Improving Sliding Wear of AISI52100 Using Cellulose Microparticles Additive

Article Preview

Abstract:

This paper discusses the wear behavior of self-mated AISI52100 bearing steel lubricated by polyol ester containing additives of bacterial cellulose particles. The wear properties are compared to those of surfaces lubricated by the base fluid without the additive. The sliding tests were conducted using a pin-on-disk reciprocating tribometer at room temperature. The results indicate that after a sliding distance of 72 meters, the friction coefficient was relatively similar for both lubricant conditions. However, the wear of the material was significantly reduced with the presence of cellulose particles in the lubricant, improving it by almost 100%. Observation of the worn area of the pin indicates the formation of a tribofilm on the contact interface facilitated by the cellulose particles. EDX analysis revealed that the film comprises oxygen and carbon-rich elements. It seems that the tribo-layer formed by a tribo-chemical reaction during sliding has acted as a protective barrier, preventing surface material ploughing and reducing wear on the tribo-pair.

You might also be interested in these eBooks

Info:

Periodical:

Materials Science Forum (Volume 1150)

Pages:

75-82

Citation:

Online since:

June 2025

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2025 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Minami, I. 2017. Molecular Science of Lubricant Additives. Applied Sciences (Switzerland) 7 (5)

DOI: 10.3390/app7050445

Google Scholar

[2] Gryglewicz, S., and B. Kolwzan. 2004. Synthesis and Biodegradation of Synthetic Oils Based on Adipic and Sebacic Esters. Journal of Synthetic Lubrication 20 (4): 281–88.

DOI: 10.1002/jsl.3000200402

Google Scholar

[3] Hewstone, R. K. 1994. Environmental Health Aspects of Lubricant Additives. Science of the Total Environment, The 156 (3): 243–54.

DOI: 10.1016/0048-9697(94)90191-0

Google Scholar

[4] J. R. Joshi, K. K. Bhanderi, and J. V. Patel, Waste cooking oil as a promising source for bio lubricants- A review. Journal of the Indian Chemical Society, vol. 100, no. 1. 2023.

DOI: 10.1016/j.jics.2022.100820

Google Scholar

[5] D. Rahmadiawan et al., Tribological Properties of Aqueous Carboxymethyl Cellulose/Uncaria Gambir Extract as Novel Anti-Corrosion Water-Based Lubricant. Tribol. Ind., vol. 44, no. 4, 2022.

DOI: 10.24874/ti.1357.08.22.10

Google Scholar

[6] N. Grishkewich, N. Mohammed, J. Tang, and K. C. Tam, Recent advances in the application of cellulose nanocrystals, Curr. Opin. Colloid Interface Sci., vol. 29, p.32–45, 2017.

DOI: 10.1016/j.cocis.2017.01.005

Google Scholar

[7] L. A. Quinchia, M. A. Delgado, T. Reddyhoff, C. Gallegos, and H. A. Spikes, Tribological studies of potential vegetable oil-based lubricants containing environmentally friendly viscosity modifiers, Tribol. Int., vol. 69, p.110–117, 2014

DOI: 10.1016/j.triboint.2013.08.016

Google Scholar

[8] R. K. Singh, O. P. Sharma, and A. K. Singh, Evaluation of cellulose laurate esters for application as green biolubricant additives, Ind. Eng. Chem. Res., vol. 53, no. 25, p.10276–10284, 2014.

DOI: 10.1021/ie501093j

Google Scholar

[9] N. W. Awang, D. Ramasamy, K. Kadirgama, G. Najafi, and N. A. Che Sidik, Study on friction and wear of Cellulose Nanocrystal (CNC) nanoparticle as lubricating additive in engine oil, Int. J. Heat Mass Transf., vol. 131, p.1196–1204, 2019, doi: 10.1016/j.ijheatmasstransfer. 2018.11.128.

DOI: 10.1016/j.ijheatmasstransfer.2018.11.128

Google Scholar

[10] Y. Zhang et al., Tribological properties of nano cellulose fatty acid esters as ecofriendly and effective lubricant additives, Cellulose, vol. 25, no. 5, 2018.

DOI: 10.1007/s10570-018-1780-9

Google Scholar

[11] N. W. Awang, D. Ramasamy, K. Kadirgama, M. Samykano, G. Najafi, and N. A. C. Sidik, An experimental study on characterization and properties of nano lubricant containing Cellulose Nanocrystal (CNC), Int. J. Heat Mass Transf., vol. 130, 2019, doi: 10.1016/j.ijheatmasstransfer. 2018.11.041.

DOI: 10.1016/j.ijheatmasstransfer.2018.11.041

Google Scholar

[12] D. Rahmadiawan, H. Abral, N. Nasruddin, and Z. Fuadi, Stability, Viscosity, and Tribology Properties of Polyol Ester Oil-Based Biolubricant Filled with TEMPO-Oxidized Bacterial Cellulose Nanofiber, Int. J. Polym. Sci., vol. 2021, p.5536047, 2021.

DOI: 10.1155/2021/5536047

Google Scholar

[13] S. C. Shi and S. Z. Jiang, Influence of graphene/copper hybrid nanoparticle additives on tribological properties of solid cellulose lubricants, Surf. Coatings Technol., vol. 389, May 2020.

DOI: 10.1016/j.surfcoat.2020.125655

Google Scholar

[14] Z. Fuadi et al., Effect of Graphene Nanoplatelets on Tribological Properties of Bacterial Cellulose/ Polyolester Oil Bio-Lubricant, Front. Mech. Eng., vol. 8, no. March, p.1–11, 2022.

DOI: 10.3389/fmech.2022.810847

Google Scholar

[15] S. M. Hisham, K. Kadirgama, D. Ramasamy, and S. Rahman, Enhancement of Tribological Behaviour and Thermal Properties of Hybrid Nanocellulose/Copper (II) Oxide Nanolubricant, J. Adv. Res. Fluid Mech. Therm. Sci., vol. 72, no. 1, 2020.

DOI: 10.37934/arfmts.72.1.4754

Google Scholar

[16] S. Hisham et al., Hybrid nanocellulose-copper (II) oxide as engine oil additives for tribological behavior improvement, Molecules, vol. 25, no. 13, 2020.

DOI: 10.3390/molecules25132975

Google Scholar

[17] S. D. Fernández-Silva, M. A. Delgado, C. Roman, and M. García-Morales, Rheological and tribological properties of nanocellulose-based ecolubricants, Nanomaterials, vol. 11, no. 11, 2021.

DOI: 10.3390/nano11112987

Google Scholar

[18] P. G. L. Da Rocha et al., Tribological performances of cellulose nanocrystals in water-based lubricating fluid, J. Appl. Polym. Sci., vol. 139, no. 20, 2022.

DOI: 10.1002/app.52167

Google Scholar

[19] M. J. Shariatzadeh and D. Grecov, Aqueous suspensions of cellulose nanocrystals as water-based lubricants, Cellulose, vol. 26, no. 7, 2019.

DOI: 10.1007/s10570-019-02398-w

Google Scholar

[20] J. Li et al., Tribological behavior of cellulose nanocrystal as an eco-friendly additive in lithiumbased greases, Carbohydr. Polym., vol. 290, 2022.

DOI: 10.1016/j.carbpol.2022.119478

Google Scholar