Magnetocrystalline Anisotropy of FeMnO3 by Stoner-Wohlfarth Model
p.139
Crystal Structure and Magnetic Properties of SrCoO3-δ with Oxygen Deficiency (δ ≈ 0.23)
p.147
The Effect of Alkali-Fluoride on the Photoluminescence Properties of Tb3+ Doped on Phosphate Glass Medium
p.155
The Effect of NaF on the Photoluminence Properties of Sammarium Ion Doped on Fluoro-Borophosphate Glass Medium
p.165
Physical and Stimulated Emission Cross Section (SEC) Properties of Nd3+ Doped Lithium Fluorophosphate (LFP) Glasses
p.175

The Effect of Alkali-Fluoride on the Photoluminescence Properties of Tb3+ Doped on Phosphate Glass Medium

Article Preview

Abstract:

The effect of alkali fluoride on the photoluminescence properties of Tb3+ doped on the phosphate glass was discovered. However, the composition of the glass samples were 20Li2O–10AlF3–69P2O5–1Tb2O3 (LAPTb) and 20Li2O–10AlF3–10NaF–59P2O5–1Tb2O3 (LANPTb). To study optical properties were examined through their absorption and luminescence spectra. Luminescence spectra were investigated by photoluminescence. Characteristic luminescence bands corresponding to electronic transitions of terbium ions (Tb3+) were detected under two direct excitations of Tb3+ ions. Upon 377 nm excitation, the glass samples were obtained transition terbium 5D4 → 7F5 at 544 nm showed a green laser. The decay time Tb3+ for the 5D4 level has been confirmed and the result was 2.865 ms and 2.982 ms corresponding to LAPTb was LANPTb, respectively. The green laser application has been investigated by a CIE-color-coordinates diagram with a color purity is ~73%.

You might also be interested in these eBooks
The 4th International Conference on Science and Technology Applications View Preview
Functional Composites, Ceramics and Glasses View Preview

Info:

Periodical:

Materials Science Forum (Volume 1080)

Pages:

155-164

DOI:

https://doi.org/10.4028/p-vp9t5x

Citation:

Cite this paper

Online since:

January 2023

Authors:

Juniar Hutahaean*, Juniastel Rajagukguk, Elyzabeth Simanullang, Chayani S. Sarumaha, Jakrapong Kaewkhao

Keywords:

CIE, Color Purity, Luminescence, Phosphate Glass, Tb3+ Ions

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

© 2023 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

References

[1] P. Suthanthirakumar, K. Marimuthu, Investigations on spectroscopic properties of Dy3+ doped zinc telluro-fluoroborate glasses for laser and white LED applications, J. Mol. Struct. 1125 (2016) 443–452.

DOI: 10.1016/j.molstruc.2016.06.080

Google Scholar

[2] R. Situmorang, Rahmaniar, D.D. Panggabean, C. Sarumaha, J. Kaewkhao, Sunaryono, J. Rajagukguk, The Dy2O3 Effect Study on Spectroscopy and Optical Properties of PbiNaGd Glass for Optical Amplification, in: J. Phys. Conf. Ser., (2020).

DOI: 10.1088/1742-6596/1428/1/012067

Google Scholar

[3] K. Jha, M. Jayasimhadri, Structural and emission properties of Eu3+-doped alkaline earth zinc-phosphate glasses for white LED applications, J. Am. Ceram. Soc. 100 (2017) 1402–1411.

DOI: 10.1111/jace.14668

Google Scholar

[4] C.S. Sarumaha, N. Wantana, J. Rajagukguk, J. Kaewkhao, Optical absorption and photoluminescence investigations Dy3+ doped oxyfluoride phosphate glass system for active laser medium and solid-state lighting materials, in: J. Phys. Conf. Ser., (2021).

DOI: 10.1088/1742-6596/2013/1/012020

Google Scholar

[5] Z. Zhang, Y. Zhang, C. Wang, Z. Feng, W. Zhang, H. Xia, White Light Emission Characteristics of Tb3+/Sm3+ Co-Doped Glass Ceramics Containing YPO4 Nanocrystals, J. Mater. Sci. Technol. 33 (2017) 432–437.

DOI: 10.1016/j.jmst.2016.10.002

Google Scholar

[6] G. Lakshminarayana, S.O. Baki, A. Lira, U. Caldiño, A.N. Meza-Rocha, I. V. Kityk, A.F. Abas, M.T. Alresheedi, M.A. Mahdi, Effect of alkali/mixed alkali metal ions on the thermal and spectral characteristics of Dy3+:B2O3-PbO-Al2O3-ZnO glasses, J. Non. Cryst. Solids. 481 (2018) 191–201.

DOI: 10.1016/j.jnoncrysol.2017.10.047

Google Scholar

[7] N. Deopa, A.S. Rao, M. Gupta, G. Vijaya Prakash, Spectroscopic investigations of Nd3+ doped Lithium Lead Alumino Borate glasses for 1.06 μm laser applications, Opt. Mater. (Amst). 75 (2018) 127–134.

DOI: 10.1016/j.optmat.2017.09.047

Google Scholar

[8] N. Luewarasirikul, H.J. Kim, P. Meejitpaisan, J. Kaewkhao, White light emission of dysprosium doped lanthanum calcium phosphate oxide and oxyfluoride glasses, Opt. Mater. (Amst). 66 (2017) 559–566.

DOI: 10.1016/j.optmat.2017.02.049

Google Scholar

[9] M. Shoaib, G. Rooh, R. Rajaramakrishna, N. Chanthima, N. Kiwsakunkran, H.J. Kim, J. Kaewkhao, S. Tuscharoen, Comparative study of Sm3+ ions doped phosphate based oxide and oxy-fluoride glasses for solid state lighting applications, J. Rare Earths. 37 (2019) 374–382.

DOI: 10.1016/j.jre.2018.09.008

Google Scholar

[10] S. Damodaraiah, V.R. Prasad, Y.C. Ratnakaram, Investigation of Green and 1.53 μm emission characteristics of Er3+ doped bismuth phosphate glasses for laser applications, J. Alloys Compd. 741 (2018) 269–280.

DOI: 10.1016/j.jallcom.2018.01.158

Google Scholar

[11] N.N. B., D. S., R.P. V., V.L. Vijaya, Y.C. Ratnakaram, Judd-Ofelt analysis and luminescence studies on Dy3+ -doped different phosphate glasses for white light emitting material applications, Optik (Stuttg). 192 (2019) 162980.

DOI: 10.1016/j.ijleo.2019.162980

Google Scholar

[12] Y.C. Ratnakaram, S. Babu, L.K. Bharat, C. Nayak, Fluorescence characteristics of Nd3+ doped multicomponent fluoro-phosphate glasses for potential solid-state laser applications, J. Lumin. 175 (2016) 57–66.

DOI: 10.1016/j.jlumin.2016.02.009

Google Scholar

[13] J. Rajagukguk, C.S. Sarumaha, N. Chanthima, N. Wantana, S. Kothan, N. Wongdamnern, J. Kaewkhao, Radio and photo luminescence of Dy3+ doped lithium fluorophosphate scintillating glass, Radiat. Phys. Chem. 185 (2021) 109520.

DOI: 10.1016/j.radphyschem.2021.109520

Google Scholar

[14] H.I. Francisco-Rodriguez, A. Lira, O. Soriano-Romero, A.N. Meza-Rocha, S. Bordignon, A. Speghini, R. Lozada-Morales, U. Caldiño, Lithium-aluminum-zinc phosphate glasses activated with Tb3+ and Tb3+/Eu3+ for green laser medium, reddish-orange and white phosphor applications, Opt. Mater. (Amst). 79 (2018) 358–365.

DOI: 10.1016/j.optmat.2018.04.004

Google Scholar

[15] W. Rittisut, N. Wantana, Y. Ruangtaweep, P. Mool-am-kha, S. Rujirawat, P. Manyum, R. Yimnirun, P. Kidkhunthod, A. Prasatkhetragarn, S. Kothan, H.J. Kim, J. Kaewkhao, The radioluminescence and photoluminescence behaviour of lithium alumino borate glasses doped with Tb2O3 and Gd2O3 for green luminescence applications, Opt. Mater. (Amst). 121 (2021).

DOI: 10.1016/j.optmat.2021.111437

Google Scholar

[16] M.Vijayakumar, K.Viswanathan, K.Marimuthu, Structural and optical studies on Dy3+:Tb3+ co-doped zinc leadfluoro-borophosphate glasses for white light applications, J. Alloys Compd. 745 (2018) 306–318.

DOI: 10.1016/j.jallcom.2018.02.211

Google Scholar

[17] J. Pisarska, A. Kos, M. Sołtys, A. Górny, E. Pietrasik, W.A. Pisarski, Spectroscopy and energy transfer in Tb3+/Sm3+-co-doped lead borate glasses, J. Lumin. 195 (2018) 87–95.

DOI: 10.1016/j.jlumin.2017.11.020

Google Scholar

[18] C.R. Kesavulu, H.J. Kim, S.W. Lee, J. Kaewkhao, E. Kaewnuam, N. Wantana, Luminescence properties and energy transfer from Gd3+ to Tb3+ ions in gadolinium calcium silicoborate glasses for green laser application, J. Alloys Compd. 704 (2017) 557–564.

DOI: 10.1016/j.jallcom.2017.02.056

Google Scholar

[19] Q. Shi, F. You, S. Huang, H. Peng, Y. Huang, Y. Tao, Excited state dynamics of Gd3+ and energy transfer efficiency from Gd3+ to Tb3+ in (La, Gd)PO4:Tb3+, J. Lumin. 152 (2014) 138–141.

DOI: 10.1016/j.jlumin.2014.01.064

Google Scholar

[20] J. Hutahaean, J. Rajagukguk, D. Rajagukguk, C. Sarumaha, N. Wantana, J. Kaewkhao, The Effect of Sodium Fluoride in Lithium Fluorophosphate (LFP) Glasses Doped with Nd2O3 Ion, Integr. Ferroelectr. 224 (2022) 100–109.

DOI: 10.1080/10584587.2022.2035600

Google Scholar

[21] C.S. Sarumaha, J. Rajagukguk, N. Wantana, N. Chanthima, R. Rajaramakrishna, J. Kaewkhao, White Light Emission of Dy3+ Doped Oxy-Fluoride Phosphate Glass System for Active Laser Medium, Integr. Ferroelectr. 224 (2022) 1–12.

DOI: 10.1080/10584587.2022.2035591

Google Scholar

[22] S. Ravangvong, N. Chanthima, R. Rajaramakrishna, H.J. Kim, N. Sangwaranatee, J. Kaewkhao, Dy3+ ions doped (Na2O/NaF)-Gd2O3–P2O5 glasses for solid state lighting material applications, Solid State Sci. 97 (2019).

DOI: 10.1016/j.solidstatesciences.2019.105972

Google Scholar

[23] J. Rajagukguk, D.H. Rajagukguk, R.S. Gultom, P. Simamora, R. Situmorang, C. Sarumaha, Structure and emission properties of Nd3+ doped oxyfluorophosphate glasses, in: J. Phys. Conf. Ser., (2022).

DOI: 10.1088/1742-6596/2193/1/012007

Google Scholar

[24] C.S. Sarumaha, J. Rajagukguk, J. Tongdang, N. Chanthima, H.J. Kim, S. Kothan, J. Kaewkhao, Effect of Gd2O3 in Li2O–AlF3–CaF2–P2O5–Eu2O3 glasses for laser medium and X-rays detection material applications, Radiat. Phys. Chem. 199 (2022) 110362.

DOI: 10.1016/j.radphyschem.2022.110362

Google Scholar

[25] J. Rajagukguk, J.H. Panggabean, M. Djamal, C.S. Sarumaha, J. Kaewkhao, Energy transfer and broad-band luminescence of Nd3+-Er3+ co-doped Lithium Fluorophosphate (LFP) glasses, Opt. Mater. (Amst). 125 (2022).

DOI: 10.1016/j.optmat.2022.112007

Google Scholar

[26] M. Shoaib, G. Rooh, N. Chanthima, R. Rajaramakrishna, H.J. Kim, C. Wongdeeying, J. Kaewkhao, Intriguing energy transfer mechanism in oxide and oxy-fluoride phosphate glasses, Opt. Mater. (Amst). 88 (2019) 429–444.

DOI: 10.1016/j.optmat.2018.11.059

Google Scholar

[27] K. Swapna, S. Mahamuda, A.S. Rao, M. Jayasimhadri, S. Shakya, G.V. Prakash, Tb3+ doped Zinc Alumino Bismuth Borate glasses for green emitting luminescent devices, J. Lumin. 156 (2014) 180–187.

DOI: 10.1016/j.jlumin.2014.08.019

Google Scholar

[28] P. Xu, Z. Fu, S. Fan, H. Lin, C. Li, G. Yao, Q. Chen, Y. Zhou, F. Zeng, Study on the sensitization of Gd3+ on Ce3+/Tb3+ co-doped GBS scintillating glass, J. Non. Cryst. Solids. 481 (2018) 441–446.

DOI: 10.1016/j.jnoncrysol.2017.11.028

Google Scholar

[29] C. Madhukar Reddy, B. Deva Prasad Raju, N. John Sushma, N.S. Dhoble, S.J. Dhoble, A review on optical and photoluminescence studies of RE3+ (RE=Sm, Dy, Eu, Tb and Nd) ions doped LCZSFB glasses, Renew. Sustain. Energy Rev. 51 (2015) 566–584.

DOI: 10.1016/j.rser.2015.06.025

Google Scholar

[30] C. Zuo, J. Huang, S. Liu, A. Xiao, Y. Shen, X. Zhang, Z. Zhou, L. Zhu, Luminescence and energy transfer of Tb3+–doped BaO–Gd2O3–Al2O3–B2O3–SiO2 glasses, Spectrochim. Acta - Part A Mol. Biomol. Spectrosc. 187 (2017) 181–185.

DOI: 10.1016/j.saa.2017.06.059

Google Scholar

[31] W.T. Carnall, P.R. Fields, K. Rajnak, Electronic energy levels of the trivalent lanthanide aquo ions. III. Tb3+, J. Chem. Phys. 49 (1968) 4412–4423.

DOI: 10.1063/1.1669895

Google Scholar

[32] N. Deopa, A.S. Rao, Photoluminescence and energy transfer studies of Dy3+ ions doped lithium lead alumino borate glasses for w-LED and laser applications, J. Lumin. 192 (2017) 832–841.

DOI: 10.1016/j.jlumin.2017.07.052

Google Scholar

[33] G. Lakshminarayana, K.M. Kaky, S.O. Baki, A. Lira, U. Caldiño, I. V. Kityk, M.A. Mahdi, Optical absorption, luminescence, and energy transfer processes studies for Dy3+/Tb3+ -codoped borate glasses for solid-state lighting applications, Opt. Mater. (Amst). 72 (2017) 380–391.

DOI: 10.1016/j.optmat.2017.06.030

Google Scholar

[34] S. Kaur, N. Deopa, A. Prasad, R. Bajaj, A.S. Rao, Intense green emission from Tb3+ ions doped zinc lead alumino borate glasses for laser and w-LEDs applications, Opt. Mater. (Amst). 84 (2018) 318–323.

DOI: 10.1016/j.optmat.2018.07.020

Google Scholar

© 2025 Trans Tech Publications Ltd. All rights are reserved, including those for text and data mining, AI training, and similar technologies. For open access content, terms of the Creative Commons licensing CC-BY are applied.
Scientific.Net is a registered trademark of Trans Tech Publications Ltd.