Support-Driven Enhancement of WO₃-Based Composite Photocatalysts for Methyl Orange Degradation under UV Light

Article Preview

Abstract:

WO3-based composite photocatalysts supported on tungsten disulfide (WS2), urea, melamine, and graphene nanoplatelets (GNPs) were synthesized and characterized. The SEM micrographs showed that the support materials had a major impact on the composites' shape. While WO3/WS2 created layered sheets with scattered nanoparticles, WO3/melamine and WO3/urea showed porous and uneven morphologies. Strong interfacial contact was demonstrated by the homogeneous distribution of tiny WO3 particles on crumpled graphene layers in WO3/GNPs. W and O from WO3, as well as S, N, and C elements from the corresponding supports, were verified by EDX. Methyl orange (MO) degradation under light irradiation was used to assess photocatalytic activity. Because of its huge surface area and improved electron mobility, WO3/GNPs showed the highest degrading efficiency. The WO3/WS2 also displayed encouraging activity efficient due to the interfacial charge separation. On the other hand, WO3/urea and WO3/melamine performed moderately, most likely as a result of agglomeration and less conductive supports. With WO3/GNPs emerging as a promising choice for dye degradation and wastewater treatment applications, these findings emphasize the importance of support materials in enhancing WO3-based photocatalysts.

You might also be interested in these eBooks

Info:

Periodical:

Materials Science Forum (Volume 1194)

Pages:

151-158

Citation:

Online since:

June 2026

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2026 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Zahra, Z., Qamar, M. T., Rauf, A., & Bashir, A. (2021). A review on the degradation of methyl orange by photocatalysis and advanced oxidation processes. Environmental Chemistry Letters, 19(2), 1153–1172

Google Scholar

[2] Chong, M. N., Jin, B., Chow, C. W., & Saint, C. (2010). Recent developments in photocatalytic water treatment technology: A review. Water Research, 44(10), 2997–3027

DOI: 10.1016/j.watres.2010.02.039

Google Scholar

[3] Fujishima, A., & Honda, K. (1972). Electrochemical photolysis of water at a semiconductor electrode. Nature, 238(5358), 37–38

DOI: 10.1038/238037a0

Google Scholar

[4] Zhang, J., Liu, Q., & Li, Y. (2020). Photocatalytic degradation of organic pollutants using WO₃-based nanomaterials under visible-light irradiation: Progress and challenges. Catalysis Today, 340, 224–243

DOI: 10.1016/j.cattod.2018.10.031

Google Scholar

[5] Khan, M. A., Lee, J., & Kim, D. (2021). Recent advances in tungsten-based photocatalysts for environmental remediation. Journal of Environmental Chemical Engineering, 9(5), 106066

DOI: 10.1016/j.jece.2021.106066

Google Scholar

[6] Wang, Z., Zhang, X., Liu, Y., & Huang, L. (2019). WO₃/WS₂ heterostructures with enhanced photocatalytic performance under visible light irradiation. Ceramics International, 45(9), 11294–11301

DOI: 10.1016/j.ceramint.2019.02.203

Google Scholar

[7] Chen, L., Liu, J., Zhang, X., & Li, Y. (2017). Nitrogen-doped porous WO₃ photocatalysts derived from melamine for efficient visible-light-driven degradation of pollutants. Applied Surface Science, 412, 48–55

DOI: 10.1016/j.apsusc.2017.03.145

Google Scholar

[8] Zhang, Z., Wang, W., & Li, Z. (2019). Design of N-doped WO₃ nanostructures for visible-light-driven photocatalysis. Materials Research Bulletin, 120, 110586

DOI: 10.1016/j.materresbull.2019.110586

Google Scholar

[9] Geim, A. K., & Novoselov, K. S. (2007). The rise of graphene. Nature Materials, 6(3), 183–191

DOI: 10.1038/nmat1849

Google Scholar

[10] Nethravathi, C., & Rajamathi, M. (2008). Chemically modified graphene sheets produced by the solvothermal reduction of colloidal dispersions of graphite oxide. Carbon, 46(14), 1994–1998

DOI: 10.1016/j.carbon.2008.08.006

Google Scholar

[11] Chen, Y., Liu, T., Zhang, J., & Ma, H. (2023). Construction of WO₃/WS₂ heterostructure for enhanced photocatalytic performance under visible light. Journal of Alloys and Compounds, 930, 167263

Google Scholar

[12] Zhao, R., Wang, C., Yu, Y., & Li, Y. (2022). Enhanced photocatalytic performance of melamine-modified WO₃ nanostructures under visible light. Materials Chemistry and Physics, 283, 125927.

Google Scholar

[13] Sadiq, M., Junaid, M., & Khan, S. B. (2019). Effect of urea-modification on the structure and optical properties of metal oxides. Ceramics International, 45(3), 3760–3768

DOI: 10.1016/j.ceramint.2018.11.199

Google Scholar

[14] Xie, T., Li, J., Liu, H., & Zhou, Y. (2022). Graphene-based composites for photocatalysis: A review. Chemical Engineering Journal, 429, 132333. https://doi.org/10.1016/j.cej. 2021.132333

Google Scholar

[15] Chen, H., Li, Q., Zhang, Y., & Zhao, X. (2023). Crystalline monoclinic WO₃ nanostructures for visible-light photocatalysis. Journal of Materials Science: Materials in Electronics, 34(6), 4400–4412

DOI: 10.1007/s10854-022-09321-3

Google Scholar

[16] Zhang, T., Zhou, Z., & Liu, W. (2023). Construction of WS₂/WO₃ heterostructures for efficient photodetectors and photocatalysis. Applied Surface Science, 627, 157279

Google Scholar

[17] Wang, L., Deng, Y., & Li, H. (2024). Hybrid WO₃/graphene heterostructures for solar water splitting: Structural and optoelectronic insights. ACS Sustainable Chemistry & Engineering, 12(4), 2031–2040

Google Scholar

[18] Kaur, J., & Singh, M. (2021). Nitrogen-doped WO₃ nanostructures synthesized via urea and melamine. Journal of Alloys and Compounds, 853, 157188. https://doi.org/10.1016/j.jallcom. 2020.157188

Google Scholar

[19] Gong, Y., Zhang, J., Chen, W., Weng, W., & Wu, Y. (2017). Enhanced photocatalytic activity of WS₂/WO₃ composite nanofibers. Materials Letters, 209, 190–193

DOI: 10.1016/j.matlet.2017.08.022

Google Scholar

[20] Zhang, Y., Yu, H., Li, M., & Zhang, H. (2020). Rational design of 2D/2D WS₂/WO₃ heterojunctions for enhanced photocatalytic hydrogen evolution. Journal of Colloid and Interface Science, 562, 430–438

DOI: 10.1016/j.jcis.2019.12.049

Google Scholar

[21] Zhou, Z., Zhang, X., Du, Y., & Li, J. (2020). Porous carbon nitride from melamine for high-performance applications. Journal of Materials Chemistry A, 8(10), 5172–5180

Google Scholar

[22] Li, K., Wang, H., Zhou, W., & Liu, Y. (2021). Urea-assisted synthesis of porous metal oxide nanostructures for photocatalytic applications. Applied Surface Science, 546, 149048

DOI: 10.1016/j.apsusc.2021.149048

Google Scholar

[23] Zhang, N., Yang, M. Q., Liu, S., Sun, Y., & Xu, Y. J. (2019). Metal-free catalysis of graphitic carbon nitride for photocatalytic hydrogen evolution. Chemical Reviews, 119(3), 1036–1086

DOI: 10.1021/acs.chemrev.8b00395

Google Scholar

[24] Chen, Y., Liu, T., Zhang, J., & Ma, H. (2023). Construction of WO₃/WS₂ heterostructure for enhanced photocatalytic performance under visible light. Journal of Alloys and Compounds, 930, 167263

DOI: 10.1016/j.jallcom.2022.167263

Google Scholar

[25] Zhang, Y., Wang, L., Liu, S., & Guo, H. (2020). Melamine-assisted synthesis of nitrogen-doped metal oxides for photocatalytic applications. Applied Surface Science, 527, 146855

DOI: 10.1016/j.apsusc.2020.146855

Google Scholar

[26] Sadiq, M., Junaid, M., & Khan, S. B. (2019). Effect of urea-modification on the structure and optical properties of metal oxides. Ceramics International, 45(3), 3760–3768

DOI: 10.1016/j.ceramint.2018.11.199

Google Scholar

[27] Xie, T., Li, J., Liu, H., & Zhou, Y. (2022). Graphene-based composites for photocatalysis: A review. Chemical Engineering Journal, 429, 132333

DOI: 10.1016/j.cej.2021.132333

Google Scholar

[28] Zhao, H., Wang, A., Zhang, L., & Zhai, J. (2020). Graphene-based photocatalysts for environmental remediation. Chemical Engineering Journal, 382, 122838

DOI: 10.1016/j.cej.2019.122838

Google Scholar

[29] Zhou, X., Pan, L., Wang, Z., & Xu, Y. (2019). Graphene-based hybrid nanomaterials for photocatalytic applications: current status and future perspective. Advanced Functional Materials, 29(20), 1902804

Google Scholar

[30] Wang, J., Zhang, J., Zhang, M., & Wang, X. (2020). Designed synthesis of melamine-derived porous g-C₃N₄ for efficient photocatalytic hydrogen evolution. ACS Applied Materials & Interfaces, 12(1), 707–717

Google Scholar

[31] Chen, X., Li, N., Kong, Z., Ong, W.-J., & Zhao, X. (2018). Photocatalytic reduction of CO₂ by metal–organic frameworks: current status, challenges, and future perspectives. Advanced Functional Materials, 28(21), 1801995

Google Scholar

[32] Li, W., Wang, F., & Wang, Q. (2017). A novel WO₃/WS₂ composite photocatalyst with enhanced visible-light photocatalytic activity for rhodamine B degradation. Applied Surface Science, 426, 1148–1156

DOI: 10.1016/j.apsusc.2017.07.215

Google Scholar