Physical Properties Study of Sodium Doped Boro-Tellurite (Na₂O: TeO₂-B₂O₃-ZnO) Glasses

Abstract:

Five boro-tellurite glasses with chemical formula 55TeO₂-(12-x)B₂O₃-32ZnO-(1+x)Na₂O (TZBN), (x= 0; 1; 2; 3; 4; mole%) were successfully synthesized by conventional melt-quenching technique. The physical properties of the glass was studied to understand effect of partial substitution between B₂O₃ and Na₂O. The density was measured using pycnometer based on Archimedes law. The other physical properties can be obtained by assisted some mathematical equation. Refer to the measurement, the density was found decreased by 4.905 to 4.590 gr/cm³ because the molecular weight difference between B₂O₃ and Na₂O. Meanwhile the molar volume increased by 25.05 to 27.11 cm³/mole due to higher atomic radii of Na rather than B which raise NBO inside the glass network. Meanwhile, OPD, V_o, polaron radius, inter-ionic distance, packing density,and number of bond per unit volume consequently have been decreased. While the Field strength has increase due to stronger Na-O bonds. Reflects from the results the TZBN glasses could be used as active material for laser.

• Periodical: Materials Science Forum (Volume 1118)
• Pages: 3-10
• DOI: https://doi.org/10.4028/p-qiZ4BJ
• Online since: March 2024
• Authors: Ahmad Marzuki*, Hery Purwanto, Artono Dwijo Sutomo, Harjana Harjana, Ari Handono Ramelan, Devara Ega Fausta, Retno Willy Astuti, Anisa Nandita Rahmawati, Frisca Aulia Alvyanti, Rivina Oktafiani
• Keywords: Boro-Tellurite, Field Strength, Inter-Ionic Distance, Packing Density, Polaron Radius

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