Physical and Stimulated Emission Cross Section (SEC) Properties of Nd3+ Doped Lithium Fluorophosphate (LFP) Glasses

Article Preview

Abstract:

This work describes a study that utilizes the Nd3+ ions (1.0 mol%) doped in glass material with the chemical formula 59P2O5 - 20Li2O - 10AlF3 - 10NaF. To obtain a glass medium with good homogeneity, all samples in the form of powder were mixed thoroughly and melted at 1100 °C for 3 hours. This sample preparation method is widely known as the melt-quenching method. The cutt and polish process is carried out to obtain a proportional and highly transparent of glass sample. Several parameters of physical properties were measured and then calculated to obtain the values of other parameters. The optical properties and stimulated emission cross sections (ECS) of a glass medium were obtained by observing the absorption and emission spectra. Based on the analysis of ECS, it was found that the radiative lifetime (τR) for Nd3+ ions experimentally and calculated were 132μs and 248μs respectively. Meanwhile, the quantum efficiency is achieved up to 53%

You might also be interested in these eBooks

Info:

Periodical:

Materials Science Forum (Volume 1080)

Pages:

175-181

Citation:

Online since:

January 2023

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2023 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Rajagukguk, J., Sarumaha, C. S., Chanthima, N., Wantana, N., Kothan, S., Wongdamnern, N., & Kaewkhao, J. (2021). Radio and photo luminescence of Dy3+ doped lithium fluorophosphate scintillating glass. Radiation Physics and Chemistry, 185. https://doi.org/10.1016/j.radphyschem.2021.109520.

DOI: 10.1016/j.radphyschem.2021.109520

Google Scholar

[2] Linganna, K., Viswanath, C. S. D., Narro-Garcia, R., Ju, S., Han, W. T., Jayasankar, C. K., & Venkatramu, V. (2015). Thermal and optical properties of Nd3+ ions in K-Ca-Al fluorophosphate glasses. Journal of Luminescence, 166, 328–334. https://doi.org/10.1016/j.jlumin.2015.05.024.

DOI: 10.1016/j.jlumin.2015.05.024

Google Scholar

[3] Donya, Hossam, and T. A. Taha. Preparation, structure and optical properties of ZnTe and PbTe nanocrystals grown in fluorophosphate glass., Journal of Materials Science: Materials in Electronics 29, no. 10 (2018): 8610-8616.

DOI: 10.1007/s10854-018-8875-9

Google Scholar

[4] Rajagukguk, J., Situmorang, R., Fitrilawati, Djamal, M., Rajaramakrishna, R., Kaewkhao, J., & Minh, P. H. (2019). Structural, spectroscopic and optical gain of Nd3+ doped fluorophosphate glasses for solid state laser application. Journal of Luminescence, 216. https://doi.org/10.1016/j.jlumin.2019.116738.

DOI: 10.1016/j.jlumin.2019.116738

Google Scholar

[5] Ismail, Mahmoud M., Inas K. Batisha, Lidia Zur, Alessandro Chiasera, Maurizio Ferrari, and Anna Lukowiak. Optical properties of Nd3+-doped phosphate glasses., Optical Materials 99 (2020): 109591.

DOI: 10.1016/j.optmat.2019.109591

Google Scholar

[6] El-Maaref, A. A., Shimaa Badr, Kh S. Shaaban, EA Abdel Wahab, and M. M. ElOkr. Optical properties and radiative rates of Nd3+ doped zinc-sodium phosphate glasses., Journal of Rare Earths 37, no. 3 (2019): 253-259.

DOI: 10.1016/j.jre.2018.06.006

Google Scholar

[7] Shanmugavelu, B., Venkatramu, V., & Ravi Kanth Kumar, V. v. (2014). Optical properties of Nd3+ doped bismuth zinc borate glasses. Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 122, 422–427. https://doi.org/10.1016/j.saa.2013.11.051.

DOI: 10.1016/j.saa.2013.11.051

Google Scholar

[8] Karunakaran, R. T., K. Marimuthu, S. Arumugam, S. Surendra Babu, S. F. Leon-Luis, and C. K. Jayasankar. Structural, optical absorption and luminescence properties of Nd3+ ions in NaO-NaF borate glasses., Optical materials 32, no. 9 (2010): 1035-1041.

DOI: 10.1016/j.optmat.2010.02.026

Google Scholar

[9] Megala, Rajesh, T. Gowthami, N. John Sushma, S. Kamala, and B. Deva Prasad Raju. A study of low threshold and high gain Nd3+ ions doped SiO2-B2O3-Na2CO3-NaF-CaF2 glasses for NIR laser applications., Infrared Physics & Technology 90 (2018): 221-229.

DOI: 10.1016/j.infrared.2018.03.015

Google Scholar

[10] Ratnakaram, Y.C., Balakrishna, A., Rajesh, D. and Seshadri, M., 2012. Influence of modifier oxides on spectroscopic properties of Sm3+ doped lithium fluoroborate glass. Journal of Molecular Structure, 1028, pp.141-147.

DOI: 10.1016/j.molstruc.2012.05.071

Google Scholar

[11] Balakrishna, A., Rajesh, D. and Ratnakaram, Y.C., 2013. Structural and optical properties of Nd3+ in lithium fluoro-borate glass with relevant modifier oxides. Optical Materials, 35(12), pp.2670-2676.

DOI: 10.1016/j.optmat.2013.08.004

Google Scholar

[12] Venkateswarlu, M., Mahamuda, S., Swapna, K., Prasad, M.V.V.K.S., Rao, A.S., Babu, A.M., Shakya, S. and Prakash, G.V., 2015. Spectroscopic studies of Nd3+ doped lead tungsten tellurite glasses for the NIR emission at 1062 nm. Optical Materials, 39, pp.8-15.

DOI: 10.1016/j.optmat.2014.10.031

Google Scholar

[13] Hutahaean, J., Rajagukguk, J., Rajagukguk, D., Sarumaha, C., Wantana, N. and Kaewkhao, J., 2022. The Effect of Sodium Fluoride in Lithium Fluorophosphate (LFP) Glasses Doped with Nd2O3 Ion. Integrated Ferroelectrics, 224(1), pp.100-109.

DOI: 10.1080/10584587.2022.2035600

Google Scholar

[14] M. Shwetha and B. Eraiah, Influence of Er3+ ions on the physical, structural, optical, and thermal properties of ZnO–Li2O–P2O5 glasses,, Appl. Phys. A Mater. Sci. Process., vol. 125, no. 3, Mar. 2019,.

DOI: 10.1007/s00339-019-2481-4

Google Scholar

[15] C. S. Sarumaha et al., Effect of Gd2O3 in Li2O–AlF3–CaF2–P2O5–Eu2O3 glasses for laser medium and X-rays detection material applications,, Radiat. Phys. Chem., vol. 199, no. June, p.110362, Oct. 2022,.

DOI: 10.1016/j.radphyschem.2022.110362

Google Scholar

[16] S. Ravangvong, N. Chanthima, R. Rajaramakrishna, H. J. Kim, and J. Kaewkhao, Effect of sodium oxide and sodium fluoride in gadolinium phosphate glasses doped with Eu2O3 content,, J. Lumin., vol. 219, Mar. 2020,.

DOI: 10.1016/j.jlumin.2019.116950

Google Scholar

[17] C. S. Sarumaha, J. Rajagukguk, N. Wantana, N. Chanthima, R. Rajaramakrishna, and J. Kaewkhao, White Light Emission of Dy 3+ Doped Oxy-Fluoride Phosphate Glass System for Active Laser Medium,, Integr. Ferroelectr., vol. 224, no. 1, p.1–12, Mar. 2022,.

DOI: 10.1080/10584587.2022.2035591

Google Scholar

[18] C. R. Kesavulu et al., Spectroscopic investigations of Nd3+doped gadolinium calcium silica borate glasses for the NIR emission at 1059 nm,, J. Alloys Compd., vol. 695, p.590–598, 2017,.

DOI: 10.1016/j.jallcom.2016.11.002

Google Scholar